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Polymer Bulletin

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08.10.2022 | Original Paper

Synthesis and characterization of polyimides from diisocyanate with enhanced solubility and thermostability properties via direct low-temperature one-step polymerization in NMP solvent

verfasst von: Najaa Mustaffa, Tatsuo Kaneko, Kenji Takada, Sumant Dwivedi, Mohd Sukor Su’ait, Nadhratun Naiim Mobarak

Erschienen in: Polymer Bulletin | Ausgabe 8/2023

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Abstract

Polyimides (PIs) can be synthesized from diisocyanate and dianhydride through a direct heating one-step polymerization process with a lower temperature and shorter reaction time than the traditional stepwise heating route. This study discusses the properties of resulting PIs produced using the direct one-step heating procedure with N-methyl-2-pyrrolidinone (NMP) as the solvent. Based on the structural and property evaluations, the reaction system used yields not only organo-soluble PIs but also ultra-high thermal stability up to 580 °C at 5% weight loss. The obtained PIs have medium molecular weights ranging from 26.6 to 35.6 kg/mol. This reaction system is found to be fast and efficient in producing high thermoresistant PI materials with improved processing ability. These findings provided insights on the energy-efficient one-step synthesis of PIs specifically derived from diisocyanate and dianhydride.

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Vorheriger Artikel Evaluation of acid digestion methodology in poly (ethylene terephthalate) resin for elementary determination by ICP OES

Nächster Artikel Effect of amphiphilic phosphorous dendrons on the conformation, secondary structure, and zeta potential of albumin and thrombin

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Titel: Synthesis and characterization of polyimides from diisocyanate with enhanced solubility and thermostability properties via direct low-temperature one-step polymerization in NMP solvent
verfasst von: Najaa Mustaffa
Tatsuo Kaneko
Kenji Takada
Sumant Dwivedi
Mohd Sukor Su’ait
Nadhratun Naiim Mobarak
Publikationsdatum: 08.10.2022
Verlag: Springer Berlin Heidelberg
Erschienen in: Polymer Bulletin / Ausgabe 8/2023
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-022-04510-w

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