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Journal of Materials Science: Materials in Electronics
Erschienen in: Journal of Materials Science: Materials in Electronics 20/2018

22.08.2018

Systematic study of electronic properties of Fe-doped TiO2 nanoparticles by X-ray photoemission spectroscopy

verfasst von: Naglaa H. S. Nasralla, Mahboubeh Yeganeh, Yayuk Astuti, Sunthon Piticharoenphun, Lidija Šiller

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 20/2018

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Abstract

The importance of investigating the electronic structure of Fe doped TiO2 nanoparticles lies in understanding their various magnetic and optical applications. In this study Fe doped TiO2 nanoparticles were synthesized by sol–gel method in a wide range of Fe/Ti molar ratios (1, 3, 5, 8, and 10%) and post annealing at 400, 600 and 800 °C in air. The structure and size of nanoparticles were studied by X-ray diffraction and transmission electron microscopy, respectively. Systematic study of the existing states of Fe ions in Fe doped TiO2 and transformation of the existing states as a function of annealing temperature and Fe concentration were carried out utilizing high-resolution X-ray photoemission spectroscopy (XPS). The XPS results showed that Fe was present in all samples while Fe ions were detected in mixed valence (Fe2+ and Fe3+) states. The Fe3+ ions were dominant in the surface region of the nanoparticles. Moreover, the Ti in Fe:TiO2 nanoparticles was assigned to the Ti4+ while a small shift towards lower binding energies was observed upon increasing the annealing temperature and dopant level. This confirms the successful incorporation of Fe into TiO2, and the shifts in binding energies were attributed to the anatase to rutile transformation. The results verify that doping by Fe up to 10% do not exceed the limit of Fe substitutation into TiO2 lattice.
Vorheriger Artikel The effect of tantalum substitution on the microstructure and dielectric and piezoelectric properties of Pb0.99(Zr0.95Ti0.05)0.98Nb0.02O3 ceramics
Nächster Artikel Influence of Mg2SiO4 addition on crystal structure and microwave properties of Mg2Al4Si5O18 ceramic system

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Literatur
1.
C.E. McCold, Q. Fu, S. Hihath, J.M. Han, Y. Halfon, R. Faller, K. van Benthem, L. Zang, J. Hihath, Ligand exchange based molecular doping in 2D hybrid molecule-nanoparticle arrays: length determines exchange efficiency and conductance change. Mol. Syst. Des. Eng. 2, 440–448 (2017)CrossRef
2.
B.M. Reddy, I. Ganesh, A. Khan, Stabilization of nanosized titania-anatase for high temperature catalytic applications. J. Mol. Catal. A 223, 295–304 (2004)CrossRef
3.
W.Y. Choi, A. Termin, M.R. Hoffmann, The role of metal ion dopants in quantum-sized TiO2: correlation between photoreactivity and charge carrier recombination dynamics. J. Phys. Chem. 84, 13669–13679 (1994)CrossRef
4.
M. Yeganeh, N. Shahtahmasebi, A. Kompany, M. Karimipour, F. Razavi, N.H.S. Nasralla, L. Šiller, The magnetic characterization of Fe doped TiO2 semiconducting oxide nanoparticles synthesized by sol-gel method. Phys. B 511, 89–98 (2017)CrossRef
5.
J.F. Zhu, W. Zheng, B. He, J.L. Zhang, M. Anpo, Characterization of Fe-TiO2 photocatalysts synthesized by hydrothermal method and their photocatalytic reactivity for photodegradation of XRG dye diluted in water. J. Mol. Catal. A 216, 35–43 (2004)CrossRef
6.
S. Liu, Y.C.X. Liu, R. Jiang, A novel preparation of highly active iron-doped titania photocatalysts with a p–n junction semiconductor structure. J. Alloys Compd. 506, 877–882 (2010)CrossRef
7.
J. Zhu, F. Chen, J. Zhang, H. Chen, M. Anpo, Fe3+-TiO2 photocatalysts prepared by combining sol-gel method with hydrothermal treatment and their characterization. J. Photochem. Photobiol. A 180, 196–204 (2006)CrossRef
8.
Y. Matsumoto, M. Murakami, T. Shono, T. Hasegawa, T. Fukumura, M. Kawasaki, P. Ahmet, T. Chikyow, S.Y. Koshihara, H. Koinuma, Room-temperature ferromagnetism in transparent transition metal-doped titanium dioxide. Science 291, 854–856 (2001)CrossRef
9.
M. Crisan, M. Raileanu, N. Dragan, D. Crisan, A. Ianculescu, I. Nitoi, P. Oancea, S. Somacescu, N. Stanica, B. Vasile, C. Stan, Sol-gel iron-doped TiO2 nanopowders with photocatalytic activity. Appl. Catal. A 504, 130–142 (2015)CrossRef
10.
J. Yan, G. Wu, N. Guan, L. Li, Z. Li, X. Cao, Understanding the effect of surface/bulk defects on the photocatalytic activity of TiO2: anatase versus rutile. Phys. Chem. Chem. Phys. 15, 10978–10988 (2013)CrossRef
11.
B. Santara, P.K. Giri, S. Dhara, K. Imakita, M. Fujii, Oxygen vacancy-mediated enhanced ferromagnetism in undoped and Fe-doped TiO2 nanoribbons. J. Phys. D 47, 235304 (2014)CrossRef
12.
I. Ganesh, P.P. Kumar, A.K. Gupta, P.S.C. Sekhar, K. Radha, G. Padmanabham, G. Sundararajan, Preparation and characterization of Fe-doped TiO2 powders for solar light response and photocatalytic applications. Process. Appl. Ceram. 6, 21–36 (2012)CrossRef
13.
S. Zhu, W. Liu, C. Fan, Y. Li, Mössbauer study of nano-TiO2 doped with Fe. Hyperfine Interact. 165, 273–278 (2005)CrossRef
14.
S.K.S. Patel, S. Kurian, N.S. Gajbhiye, Room-temperature ferromagnetism of Fe-doped TiO2 nanoparticles driven by oxygen vacancy. Mater. Res. Bull. 48, 655–660 (2013)CrossRef
15.
Q. Wu, Q. Zheng, R. Krol, Creating oxygen vacancies as a novel strategy to form tetrahedrally coordinated Ti4+ in Fe/TiO2 nanoparticles. J. Phys. Chem. C 116, 7219–7226 (2012)CrossRef
16.
T. Ali, P. Tripathi, A. Azam, W. Raza, A.S. Ahmed, A. Ahmed, M. Muneer, Photocatalytic performance of Fe-doped TiO2 nanoparticles under visible-light irradiation. Mater. Res. Express 4, 015022 (2017)CrossRef
17.
H. Moradi, A. Eshaghi, S.R. Hosseini, K. Ghani, Fabrication of Fe-doped TiO2 nanoparticles and investigation of photocatalytic decolorization of reactive red 198 under visible light irradiation. Ultrason. Sonochem. 32, 314–319 (2016)CrossRef
18.
A.N. Mangham, N. Govind, M.E. Bowden, V. Shutthanandan, A.G. Joly, M.A. Henderson, S.A. Chambers, Photochemical properties, composition, and structure in molecular beam epitaxy grown Fe “doped” and (Fe,N) codoped rutile TiO2 (110). J. Phys. Chem. C 115, 15416–15424 (2011)CrossRef
19.
N.D. Abazovic, L. Mirenghi, I.A. Jankovic, N. Bibic, D.V. Šojic, B.F. Abramovic, M. Comor, Synthesis and characterization of rutile TiO2 nanopowders doped with iron ions. Nanoscale Res. Lett. 4, 518–525 (2009)CrossRef
20.
P. Esparza, T. Hernández, M.E. Borges, M.C. Álvarez-Galván, J.C. Ruiz-Morales, J.L.G. Fierro, TiO2 modifications by hydrothermal treatment and doping to improve its photocatalytic behaviour under visible light. Catal. Today 210, 135–141 (2013)CrossRef
21.
L.Y. Zhu, X.T. Liu, W.W. Qin, X.S. Liu, N.N. Cai, X.Q. Wang, X.J. Lin, G.H. Zhang, D. Xu, Preparation, characterization and electronic structures of Fe-doped TiO2 nanostructured fibers. Mater. Res. Bull. 48, 2737–2745 (2013)CrossRef
22.
A.B. Grosvenor, B.A. Kobe, M.C. Biesinger, N.S. Mclntyre, Investigation of multiplet splitting of Fe 2p XPS spectra and bonding in iron compounds. Surf. Interface Anal. 36, 1564–1574 (2004)CrossRef
23.
M. Mullet, V. Khare, C. Ruby, XPS study of Fe(II) Fe(III)(oxy) hydroxycarbonate green rust compounds. Surf. Interface Anal. 40, 323–328 (2008)CrossRef
24.
Y. Wu, J. Zhang, L. Xiao, F. Chen, Properties of carbon and iron modified TiO2 photocatalyst synthesized at low temperature and photodegradation of acid orange 7 under visible light. Appl. Surf. Sci. 256, 4260–4268 (2010)CrossRef
25.
J. Yu, Q. Xiang, M. Zhou, Preparation, characterization and visible-light-driven photocatalytic activity of Fe-doped titania nonorods and first-principles study of electronic structures. Appl. Catal. B 90, 595–602 (2009)CrossRef
26.
J. Zhang, X. Chen, Y. Shen, Y. Li, Z. Hu, J. Chu, Synthesis, surface morphology, and photoluminescence properties of anatase iron-doped titanium dioxide nano-crystalline films. Phys. Chem. Chem. Phys. 13, 13096–13105 (2011)CrossRef
27.
E. McCafferty, J.P. Wightman, Determination of the concentration of surface hydroxyl groups on metal oxide films by a quantitative XPS method. Surf. Interface Anal. 26, 549–564 (1998)CrossRef
28.
S. Doniach, M. Šunjic, Many-electron singularity in X-ray photoemission and X-ray line spectra from metals. J. Phys. C 3, 285 (1970)CrossRef
29.
J. Di’az, G. Paolicelli, S. Ferrer, F. Comin, Separation of the sp3 and sp2 components in the C 1s photoemission spectra of amorphous carbon films. Phys. Rev. B 54, 8064 (1996)CrossRef
30.
D.A. Shirley, High-resolution X-ray photoemission spectrum of the valence bands of gold. Phys. Rev. B 5, 4709 (1972)CrossRef
31.
Q. Fu, J. Chen, C. Shi, D. Ma, Room-temperature sol–gel derived molybdenum oxide thin films for efficient and stable solution-processed organic light-emitting diodes. ACS Appl. Mater. Interfaces 5(13), 6024–6029 (2013)CrossRef
32.
J.F. Moudler, W.F. Stickle, P.E. Sobol, K.D. Bomben, Handbook of X-ray Photoelectron Spectroscopy (Perkin-Elmer Corp, Eden Prairie, 1992)
33.
J.T. Mayer, U. Diebold, T.E. Madey, E. Garfunkel, Titanium and reduced titania overlayers on titanium dioxide (110). J. Electron Spectrosc. Relat. Phenom. 73, 1–11 (1995)CrossRef
34.
U. Diebold, The surface science of titanium dioxide. Surf. Sci. Rep. 48, 53–229 (2003)CrossRef
35.
D.A.H. Hanaor, I. Chironi, I. Karatchevtseva, G. Traini, C.C. Sorrell, Single and mixed phase TiO2 powders prepared by excess hydrolysis of titanium alkoxide. Adv. Appl. Ceram. 111, 149–158 (2012)CrossRef
36.
E.A. Kozlova, T.P. Korobkina, A.V. Vorontsov, V.N. Parmon, Enhancement of the O2 or H2 photoproduction rate in a Ce3+/Ce4+-TiO2 system by the TiO2 surface and structure modification. Appl. Catal. A 367, 130–137 (2009)CrossRef
37.
J.F. Porter, Y.G. Li, C.K. Chan, The effect of calcination on the microstructural characteristics and photoreactivity of Degussa P-25 TiO2. J. Mater. Sci. 34, 1535–1545 (1999)CrossRef
38.
N.L. Wu, M.S. Lee, Z.J. Pon, J.Z. Hsu, Effect of calcination atmosphere on TiO2 photocatalysis in hydrogen production from methanol/water solution. J. Photochem. Photobiol. A 163, 277–280 (2004)CrossRef
39.
P.R. Ettireddy, N. Ettireddy, S. Mamedov, P. Boolchand, P.G. Smirniotis, Surface characterization studies of TiO2 supported manganese oxide catalysts for low temperature SCR of NO with NH3. Appl. Catal. B 76, 123–134 (2007)CrossRef
40.
X. Weimiao, C. Hui, Z. Xuanhui, H. Xianchao, L. Guohua, Preparation and photocatalytic activity of rutile TiO2 and goethite composite photocatalysts. Chin. J. Catal. 34, 1076–1086 (2013)CrossRef
41.
J.T. Kloprogge, L.V. Duong, B.J. Wood, R.L. Frost, J. Colloid Interface Sci. 296, 572–576 (2006)CrossRef
42.
F.F.H. Aragon, J.D. Ardisson, J.C.R. Aquino, I. Gonzalez, W.A.A. Macedo, J.A.H. Coaquira, J. Mantilla, S.W.D. Silva, P.C. Morais, Effect of the thickness reduction on the structural, surface and magnetic properties of α-Fe2O3 thin films. Thin Solid Films 607, 50–54 (2016)CrossRef
43.
J.T. Carneiro, T.J. Savenije, J.A. Moulijn, G. Mul, Toward a physically sound structure—activity relationship of TiO2-based photocatalysts. J. Phys. Chem. C 114, 327–332 (2010)CrossRef
44.
M. Hirano, T. Joji, M. Inagaki, H. Iwata, Direct formation of iron(III)-doped titanium oxide (anatase) by thermal hydrolysis and its structure property. J. Am. Ceram. Soc. 87, 35–41 (2004)CrossRef
45.
J. Yu, M. Zhou, H. Yu, Q. Zhang, Y. Yu, Enhanced photoinduced super-hydrophilicity of the sol–gel-derived TiO2 thin films by Fe-doping. Mater. Chem. Phys. 95, 193–196 (2006)CrossRef
46.
C.C. Yen, D.Y. Wang, L.S. Chang, H.C. Shih, Characterization and photocatalytic activity of Fe- and N-co-deposited TiO2 and first-principles study for electronic structure. J. Solid State Chem. 184, 2053–2060 (2011)CrossRef
47.
M. Muhler, R. Schlogl, G. Ertl, The nature of the iron oxide-based catalyst for dehydrogenation of ethylbenzene to styrene 2. Surface chemistry of the active phase. J. Catal. 138, 413–444 (1992)CrossRef
48.
N.N. Greenwood, A. Earnshaw, Chemistry of the Elements, 2nd edn. (Butterworth-Heinemann, Amsterdam, 1997)
49.
V.E. Heinrich, P.A. Cox, The Surface Science of Metal Oxides (Cambridge University Press, Cambridge, 1994)
50.
T. Tong, J. Zhang, B. Tian, F. Chen, D. He, Preparation of Fe3+-doped TiO2 catalysts by controlled hydrolysis of titanium alkoxide and study on their photocatalytic activity for methyl orange degradation. J. Hazard. Mater. 155, 572–579 (2008)CrossRef
51.
H.W. Nesbitt, I.J. Muir, X-ray photoelectron spectroscopic study of a pristine pyrite surface reacted with water vapour and air. Geochim. Cosmochim. Acta 58, 4667–4679 (1994)CrossRef
52.
T. Droubay, S.A. Chambers, Surface-sensitive Fe 2p photoemission spectra for α-Fe2O3(0001): the influence of symmetry and crystal-field strength. Phys. Rev. B 64, 205414 (2001)CrossRef
53.
S. Hüfner, Photoelectron Spectroscopy: Principles and Applications (Springer, Berlin, 2003)CrossRef
54.
J.M.D. Coey, M. Venkatesan, C.B. Fitzgerald, Donor impurity band exchange in dilute ferromagnetic oxides. Nat. Mater. 4, 173–179 (2005)CrossRef
Metadaten
Titel
Systematic study of electronic properties of Fe-doped TiO2 nanoparticles by X-ray photoemission spectroscopy
verfasst von
Naglaa H. S. Nasralla
Mahboubeh Yeganeh
Yayuk Astuti
Sunthon Piticharoenphun
Lidija Šiller
Publikationsdatum
22.08.2018
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 20/2018
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-018-9911-5

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