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Biomass Conversion and Biorefinery
Erschienen in: Biomass Conversion and Biorefinery 6/2024

30.06.2022 | Original Article

Sodium lignosulfonate: a renewable corrosion inhibitor extracted from lignocellulosic waste

verfasst von: Nour S. Abdelrahman, Emmanuel Galiwango, Ali H. Al-Marzouqi, Eyas Mahmoud

Erschienen in: Biomass Conversion and Biorefinery | Ausgabe 6/2024

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Abstract

In this study, sodium lignosulfonate was extracted from a natural lignocellulose waste and its characterization and potential application as a corrosion inhibitor were investigated. FTIR results confirmed presence of sulfonic groups like ones in a commercial sample. The aqueous solubility of sodium lignosulfonate increased from 29.17 to 88.58 wt% when reaction time was increased from 1 to 4 h. Corrosion inhibition efficiency of 90.23% was obtained. The main factors of lignin concentration (10–25 g/L), temperature (80–140 °C), reaction time (1–4 h), sodium hydroxymethyl sulfonate/lignin mole ratio (0.3–1.2), and sodium hydroxide concentration (0.25–1 M) were investigated for their effect towards the aqueous solubility of sodium lignosulfonate. The Taguchi orthogonal array statistical design was used to investigate effects of factors, their interactions, and the optimum values within factor levels towards solubility as the response. The solubility of the sodium lignosulfonate was found to be more significantly influenced by reaction time > lignin concentration > sodium hydroxide > temperature > reactants/lignin ratio. The optimum condition for sulfomethylation reaction was found to be 4 h, 100 °C, 25 g/L, 0.9, and 0.5 M for reaction time, temperature, lignin concentration, reactant/lignin ratio, and NaOH concentration, respectively. The corrosion test revealed a reduction in corrosion rate from 2.6 to 1.2 mm/year when the concentration of the sodium lignosulfonate was increased from 0 to 8 ppm.
Vorheriger Artikel Characterization and pyrolysis kinetics study of hydrochar derived from turfgrass (Zoysia matrella) using hydrothermal carbonization
Nächster Artikel Mechanical, thermal, and water absorption properties of hybrid short coconut tree primary flower leaf stalk fiber/glass fiber-reinforced unsaturated polyester composites for biomedical applications

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Metadaten
Titel
Sodium lignosulfonate: a renewable corrosion inhibitor extracted from lignocellulosic waste
verfasst von
Nour S. Abdelrahman
Emmanuel Galiwango
Ali H. Al-Marzouqi
Eyas Mahmoud
Publikationsdatum
30.06.2022
Verlag
Springer Berlin Heidelberg
Erschienen in
Biomass Conversion and Biorefinery / Ausgabe 6/2024
Print ISSN: 2190-6815
Elektronische ISSN: 2190-6823
DOI
https://doi.org/10.1007/s13399-022-02902-6

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