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Journal of Sol-Gel Science and Technology

Erschienen in:

09.06.2022 | Original Paper: Industrial and technological applications of sol-gel and hybrid materials

Sorbents based on Ni(OH)₂/chitosan, immobilization of metal hexacyanoferrates, and application for removal of radionuclide Cs from aqueous solutions

verfasst von: Larisa Zemskova, Eduard Tokar, Darya Shlyk, Andrei Egorin

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 2/2023

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Abstract

In the present work, in-situ formed nickel(II) hydroxide particles have been immobilized in a chitosan matrix with subsequent introduction of potassium hexacyanoferrate into this hybrid material, which has resulted in the formation of advanced composite sorbents for ¹³⁷Cs removal. The immobilization of microcrystalline nickel(II) hydroxide particles has been carried out via homogeneous alkalization of nickel(II) chloride solutions by urea hydrolysis. Intercalation of the Fe(CN)₆⁴⁻ ion into nickel hydroxide has been performed at the stage of formation of nickel hydroxide in the chitosan gel. In the process of anion exchange sorption of Fe(CN)₆⁴⁻ ions with nickel hydroxide, a composite sorbent Ni(OH)₂–CS–KNiFe(CN)₆ has been formed. According to X-ray diffraction analysis, the composite sorbent also contains α-Ni(OH)₂. Both types of sorbents can be used to remove cesium from wastewaters.

Vorheriger Artikel State-of-the-art and development of sol–gel technology in Uzbekistan (Preface)

Nächster Artikel Conditions for selection of superabsorbent polymer hydrogel for cement compositions

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Titel: Sorbents based on Ni(OH)2/chitosan, immobilization of metal hexacyanoferrates, and application for removal of radionuclide Cs from aqueous solutions
verfasst von: Larisa Zemskova
Eduard Tokar
Darya Shlyk
Andrei Egorin
Publikationsdatum: 09.06.2022
Verlag: Springer US
Erschienen in: Journal of Sol-Gel Science and Technology / Ausgabe 2/2023
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI: https://doi.org/10.1007/s10971-022-05861-6

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