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Journal of Materials Science
Erschienen in: Journal of Materials Science 7/2020

22.10.2019 | Energy materials

Single-crystal LiNi0.5Co0.2Mn0.3O2: a high thermal and cycling stable cathodes for lithium-ion batteries

verfasst von: Zeqin Zhong, Lingzhen Chen, Shaozhen Huang, Weili Shang, Lingyong Kong, Ming Sun, Lei Chen, Wangbao Ren

Erschienen in: Journal of Materials Science | Ausgabe 7/2020

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Abstract

Single-crystalline LiNi0.5Co0.2Mn0.3O2 (denoted as SC-523) with micron size had been successfully synthesized through a facile method. Electrochemical impedance spectroscopy and differential scanning calorimetry were carried out to identify the improved electrochemical performance and desired thermal stability. Even after 100 cycles, SC-523 still delivered a discharge capacity of 151.1 mA h g−1 (capacity retention with 90.3%) at 1 C in voltage range from 3.0 to 4.5 V (vs. Li/Li+), while polycrystalline spherical LiNi0.5Co0.2Mn0.3O2 (denoted as PC-523) only exhibited 141.7 mA h g−1 (capacity retention with 78.4%). Besides, SC-523 shows a higher decomposition temperature of 332.13 °C, 14.61 °C higher than that of PC-523 during the thermal decomposition. Consequently, single-crystalline particles with robust morphological integrity ensure the enhanced cycling stability and thermal stability.
Vorheriger Artikel Effects of Pb doping on the electrical transport performance of Cu1.98Se
Nächster Artikel Preparation and characterization of hematite nanoparticles-decorated zinc oxide particles (ZnO/Fe2O3) as photoelectrodes for solar cell applications

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Metadaten
Titel
Single-crystal LiNi0.5Co0.2Mn0.3O2: a high thermal and cycling stable cathodes for lithium-ion batteries
verfasst von
Zeqin Zhong
Lingzhen Chen
Shaozhen Huang
Weili Shang
Lingyong Kong
Ming Sun
Lei Chen
Wangbao Ren
Publikationsdatum
22.10.2019
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 7/2020
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-019-04133-z

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