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Journal of Polymer Research

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01.09.2022 | Original Paper

Synthesis, structural, morphological and optical analyses of new Prussian blue, ruthenium oxide and polyindole (PIn-PB-RuO₂) nanocomposite

verfasst von: Roshini Gunasekaran, Julie Charles

Erschienen in: Journal of Polymer Research | Ausgabe 9/2022

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Abstract

A novel ternary nanocomposite comprising of conducting polymer polyindole (PIn), prussian blue (PB) and ruthenium oxide (RuO₂), i.e., PIn-PB-RuO₂ nanocomposite is obtained through chemical method by grinding the as-synthesized PIn, PB and RuO₂ nanoparticles at the stoichiometric ratio of 1:1:1. FTIR, XRD, TGA, FESEM, EDAX, UV–Vis and PL techniques were applied to investigate the structure and optical properties of PIn-PB-RuO₂ nanocomposite. FTIR spectrum shows that the characteristic peaks present in all the unary nanoparticles are also present in the ternary nanocomposite with a small shift in the absorption maximum. The XRD pattern reveals the semicrystalline structure of PIn-PB-RuO₂ nanocomposite with an average crystallite size of 7.27 nm. The value of the intrinsic strain obtained for the ternary material from W–H plot is found to be 0.05466 × 10^–3. FESEM shows mixed morphological features as the surface of PB nanocubes is covered with a uniform level shagginess due to the presence of PIn and RuO₂ nanoparticles. EDAX reveals the presence of C, N, O, Fe, K and Ru elements in PIn-PB-RuO₂. Detailed UV–Vis spectroscopic analysis revealed that the ternary material showed an increase of extinction coefficient, refractive index, optical conductivity, Urbach energy and dielectric constant values compared to all the unary materials. The estimated bandgap of PIn-PB-RuO₂ indicates the material’s applicability in optoelectronic devices. Further, the blue emission peak from the PL results confirms that the PIn-PB-RuO₂ composite is highly suitable for visible light based device applications.

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Titel: Synthesis, structural, morphological and optical analyses of new Prussian blue, ruthenium oxide and polyindole (PIn-PB-RuO2) nanocomposite
verfasst von: Roshini Gunasekaran
Julie Charles
Publikationsdatum: 01.09.2022
Verlag: Springer Netherlands
Erschienen in: Journal of Polymer Research / Ausgabe 9/2022
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-022-03192-2

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