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Journal of Polymer Research

Erschienen in:

01.09.2022 | Original Paper

Polydiacetylene/organic magadiite nanocomposite film with stable reversible structure and reversible thermochromism

verfasst von: Mingliang Ge, Ziyu He, Zhaopeng Song

Erschienen in: Journal of Polymer Research | Ausgabe 9/2022

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Abstract

The composite with strong interaction force was prepared based on organic magadiite (OMAG) and polydiacetylene (PDA). Structural analyses indicate that γ-Aminopropyl triethoxysilane (KH550) acts as a bridge, connecting PDA and OMAG by electrostatic interactions and hydrogen bonding. Thus, PDA can be assembled on OMAG orderly, which allows the PDA-KH550-OMAG to have the properties of reversible dynamic structural changes during hot and cold conversion. It stands for reversible thermochromism. To fabricate the film with higher strength and good applicability, we polymerized nanocomposite film in carboxymethylcellulose matrix via simple preparation method. The film change from bluish purple to red when heated from 20 to 80 ℃, and normalized signal can can recover to 1.2 after ten heating cycles. The film persists in different organic solutions stably, expanding the application scope in harsh environments to become better smart sensing materials. Other coupling agents are difficult to achieve the same results, which further illustrates that amino plays an essential role in the reversible conformation of PDA chain.

Vorheriger Artikel Synthesis, structural, morphological and optical analyses of new Prussian blue, ruthenium oxide and polyindole (PIn-PB-RuO2) nanocomposite

Nächster Artikel Interfacial aggregation behavior of triblock terpolymers

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Titel: Polydiacetylene/organic magadiite nanocomposite film with stable reversible structure and reversible thermochromism
verfasst von: Mingliang Ge
Ziyu He
Zhaopeng Song
Publikationsdatum: 01.09.2022
Verlag: Springer Netherlands
Erschienen in: Journal of Polymer Research / Ausgabe 9/2022
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-022-03236-7

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