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Erschienen in: Optical and Quantum Electronics 3/2024

01.03.2024

Structural, mechanical and electrical characteristics as well radiation attenuation capacities of barium lithium meta-phosphate glasses

verfasst von: M. Hamed Misbah, R. M. Ramadan, Z. Y. Khattari, Y. S. Rammah, G. El-Damrawi

Erschienen in: Optical and Quantum Electronics | Ausgabe 3/2024

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Abstract

Structural, density, mechanical, electrical and shielding properties of xLi2O·(49.5-x)BaO·50P2O5·0.5CuO (0 ≤ x ≤ 49.5 mol%) glasses have been studied. XRD patterns and SEM analyses have demonstrated the amorphous nature of the prepared glass system. FTIR spectra showed that there is a slight increase in the relative areas of Q1 and Q2, and a decrease in that of P=O as Li2O replaces BaO. This is concomitant not only with a decrease in density and molar volume but also with an increase in electrical conductivity and elastic parameters (Young, shear and bulk moduli). This is attributed to the significantly heavier mass of BaO than Li2O, as well as the higher ionic radius of the Ba2+ cation than the Li+ ion. Furthermore, the mass and linear attenuation coefficients, effective electron density and effective atomic number are decreased. Thus, the radiation shielding capacity decreases as the Li2O content replaces BaO. Overall, the proposed glass matrix is promising for electronic devices and radiation shielding applications.

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Metadaten
Titel
Structural, mechanical and electrical characteristics as well radiation attenuation capacities of barium lithium meta-phosphate glasses
verfasst von
M. Hamed Misbah
R. M. Ramadan
Z. Y. Khattari
Y. S. Rammah
G. El-Damrawi
Publikationsdatum
01.03.2024
Verlag
Springer US
Erschienen in
Optical and Quantum Electronics / Ausgabe 3/2024
Print ISSN: 0306-8919
Elektronische ISSN: 1572-817X
DOI
https://doi.org/10.1007/s11082-023-06074-z

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