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Polymer Bulletin
Erschienen in: Polymer Bulletin 1/2018

08.04.2017 | Original Paper

Synthesis and characterization of zein-based superabsorbent hydrogels and their potential as heavy metal ion chelators

verfasst von: Na Ni, Daihui Zhang, Marie-Josée Dumont

Erschienen in: Polymer Bulletin | Ausgabe 1/2018

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Abstract

Superabsorbent hydrogels were synthesized by solution-based graft copolymerization of acrylic acid monomers on the hydrolyzed zein protein backbones in the presence of an acrylamide crosslinker, sodium bisulfite and potassium persulfate as initiators. The grafting was confirmed by Fourier transform infrared spectroscopy and the morphology was studied by scanning electron microscopy. A loose structure was observed in the hydrolyzed zein protein-g-polyacrylic acid. Moreover, differential scanning calorimetry and swelling tests were performed to evaluate the effect of the formulations on the thermal and swelling properties of the hydrogels. The highest equilibrium swelling value in distilled water reached 239.6 g/g of hydrogel. The potential of these materials as heavy metal ions chelator was also assessed. The preliminary results showed that the hydrogels had a good copper ion chelation capacity (maximum of 208 mg/g at pH 4.5), probably due to the presence of a large number of functional groups from the polyacrylic acid and the hydrolyzed zein protein.
Vorheriger Artikel Steady-shear rheology and activation thermodynamics of the interpolymer complex between nonionic polymeric surfactant and hydrophobically modified polyacrylic acid in propylene glycol–water mixture
Nächster Artikel Novel hydrophobic macromonomers for potential amphiphilic block copolymers

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Metadaten
Titel
Synthesis and characterization of zein-based superabsorbent hydrogels and their potential as heavy metal ion chelators
verfasst von
Na Ni
Daihui Zhang
Marie-Josée Dumont
Publikationsdatum
08.04.2017
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 1/2018
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-017-2017-z

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