Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Bücher
Zeitschriften
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
ATZ-Fachkongress

Chassis.tech plus 2024


4 Kongresse in einer Veranstaltung

Treffen Sie in München die Fachleute von Chassis, Lenkung, Bremsen sowie Reifen/Räder.
Erweiterte Suche
Anmelden
nach oben
Journal of Polymer Research
Erschienen in: Journal of Polymer Research 10/2017

01.09.2017 | ORIGINAL PAPER

Synthesis, characterization and application of a novel nanometer-sized chelating resin for removal of Cu(II), Co(II) and Ni(II) ions from aqueous solutions

verfasst von: A. F. Shaaban, A. A. Khalil, Mohamed Radwan, Manal El Hefnawy, H. A. El Khawaga

Erschienen in: Journal of Polymer Research | Ausgabe 10/2017

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

A novel nanometer-sized chelating resin (NSCR) was prepared via two steps, First step: copolymerization reaction of N-methacryloxyphtalimide (NMP) with methylenebisacrylamide (MBA) by suspension polymerization method to give ultrafine poly (NMP-co-MBA). Second step: reaction of triethylenetetramine (TETA) with poly (NMP-co-MBA) to give NSCR. The prepared NSCR was characterized by Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), Transmission electron microscopy (TEM), Brunauer-Emmett-Taller (BET) and thermogravimetric analysis (TGA). This study illustrated the capability of NSCR for extraction of Cu(II), Co(II) and Ni(II) from aquatic solutions. The pH effect, metal ions concentration, temperature and contact time were elaborated in batch experiments. The results showed that high capacities were 1.3, 1.0 and 0.95 mmol/g resin for Cu(II), Ni(II) and Co(II) ions, respectively. The experimental data of adsorption isotherms were convenient for Langmuir isotherm, and the kinetic data illustrated that the removal process was described by pseudo-second order kinetic model. The parameters of Thermo dynamic illustrated that the process of adsorption was endothermic and spontaneous reaction. The prepared NSCR was regenerated and used repetitively for five times with small decrease in adsorption capacity.
Vorheriger Artikel Synthesis, characterization and toxicological evaluation of pH-sensitive polyelectrolyte Nanogels
Nächster Artikel Nano-assembly of intertwining lamellae of opposite bending senses in poly(ethylene oxide) co-crystallizing with poly(p-vinyl phenol)

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
1.
Van Genderen EJ, Ryan AC, Tomasso JR, Klaine SJ (2005) Evaluation of acute copper toxicity to larval fathead minnows (Pimephales Promelas) in soft surface waters. Environ Toxicol Chem 24:408–414CrossRef
2.
Apostoli P, Catalani S, Zaghini A, Mariotti A, Poliani PL, Vielmi V, Semeraro F, Duse S, Porzionato A, Macchi V, Padovani A, Rizzetti MC, De Caro R (2012) High doses of cobalt induce optic and auditory neuropathy. Exp Toxicol Pathol 65:719–727CrossRef
3.
Das KK, Das SN, Dhundasi SA (2008) Nickel, its adverse health effects & oxidative stress. Indian J Med Res 128:412–425
4.
Nebel BJ, Wright RT (1966) Environmental science 5th edn. Prenticehall, London,
5.
Nagh WSW, Endud CS, Mayanar R (2002) Removal of Cu(II) ions from aqueous solution onto chitosan and crosslinked chitosan beads. React Funct Polym 50:181–190CrossRef
6.
Tofighy MA, Mohammadi T (2011) Adsorption of divalent heavy metal ions from water using carbon nano tube sheet. J Hazard Mater 185:140–147CrossRef
7.
Deligz H, Erdem E (2008) Comparative studies on the solvent extraction of transition metal cations by calixarene, phenol and ester derivatives. J Hazard Mater 154:29–32CrossRef
8.
Bessbousse H, Rhlalou T, Verchere JF, Lebrun L (2008) Removal of heavy metal ions from aqueous solutions by filteration with a novel complexing membrane containing poly(ethyleneimine) inapoly (vinylalcohol) matrix. J Membr Sci 307:249–259CrossRef
9.
Rivas BL, Quilodran B, Quiroz E (2004) Trace metal ion retention properties of crosslinked poly(4-Vinylpyridine) and poly(acrylic acid). J Appl Polym Sci 92:2908–2916CrossRef
10.
Henry WD, Zhao D, Sengupta AK, Lang C (2004) Preparation and characterization of a new class of polymeric ligand exchangers for selective removal of trace contaminants from water. React Funct Polym 60:109–120CrossRef
11.
Nastasovic A, Jovanovic S, Dordevic D, Onjia A, Jakovljevic D, Novakovic T (2004) Metal sorption on macroporous poly (GMA-co-EGDMA) modified with ethylene di amine. React Funct Polym 58:139–147CrossRef
12.
Baraka A, Hall PJ, Heslop MJ (2007) Preparation and characterization of melamine-formaldehyde-dtpa chelating resin and its use as an adsorbent for heavy metals removal from wastewater. React Funct Polym 67:585–600CrossRef
13.
Leinonen H, Lehto J (2000) Ion-exchange of nickel by iminodiacetic acid chelating resin Chelex 100. React Funct Polym 43:1–6CrossRef
14.
Neagu V, Bunia I, Luca C (2006) Organic ion exchangers synthesis and their behaviour in the retention of some metal ions. Macromol Symp 235:136–142CrossRef
15.
Denizli A, Sanli N, Garipcan B, Patir S, Alsancak G (2004) Methacryloylamidoglutamic acid incorporated porous poly(methyl methacrylate) beads for heavy-metal removal. Ind Eng Chem Res 43:6095–6101CrossRef
16.
Zohuriaan Mehr MJ, Pourjavadi A, Salehi Rad M (2004) Modified CMC. 2. Novel carboxymethylcellulose-based poly(amidoxime) chelating resin with high metal sorption capacity. React Funct Polym 61:23–31CrossRef
17.
Shaaban AF, Fadel DA, Mahmoud AA, Elkomy MA, Elbahy SM (2014) Synthesis of a new chelating resin bearing amidoxime group for adsorption of cu(II), Ni(II) and Pb(II) by batch and fixed-bed column methods. J Environ Chem Eng 2:632–641CrossRef
18.
Shaaban AF, Fadel DA, Mahmoud AA, Elkomy MA, Elbahy SM (2013) Removal of Pb(II), cd(II), Mn(II) and Zn(II) using iminodiacetate chelating resin by batch and fixed bed column methods. Desalin Water Treat 51:5526–5536CrossRef
19.
Shaaban AF, Fadel DA, Mahmoud AA, Elkomy MA, Elbahy SM (2013) Synthesis and characterization of dithiocarbamate chelating resin and its adsorption performance towards Hg(II), Cd(II) and Pb(II) by batch and fixed-bed column methods. J Environ Chem Eng 1:208–217CrossRef
20.
Shaaban AF, Mohamed TY, Fadel DA, Bayomi NM (2017) Removal of Ba(II) and Sr(II) ions using modified chitosan beads with bendent amidoxime moieties by batch and fixed column methods. J Desalin Water Treat in press
21.
Ge F, Li M, Ye H, Zhao B (2012) Effective removal of heavy metal ions Cd2+, Zn2+, Pb2+, Cu2+ from aqueous solution by polymer-modified magnetic nanoparticles. J Hazard Mater 211–212:366–372CrossRef
22.
Cumbal L, Sengupta AK (2005) Removal using polymer-supported hydrated iron(III) oxide nanoparticles: role of donnan membrane effect. Environ Sci Technol 39:6508–6515
23.
Zargoosh K, Abedini H, Abdolmaleki A, Molavian MR (2013) Effective removal of heavy metal ions from industrial wastes using thiosalicylhydrazide-modified magnetic nanoparticles. Ind Eng Chem Res 52:14944–14954CrossRef
24.
Wang X, Guo Y, Yang L, Han M, Zhao J, Cheng X (2012) Nanomaterials as sorbents to remove heavy metal ions in wastewater treatment. J Environ Anal Toxicol 2:154CrossRef
25.
Shaaban AF, Arief MMH, Khalil AA, Messina NN (1988) 2-Poly-N-acyloyloxy- and -N- methacryloyloxyphthalimi- de as activated drug-binding matrices. Acta Polym 39:145–148CrossRef
26.
Khalil AA (2006) Exchange reactions of poly-2-(N-phthalimido) ethyl acrylate with hydroxyl and amino compounds. J Appl Polym Sci 99:2258–2262CrossRef
27.
Long C, Li Y, Yu W, Li A (2012) Adsorption characteristics of water vapor on the hypercrosslinked polymeric adsorbent. Chem Eng J 180:106–112CrossRef
28.
Bratkowska D, Fontanals N, Borrull F, Cormack PAG, Sherrington DC, Marce RM (2010) Hydrophilic hypercrosslinked polymeric sorbents for the solid-phase extraction of polar contaminants from water. J Chromatogr A 1217:3238–3243CrossRef
29.
Gurses A, Yalcin M, Sozbilir M, Dogar C (2003) The investigation of adsorption thermodynamics and mechanism of a cationic surfactant, CTAB, onto powdered active carbon. Fuel Process Technol 81:57–66CrossRef
30.
Cumbal L, Greenleaf J, Leun D, SenGupta AK (2003) Polymer supported inorganic nanoparticles: characterization and environmental applications. React Funct Polym 54:167–180CrossRef
31.
Elbhiri Z, Chevalier Y, Chovelon J-M, Jeffrezic-Renault N (2000) Grafting of phosphonate groups on the silica surface for the elaboration of ion-sensitive field-effect transistors. Talanta 52:495–507CrossRef
32.
Lin Z, Zhang Y, Chen Y, Qian H (2012) Extraction and recycling utilization of metal ions (Cu2+, Co2+ and Ni2+) with magnetic polymer beads. J Chem Eng 200–202:104–110CrossRef
33.
Pekel N, Sahiner N, Guven O (2001) Use of amidoximated acrylonitrile/N-vinyl 2 pyrrolidone interpenetrating polymer networks for uranyl ion adsorption from aqueous systems. J Appl Polym Sci 81:2324–2329CrossRef
34.
Kawai O, Saito K, Sugita K (2000) Comparison of amidoxime adsorbents prepared by cografting methacrylic acid and 2-hydroxyethyl methacrylate with acrylonitrile onto polyethylene. Ind Eng Chem Res 39:2910–2915CrossRef
35.
Cegłowski M, Schroeder G (2015) Removal of heavy metal ions with the use of chelating polymers obtained by grafting pyridine–pyrazole ligands onto polymethylhydrosiloxane. J Chem Eng 259:885–893CrossRef
36.
Lia B, Liu F, Wang J, Ling C, Li L, Hou P, Li A, Bai Z (2012) Efficient separation and high selectivity for nickel from cobalt-solution by a novel chelating resin: batch, column and competition investigation. J Chem Eng 195–196:31–39CrossRef
37.
Coşkun R, Soykan C, Saçak M (2006) Adsorption of copper(II), nickel(II) and cobalt(II) ions from aqueous solution by methacrylic acid/acrylamide monomer mixture grafted poly(ethylene terephthalate) fiber. Sep Purif Technol 49:107–114CrossRef
38.
Bekheit MM, Nawar N, Addison AW, Abdel-Latif DA, Monier M (2011) Preparation and characterization of chitosan-grafted-poly(2-amino-4,5-pentamethylene-thiophene-3-carboxylic acid N -acryloyl-hydrazide) chelating resin for removal of Cu(II), Co(II) and Ni(II) metal ions from aqueous solutions. Int J Biol Macromol 48:558–565CrossRef
39.
Monier M, Ayad DM, Wei Y, Sarhan AA (2010) Preparation and characterization of magnetic chelating resin based on chitosan for adsorption of Cu(II), Co(II), and Ni(II) ions. React Funct Polym 70:257–266CrossRef
40.
Sales Jose AA, Faria Flavia P, Prado Alexandre GS, Claudio A (2004) Attachment of 2-aminomethylpyridine molecule onto grafted silica gel surface and its ability in chelating cations. Polyhedron 23:719–725CrossRef
41.
Monier M, Ayad DM, Wei Y, Sarhan AA (2010) Adsorption of Cu(II), Co(II), and Ni(II) ions by modified magnetic chitosan chelating resin. J Hazard Mater 177:962–970CrossRef
42.
Langmuir I (1918) The adsorption of gases on plane surfaces of glass, mica and platinum. J Am Chem Soc 40:1361–1403CrossRef
43.
Weber TW, Chakravot RK (1974) Pore and solid diffusion models for fixed bed adsorbents. AICHE J 20:228–238CrossRef
44.
Sari A, Tuzen M, Citak D, Soylak M (2007) Equilibrium, kinetic and thermodynamic studies of adsorption of Pb(II) from aqueous solution onto Turkish kaolinite clay. J Hazard Mater 149:283–291CrossRef
45.
Wang XS, Huang J, Hua HQ, Wang J, Qin Y (2007) Determination of kinetic and equilibrium parameters of the batch adsorption of Ni(II) from aqueous solutions by Na-mordenite. J Hazard Mater 142:468–476CrossRef
46.
Freundlich H (1906) Adsorption in solution. Phys Chem Soc 40:1361–1368
47.
Temkin MJ, Phyzev V (1940) Recent modifications to Langmuir isotherms. Acta Physiochim 12:217–222
48.
Lagergren S, Svenska BK (1898) Zur theorie der sogenannten adsorption geloester stoffe. K Svenska Vetenskapsakad Handl 24:1–39
49.
Ho YS (2006) Second order kinetic model for the sorption of cadmium on to tree fern: a comparison of linear and non linear methods. Water Res 40:119–125CrossRef
50.
Weber WJ, Morris JC (1964) Equilibria and capacities for adsorption on carbon. J Sanit Eng Div 90:79–91
51.
Sarici-Ozdemir C, Onal Y (2010) Equilibrium, kinetic and thermodynamic adsorptions of the environmental pollutant tannic acid onto activated carbon. Desalination 251:146–152CrossRef
52.
Nilchi A, Saberi R, Moradi M, Azizpour H, Zarghami R (2011) Adsorption of cesium on copper hexacyanoferrate–PAN composite ion exchanger from aqueous solution. J Chem Eng 172:572–580CrossRef
53.
Unlu N, Ersoz M (2007) Removal of heavy metal ions by using dithiocarbamated- sporopollenin. Sep Purif Technol 52:461–469CrossRef
54.
Bandegharaei AH, Hosseini MS, Jalalabadi Y, Sarwghadi M, Nedaie M, Taherian A, Ghaznavi A, Eftekhari A (2011) Removal of Hg (II) from aqueous solutions using a novel impregnated resin containing 1-(2-thiazolylazo)-2-naphthol (TAN). J Chem Eng 168:1163–1173CrossRef
Metadaten
Titel
Synthesis, characterization and application of a novel nanometer-sized chelating resin for removal of Cu(II), Co(II) and Ni(II) ions from aqueous solutions
verfasst von
A. F. Shaaban
A. A. Khalil
Mohamed Radwan
Manal El Hefnawy
H. A. El Khawaga
Publikationsdatum
01.09.2017
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 10/2017
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-017-1323-3

Weitere Artikel der Ausgabe 10/2017

Journal of Polymer Research 10/2017 Zur Ausgabe

OriginalPaper

Disperse-within-disperse patterning on ternary/binary mixed-brush single crystals using polyaniline, polystyrene and poly(methyl methacrylate) grafts

ORIGINAL PAPER

Silver nanoparticles embedded gum ghatti-graft-poly(N,N-dimethylacrylamide) biodegradable hydrogel: evaluation as matrix for controlled release of 2,4-dichlorophenoxyacetic acid

ORIGINAL PAPER

An antibacterial composite system based on multi-responsive microgels hosting monodisperse gold nanoparticles

ORIGINAL PAPER

Nano-assembly of intertwining lamellae of opposite bending senses in poly(ethylene oxide) co-crystallizing with poly(p-vinyl phenol)

ORIGINAL PAPER

Preparation of random poly(butylene alkylate-co-terephthalate)s with different methylene group contents: crystallization and degradation kinetics

ORIGINAL PAPER

In vitro cytotoxicity of hydrogels based on chitosan and modified with gold nanoparticles

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise