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Journal of Nanoparticle Research

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01.11.2021 | Research paper

Synthesis of La-doped Bi₂WO₆ to study on the removal of RhB wastewater under visible light

verfasst von: Zhi Li, XiaoMei Zhu, Hui Liu, Yu Liu, Tong Yu, Bing Sun

Erschienen in: Journal of Nanoparticle Research | Ausgabe 11/2021

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Abstract

Bismuth tungstate photocatalysts were prepared by the hydrothermal synthesis method which is both simple and safe. La was doped at different molar ratios into Bi₂WO₆ samples. The photocatalytic activity of the as-prepared samples was then evaluated by removal of Rhodamine B (RhB) solution under visible light irradiation. Samples with high photocatalytic activity were characterized by various methods, such as Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), Brunauer–Emmett–Teller (BET) surface area, and ultraviolet visible (UV–vis) diffuse reflectance spectra (DRS). Compared with pure Bi₂WO₆, the La doping effectively improved the photocatalytic activity of Bi₂WO₆. 3%La/Bi₂WO₆ sample displayed superior photocatalytic efficiency with nearly 98.2% removal of RhB solution in 120 min of visible light irradiation. The results of characterization revealed that the specific surface area of Bi₂WO₆ photocatalyst was also increased after La doping. It indicated that La doping decreases the band gap and hinders the re-binding of e⁻ and h⁺. Therefore, the La-doped Bi₂WO₆ samples have an absorption property in the visible light range and have a good morphology. The experimentally determined photocatalytic mechanism showed that h⁺ was the main active species. The photocatalytic degradation effects of photocatalyst amount, initial RhB concentration, and initial pH of the RhB solution were investigated in the 3%La/Bi₂WO₆ sample, which optimized the photocatalytic activity. In addition, a possible mechanism is proposed to explain the process of RhB solution removal.

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Vorheriger Artikel Template-assisted synthesis of porous Co3O4 nanosheet with excellent electrochemical performance for rechargeable lithium-ion batteries

Nächster Artikel Single, binary and successive patterning of charged nanoparticles by electrophoretic deposition

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Abu MH, Elella EA, ElHafeez ES, Goda SL, Yoon KR (2019) Smart bactericidal filter containing biodegradable polymers for crystal violet dye adsorption. Cellulose 26:9179–9206. https://doi.org/10.1007/s10570-019-02698-1CrossRef

Abu MH, Elella ES, Goda HG, El-Bahy SM, Nour MA, Yoon KR (2021a) Green antimicrobial adsorbent containing grafted xanthan gum/SiO₂ nanocomposites for malachite green dye. Int J Biol Macromol 191:385–395. https://doi.org/10.1016/j.ijbiomac.2021.09.040CrossRef

Abu MH, Elella ES, Goda KR, Yoon SE, Hong MS, Morsy RA, Sadak HebaGamal (2021b) Novel vapor polymerization for integrating flame retardant textile with multifunctional properties. Compos Commun 24:100614. https://doi.org/10.1016/j.coco.2020.100614CrossRef

Abu Elella MH, Goda ES, Abdallah HM, Shalan AE, Gamal H, Yoon KR (2021a) Innovative bactericidal adsorbents containing modified xanthan gum/montmorillonite nanocomposites for wastewater treatment. Int J Biol Macromol 167:1113–1125. https://doi.org/10.1016/j.ijbiomac.2020.11.065CrossRef

Abu Elella MH, Goda Emad S, Gab-Allah Mohamed A, EunHong Sang, Pandit Bidhan, Lee Seungho, Gamal Heba, Rehman Aafaq Ur, RoYoonb Kuk (2021) Xanthan gum-derived materials for applications in environment and eco-friendly materials: a review. J Environ Chem Eng 9(1):104702. https://doi.org/10.1016/j.jece.2020.104702CrossRef

Ait Ahsaine H, El Jaouhari A, Slassi A, Ezahri M, Benlhachemi A, Bakiz B, Guinneton F, Gavarri JR (2016) Electronic band structure and visible-light photocatalytic activity of Bi₂WO₆: elucidating the effect of lutetium doping. RSC Adv 6(103):101105–101114. https://doi.org/10.1039/C6RA22669HCrossRef

Amano F, Nogami K, Ohtani B (2009) Visible light-responsive bismuth tungstate photocatalysts: effects of hierarchical architecture on photocatalytic activity. J Phys Chem C 113:1536–1542. https://doi.org/10.1021/jp808685mCrossRef

Amano F, Yamakata A, Nogami K, Osawa M, Ohtani B (2011) Effect of photoexcited electron dynamics on photocatalytic efficiency of bismuth tungstate. J Phys Chem C 115:16598–16605. https://doi.org/10.1021/jp2051257CrossRef

Bhattacharya C, Lee H, Bard A (2013) Rapid screening by scanning electrochemical microscopy (SECM) of dopants for Bi₂WO₆ improved photocatalytic water oxidation with Zn doping. J Phys Chem C 117(19):9633–9640. https://doi.org/10.1021/jp308629qCrossRef

Bingham S, Daoud W (2011) Recent advances in making nano-sized TiO₂ visible-light active through rare-earth metal doping. J Mater Chem 21:2041–2050. https://doi.org/10.1039/c0jm02271cCrossRef

Di J, Xia J, Ge Y, Li H, Ji H, Xu H, Zhang Q, Li H, Li M (2015) Novel visible-light-driven CQDs/Bi₂WO₆ hybrid materials with enhanced photocatalytic activity toward organic pollutants degradation and mechanism insight. Appl Catal B-Environ 168–169:51–61. https://doi.org/10.1016/j.apcatb.2014.11.057CrossRef

Goda ES, Abu Elella MH, Sohail M, Singu BS, Pandit B, El Shafey AM, Aboraia AM, Gamal H, Hong SE, Yoon KR (2021) N-Methylene phosphonic acid chitosan/graphene sheets decorated with silver nanoparticles as green antimicrobial agents. Int J Biol Macromol 182:680–688. https://doi.org/10.1016/j.ijbiomac.2021.04.024CrossRef

Goda Emad S, Rehman Aafaq Ur, Pandit Bidhan, Eissa Ahmed Al-Shahat, Hong SangEun, Yoon Kuk Ro (2022) Al-doped Co₉S₈ encapsulated by nitrogen-doped graphene for solid-state asymmetric supercapacitors. Chem Eng J 428:132470. https://doi.org/10.1016/j.cej.2021.132470CrossRef

Gou J, Ma Q, Deng X, Cui Y, Zhang H, Cheng X, Li X, Xie M, Cheng Q (2017) Fabrication of Ag₂O/TiO₂-zeolite composite and its enhanced solar light photocatalytic performance and mechanism for degradation of norfloxacin. Chem. Eng J 308:818–826. https://doi.org/10.1016/j.cej.2016.09.089CrossRef

Gu H, Yu L, Wang J, Ni M, Liu T, Chen F (2017a) Tunable luminescence and enhanced photocatalytic activity for Eu(III) doped Bi₂WO₆ nanoparticles. Spectrochim Acta A 177:58–62. https://doi.org/10.1016/j.saa.2017.01.034CrossRef

Gu H, Yu L, Wang J, Ni M, Liu T, Chen F (2017b) Tunable luminescence and enhanced photocatalytic activity for Eu(III) doped Bi₂WO₆ nanoparticles. Spectrochim. Acta Part a: Mol Biomol Spectrosc 177:58–62. https://doi.org/10.1016/j.saa.2017.01.034CrossRef

Gui M, Zhang W, Chang Y, Yu Y (2012) One-step hydrothermal preparation strategy for nanostructured WO₃/Bi₂WO₆ heterojunction with high visible light photocatalytic activity. Chem Eng J 197:283–288. https://doi.org/10.1016/j.cej.2012.05.032CrossRef

Guo Y, Zhao J, Zhang H, Yang S, Qi J, Wang Z, Xu H (2005) Use of rice husk-based porous carbon for adsorption of Rhodamine B from aqueous solutions. Dyes Pigments 66:123–128. https://doi.org/10.1016/j.dyepig.2004.09.014CrossRef

Guo S, Li X, Wang H, Dong F, Wu Z (2012) Fe-ions modified mesoporous Bi₂WO₆ nanosheets with high visible light photocatalytic activity. J Colloid Interface Sci 369:373–380. https://doi.org/10.1016/j.jcis.2011.12.007CrossRef

Hepemma OA, et al. (1990) J Applied Catalysis, 62(1), 1.

Hu T, Li H, Du N, Hou W (2018) Iron-doped bismuth tungstate with an excellent photocatalytic performance. ChemCatChem 10(14):3040–3048. https://doi.org/10.1002/cctc.201701965CrossRef

Irie H, Watanabe Y, Hashimoto K (2003) Nitrogen-concentration dependence on photocatalytic activity of TiO_2-xN_x powders. J Phys Chem B 107:5483–5486. https://doi.org/10.1021/jp030133hCrossRef

Kim M, Kang Y, Jang D (2007) Synthesis and characterization of highly luminescent CdS@ZnS core−shell nanorods. J Phys Chem C 111:18507–18511. https://doi.org/10.1021/jp075218nCrossRef

Kment S, Riboni F, Pausova S, Wang L, Wang L, Han H, Hubicka Z, Krysa J, Schmuki P, Zboril R (2017) Photoanodes based on TiO₂ and α-Fe₂O₃ for solar water splitting–superior role of 1D nanoarchitectures and of combined heterostructures. Chem Soc Rev 46:3716–3769. https://doi.org/10.1039/c6cs00015kCrossRef

Kudo I, Tsuji HK (2002) AgInZn₇S₉ solid solution photocatalyst for H₂ evolution from aqueous solutions under visible light irradiation. Chem Commun 17:1958–1959CrossRef

Lee J, Goda ES, Choi J, Park J, Lee S (2020) Synthesis and characterization of elution behavior of nonspherical gold nanoparticles in asymmetrical flow field-flow fractionation (AsFlFFF). J Nanopart Res 256:2–12. https://doi.org/10.1007/s11051-020-04987-4CrossRef

Li H, Cui Y, Hong W (2013) High photocatalytic performance of BioI/Bi₂WO₆ toward toluene and Reactive Brilliant Red. Appl Surf Sci 264:581–588. https://doi.org/10.1016/j.apsusc.2012.10.068CrossRef

Li H, Li W, Gu S, Wang F, Zhou H (2015) In-built Tb⁴⁺/Tb³⁺ redox centers in terbium-doped bismuth molybdate nanograss for enhanced photocatalytic activity. Catal Sci Technol 6(10):3510–3519. https://doi.org/10.1039/C5CY01730KCrossRef

Long T, Zhang Y, Zhong S (2018) Synthesis and photocatalytic activity of BiOCl/Bi₂Sn₂O₇ composite catalytic materials. Chinese Journal of Nonferrous Metals, 28, 2217–2213. https://doi.org/10.19476/j.ysxb.1004.0609.2018.11.06

Maczka M, Macalik L, Hermanowicz K, Kepinski L, Tomaszewski P (2010a) Phonon properties of nanosized bismuth layered ferroelectric material-Bi₂WO₆. J Raman Spectrosc 41:1059–1066. https://doi.org/10.1002/jrs.2526CrossRef

Maczka M, Macalik L, Hermanowicz K (2010b) Phonon properties of nanosized bismuth layered ferroelectric material-Bi₂WO₆. J Raman Spectrosc 41:1059–1066. https://doi.org/10.1002/jrs.2526CrossRef

Maczka M, Hanuza J, Paraguassu W, Souza AG, Freire PTC, Mendes J (2008) Phonons in ferroelectric Bi₂WO₆: Raman and infrared spectra and lattice dynamics. Appl Phys Lett, 92(11), 112911–112911–3. https://doi.org/10.1063/1.2896312

Pandit Bidhan, Goda Emad S, Abu Mahmoud H, Elella Aafaq Ur, Rehman Sang Eun, Hong Sachin R, Rondiya Pranay Barkataki, Shaikh Shoyebmohamad F, Al-Enizi Abdullah M, El-Bahy Salah M, Yoon Kuk Ro (2022) One-pot hydrothermal preparation of hierarchical manganese oxide nanorods for high-performance symmetric supercapacitors. J Energy Chem 65:116–126. https://doi.org/10.1016/j.jechem.2021.05.028CrossRef

Ren J, Wang W, Zhang L, Chang J, Hu S (2009) Photocatalytic inactivation of bacteria by photocatalyst Bi₂WO₆ under visible light. Catal Commun 10:940–1943. https://doi.org/10.1016/j.catcom.2009.07.006CrossRef

Sing K (1985) Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984). Pure Appl Chem 57:603–619. https://doi.org/10.1351/pac198557040603CrossRef

Sun S, Wang W, Zhang L, Zhou L, Yin W, Shang M (2009) Visible light-induced efficient contaminant removal by Bi₅O₇I. Environ Sci Technol 43:2005–2010. https://doi.org/10.1021/es8032814CrossRef

Tian Y, Zhang L, Zhang J (2012) A superior visible light-driven photocatalyst: europium-doped bismuth tungstate hierarchical microspheres. J Alloy Compd 537(1):24–28. https://doi.org/10.1016/j.jallcom.2012.05.029CrossRef

Tian J, Sang Y, Yu G, Jiang H, Mu X, Liu H (2013) A Bi₂WO₆-based hybrid photocatalyst with broad spectrum photocatalytic properties under UV, visible, and near-infrared irradiation. Adv Mater 25(36):5075–5080. https://doi.org/10.1002/adma.201370230CrossRef

Tian N, Zhang Y, Huang H, He Y, Guo Y (2014) Influences of Gd substitution on the crystal structure and visible-light-driven photocatalytic performance of Bi₂WO₆. J Phys Chem C 118:15640–15648. https://doi.org/10.1021/jp500645pCrossRef

Wang C, Zhang H, Li F, Zhu L (2010) Degradation and mineralization of bisphenol a by mesoporous Bi₂WO₆ under simulated solar light irradiation. Environ Sci Technol 44(17):6843–6848. https://doi.org/10.1021/es101890wCrossRef

Wang H, Song J, Zhang H, Gao F, Zhao S, Hu H (2012) Controlled synthesis of three-dimensional hierarchical Bi₂WO₆ microspheres with optimum photocatalytic activity. Mater Res Bull 47(2):315–320. https://doi.org/10.1016/j.materresbull.2011.11.017CrossRef

Wang F, Li W, Gu S, Li H, Liu X (2016) Samarium and nitrogen co-doped Bi₂WO₆ photocatalysts: synergistic effect of Sm³⁺/Sm²⁺ redox centers and N-doped level for enhancing visible-light photocatalytic activity. Chem a Eur J 22:12859–12867. https://doi.org/10.1002/chem.201602168CrossRef

Yuan Q, Chen L, Xiong M, He J, Luo SL, Au CT, Yin SF (2014) Cu₂O/BiVO₄ heterostructures: synthesis and application in simultaneous photocatalytic oxidation of organic dyes and reduction of Cr(VI) under visible light. Chem. Eng J 255:394–402. https://doi.org/10.1016/j.cej.2014.06.031CrossRef

Yue T et al (2011) Bismuth tungstate nano/microstructures: controllable morphologies, growth mechanism and photocatalytic properties. J Alloy Compd 509(3):724–730. https://doi.org/10.1016/j.jallcom.2010.09.010CrossRef

Zhang C, Zhu Y (2005) Synthesis of square Bi₂WO₆ nanoplates as high-activity visible-light-driven photocatalysts. Chem Mater 17:3537–3545. https://doi.org/10.1039/B204259BCrossRef

Zhang Z, Wang W, Yin W, Meng S, Lu W, Sun S (2010) Inducing photocatalysis by visible light beyond the absorption edge: effect of upconversion agent on the photocatalytic activity of Bi₂WO₆. Appl Catal B 101, 68-73. https://doi.org/10.1016/j.apcatb.2010.09.008

Zhang L, Wang H, Chen Z, Wong P, Liu J (2011) Bi₂WO₆ micro/nano-structures: synthesis, modifications and visible-light-driven photocatalytic applications. Appl Catal B 106:1–13. https://doi.org/10.1016/j.apcatb.2011.05.008CrossRef

Zhang J, Huang Z, Yong X, Kang F (2013) Hydrothermal synthesis of graphene/Bi₂WO₆ composite with high adsorptivity and photoactivity for azo dyes. J Am Chem Soc 96:1562–1569. https://doi.org/10.1111/jace.12261CrossRef

Zhang G, Ji S, Zhang Y, Wei Y (2017a) Facile synthesis of p-n heterojunction of phosphorus doped TiO₂ and BiOI with enhanced visible-light photocatalytic activity. Solid, State, Commun 259:34–39. https://doi.org/10.1016/j.ssc.2017.05.005CrossRef

Zhang J, Yuan X, Jiang L et al (2017b) Highly efficient photocatalysis toward tetracycline of nitrogen doped carbon quantum dots sensitized bismuth tungstate based on interfacial charge transfer. J Colloid Interface Sci 511:296–306. https://doi.org/10.1016/j.jcis.2017.09.083CrossRef

Zhao Y, Pan F, Li H, Zhao D, Liu L, Xu GQ et al (2013) Uniform mesoporous anatase-brookite biphase TiO₂ hollow spheres with high crystallinity via Ostwald ripening. J Phys Chem C 117:21718–21723. https://doi.org/10.1021/jp408322gCrossRef

Titel: Synthesis of La-doped Bi2WO6 to study on the removal of RhB wastewater under visible light
verfasst von: Zhi Li
XiaoMei Zhu
Hui Liu
Yu Liu
Tong Yu
Bing Sun
Publikationsdatum: 01.11.2021
Verlag: Springer Netherlands
Erschienen in: Journal of Nanoparticle Research / Ausgabe 11/2021
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-021-05360-9

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