Skip to main content
Erschienen in: Wood Science and Technology 2/2017

01.10.2016 | Original

Tartaric acid catalyzed furfurylation of beech wood

verfasst von: Prabu Satria Sejati, Aurélia Imbert, Christine Gérardin-Charbonnier, Stéphane Dumarçay, Emmanuel Fredon, Eric Masson, Dodi Nandika, Trisna Priadi, Phillipe Gérardin

Erschienen in: Wood Science and Technology | Ausgabe 2/2017

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

European beech (Fagus sylvatica L.) is a major tree species of European forest which is underexploited because of its low dimensional stability and durability. Similarly to what has been developed with radiata pine, furfurylation might be the answer to optimize the utilization of local beech wood. Beech wood furfurylation process was studied using five different catalysts: maleic anhydride, maleic acid, citric acid, itaconic acid, and tartaric acid. Optimization of the furfurylation process was investigated for different catalyst and furfuryl alcohol (FA) contents, and different duration of polymerization. The following properties were studied: weight percent gain (WPG), leachability, anti-swelling efficiency (ASE), wettability, modulus of elasticity, modulus of rupture, Brinell hardness, and decay durability. Tartaric acid, never investigated up to now, was retained as catalyst to perform furfurylation due to its efficacy compared to other catalysts and its novelty. Wood modification with FA and tartaric acid as catalyst led to samples with high WPG even after leaching, improved ASE, and lower wettability with water. Increasing the polymerization duration increased the fixation of FA in treated wood. Most of all, treatment gave a significant improvement in mechanical properties and resistance to wood decaying fungi.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Literatur
Zurück zum Zitat Barr JB, Wallon SB (1971) The chemistry of furfuryl alcohol resins preparation of resin. J Appl Polym Sci 15:1079–1090CrossRef Barr JB, Wallon SB (1971) The chemistry of furfuryl alcohol resins preparation of resin. J Appl Polym Sci 15:1079–1090CrossRef
Zurück zum Zitat Baysal E, Ozaki SK, Yalinkilic MK (2004) Dimensional stabilization of wood treated with furfuryl alcohol catalysed by borates. Wood Sci Technol 38:405–415 Baysal E, Ozaki SK, Yalinkilic MK (2004) Dimensional stabilization of wood treated with furfuryl alcohol catalysed by borates. Wood Sci Technol 38:405–415
Zurück zum Zitat Bryne LE, Walinder MEP (2010) Ageing of modified wood. Part 1: wetting properties of acetylated, furfurylated, and thermally modified wood. Holzforschung 64:295–304 Bryne LE, Walinder MEP (2010) Ageing of modified wood. Part 1: wetting properties of acetylated, furfurylated, and thermally modified wood. Holzforschung 64:295–304
Zurück zum Zitat Ducoroy L, Martel B, Bacquet B, Morcellet M (2007) Ion exchange textiles from the finishing of PET fabrics with cyclodextrins and citric acid for the sorption of metallic cations in water. J Incl Phenom Macrocycl Chem 57:271–277CrossRef Ducoroy L, Martel B, Bacquet B, Morcellet M (2007) Ion exchange textiles from the finishing of PET fabrics with cyclodextrins and citric acid for the sorption of metallic cations in water. J Incl Phenom Macrocycl Chem 57:271–277CrossRef
Zurück zum Zitat Engonga PE, Schneider R, Gerardin P, Loubinoux B (1999) Chemical modification of wood with perfluoroalkyl ethanol and 4,4′-diphenylmethane diisocyanate. Holzforschung 53:272–276CrossRef Engonga PE, Schneider R, Gerardin P, Loubinoux B (1999) Chemical modification of wood with perfluoroalkyl ethanol and 4,4′-diphenylmethane diisocyanate. Holzforschung 53:272–276CrossRef
Zurück zum Zitat Engonga PE, Schneider R, Gerardin P, Loubinoux B (2000) Preparation and dimensional stability of wood grafted with alkyl chains. Holz Roh- Werkst 58:284–286CrossRef Engonga PE, Schneider R, Gerardin P, Loubinoux B (2000) Preparation and dimensional stability of wood grafted with alkyl chains. Holz Roh- Werkst 58:284–286CrossRef
Zurück zum Zitat Epmeier H, Westin M, Rapp A (2004) Differently modified wood: comparison of some selected properties. Scand J For Res 19:31–37CrossRef Epmeier H, Westin M, Rapp A (2004) Differently modified wood: comparison of some selected properties. Scand J For Res 19:31–37CrossRef
Zurück zum Zitat Epmeier H, Johansson M, Kliger R, Westin M (2007) Material properties and their interrelation in chemically modified clear wood of Scots pine. Holzforschung 61:34–42CrossRef Epmeier H, Johansson M, Kliger R, Westin M (2007) Material properties and their interrelation in chemically modified clear wood of Scots pine. Holzforschung 61:34–42CrossRef
Zurück zum Zitat Esteves B, Nunes L, Pereira H (2011) Properties of furfurylated wood (Pinus pinaster). Eur J Wood Prod 69:521–525CrossRef Esteves B, Nunes L, Pereira H (2011) Properties of furfurylated wood (Pinus pinaster). Eur J Wood Prod 69:521–525CrossRef
Zurück zum Zitat Gandini A (2013) The furan/maleimide Diels-Alder reaction: a versatile click-unclick tool in macromolecular synthesis. Prog Polym Sci 38:1–29CrossRef Gandini A (2013) The furan/maleimide Diels-Alder reaction: a versatile click-unclick tool in macromolecular synthesis. Prog Polym Sci 38:1–29CrossRef
Zurück zum Zitat Gascon-Garrido P, Oliver-Villanueva JV, Ibiza-Palacios MS, Militz H, Mai C, Adamopoulos S (2013) Resistance of wood modified with different technologies against Mediterranean termites (Reticulitermes spp.). Int Biodeterior Biodegrad 82:13–16CrossRef Gascon-Garrido P, Oliver-Villanueva JV, Ibiza-Palacios MS, Militz H, Mai C, Adamopoulos S (2013) Resistance of wood modified with different technologies against Mediterranean termites (Reticulitermes spp.). Int Biodeterior Biodegrad 82:13–16CrossRef
Zurück zum Zitat Goldstein IS, Dreher WA (1960) Stable furfuryl alcohol impregnating solutions. Ind Eng Chem 52:57–58CrossRef Goldstein IS, Dreher WA (1960) Stable furfuryl alcohol impregnating solutions. Ind Eng Chem 52:57–58CrossRef
Zurück zum Zitat Hadi YS, Westin M, Rasyid E (2005) Resistance of furfurylated wood to termite attack. For Prod J 55:85–88 Hadi YS, Westin M, Rasyid E (2005) Resistance of furfurylated wood to termite attack. For Prod J 55:85–88
Zurück zum Zitat Hill C (2006) Wood modification chemical, thermal and other processes. John, ChichesterCrossRef Hill C (2006) Wood modification chemical, thermal and other processes. John, ChichesterCrossRef
Zurück zum Zitat Lande S, Eikenes M, Westin M (2004a) Chemistry and ecotoxicology of furfurylated wood. Scand J For Res 19:14–21CrossRef Lande S, Eikenes M, Westin M (2004a) Chemistry and ecotoxicology of furfurylated wood. Scand J For Res 19:14–21CrossRef
Zurück zum Zitat Lande S, Westin M, Schneider M (2004b) Properties of furfurylated wood. Scand J For Res 19:22–30CrossRef Lande S, Westin M, Schneider M (2004b) Properties of furfurylated wood. Scand J For Res 19:22–30CrossRef
Zurück zum Zitat Lande S, Westin M, Schneider M (2008) Development of modified wood products based on furan chemistry. Mol Cryst Liq Cryst 484:367–378CrossRef Lande S, Westin M, Schneider M (2008) Development of modified wood products based on furan chemistry. Mol Cryst Liq Cryst 484:367–378CrossRef
Zurück zum Zitat Li Y, Wu Q, Li J, Liu Y, Wang XM, Liu Z (2012) Improvement of dimensional stability of wood via combination treatment: swelling with maleic anhydride and grafting with glycidyl methacrylate and methyl methacrylate. Holzforschung 66:59–66 Li Y, Wu Q, Li J, Liu Y, Wang XM, Liu Z (2012) Improvement of dimensional stability of wood via combination treatment: swelling with maleic anhydride and grafting with glycidyl methacrylate and methyl methacrylate. Holzforschung 66:59–66
Zurück zum Zitat Li W, Wang H, Ren D, Yu YS, Yu Y (2015) Wood modification with furfuryl alcohol catalysed by a new composite acidic catalyst. Wood Sci Technol 49:845–856CrossRef Li W, Wang H, Ren D, Yu YS, Yu Y (2015) Wood modification with furfuryl alcohol catalysed by a new composite acidic catalyst. Wood Sci Technol 49:845–856CrossRef
Zurück zum Zitat Militz H, Lande S (2009) Challenges in wood modification technology on the way to practical applications. Wood Mater Sci Eng 4:23–29CrossRef Militz H, Lande S (2009) Challenges in wood modification technology on the way to practical applications. Wood Mater Sci Eng 4:23–29CrossRef
Zurück zum Zitat Nordstierna L, Lande S, Westin M, Karlsson O, Furo I (2008) Towards novel wood-based materials: chemical bonds between lignin-like model molecules and poly(furfuryl alcohol) studied by NMR. Holzforschung 62:709–713CrossRef Nordstierna L, Lande S, Westin M, Karlsson O, Furo I (2008) Towards novel wood-based materials: chemical bonds between lignin-like model molecules and poly(furfuryl alcohol) studied by NMR. Holzforschung 62:709–713CrossRef
Zurück zum Zitat Pfriem A, Dietrich T, Buchelt B (2012) Furfuryl alcohol impregnation for improved plasticization and fixation during the densification of wood. Holzforschung 66:215–218CrossRef Pfriem A, Dietrich T, Buchelt B (2012) Furfuryl alcohol impregnation for improved plasticization and fixation during the densification of wood. Holzforschung 66:215–218CrossRef
Zurück zum Zitat Pilgard A, Alfredsen G (2009) A better understanding of the mode of action of furfurylated wood. In: Bergstedt A (ed) Proceedings of the 5th meeting of the Nordic-Baltic Network in Wood Material Science and Engineering (WSE). Forest & Landscape Denmark University of Copenhagen, Copenhagen, pp 13–20 Pilgard A, Alfredsen G (2009) A better understanding of the mode of action of furfurylated wood. In: Bergstedt A (ed) Proceedings of the 5th meeting of the Nordic-Baltic Network in Wood Material Science and Engineering (WSE). Forest & Landscape Denmark University of Copenhagen, Copenhagen, pp 13–20
Zurück zum Zitat Pilgard A, Treu A, Van Zeeland ANT, Gosselink RJA, Westin M (2010) Toxic hazard and chemical analysis of leachates from furfurylated wood. Environ Toxicol Chem 29:1918–1924PubMed Pilgard A, Treu A, Van Zeeland ANT, Gosselink RJA, Westin M (2010) Toxic hazard and chemical analysis of leachates from furfurylated wood. Environ Toxicol Chem 29:1918–1924PubMed
Zurück zum Zitat Rowell RM, Ellis WD (1978) Determination of dimensional stabilization of wood using the water-soak method. Wood Sci 13:104–111 Rowell RM, Ellis WD (1978) Determination of dimensional stabilization of wood using the water-soak method. Wood Sci 13:104–111
Zurück zum Zitat Schneider MH (1995) New cell wall and cell lumen wood polymer composites. Wood Sci Technol 29:121–127CrossRef Schneider MH (1995) New cell wall and cell lumen wood polymer composites. Wood Sci Technol 29:121–127CrossRef
Zurück zum Zitat Silva DE (2010) Ecologie du Hêtre (Fagus sylvatica L.) en Marge Sud-Ouest de Son Aire de Distribution. (Beech ecology (Fagus sylvatica L.) in Southwest margin of its distribution area) (in French). Thesis, Université Henri Poincaré, Nancy I, 193 p. + annexes Silva DE (2010) Ecologie du Hêtre (Fagus sylvatica L.) en Marge Sud-Ouest de Son Aire de Distribution. (Beech ecology (Fagus sylvatica L.) in Southwest margin of its distribution area) (in French). Thesis, Université Henri Poincaré, Nancy I, 193 p. + annexes
Zurück zum Zitat Temiz A, Terziev N, Eikenes M, Hafren J (2007) Effect of accelerated weathering on surface chemistry of modified wood. Appl Surf Sci 253:5355–5362CrossRef Temiz A, Terziev N, Eikenes M, Hafren J (2007) Effect of accelerated weathering on surface chemistry of modified wood. Appl Surf Sci 253:5355–5362CrossRef
Zurück zum Zitat Thygesen LG, Barsberg S, Venas TM (2010) The fluorescence characteristics of furfurylated wood studied by fluorescence spectroscopy and confocal laser scanning microscopy. Wood Sci Technol 44:51–65CrossRef Thygesen LG, Barsberg S, Venas TM (2010) The fluorescence characteristics of furfurylated wood studied by fluorescence spectroscopy and confocal laser scanning microscopy. Wood Sci Technol 44:51–65CrossRef
Zurück zum Zitat Treu A, Pilglard A, Puttmann S, Krause A, Westin M (2009) Material properties of furfurylated wood for window production. In: 40th annul meeting, international research group on wood protection, Beijing, pp 1–13 Treu A, Pilglard A, Puttmann S, Krause A, Westin M (2009) Material properties of furfurylated wood for window production. In: 40th annul meeting, international research group on wood protection, Beijing, pp 1–13
Zurück zum Zitat Venas TM, Rinnan A (2008) Determination of weight percent gain in solid wood modified with in situ cured furfuryl alcohol by near-infrared reflectance spectroscopy. Chemom Intell Lab Syst 92:125–130CrossRef Venas TM, Rinnan A (2008) Determination of weight percent gain in solid wood modified with in situ cured furfuryl alcohol by near-infrared reflectance spectroscopy. Chemom Intell Lab Syst 92:125–130CrossRef
Zurück zum Zitat Walinder MEP (2000) Wetting phenomena on wood, factors influencing measurements of wood wettability. KTH-Royal Institute of Technology, Stockholm Walinder MEP (2000) Wetting phenomena on wood, factors influencing measurements of wood wettability. KTH-Royal Institute of Technology, Stockholm
Zurück zum Zitat Westin M, Rapp A, Nilsson T (2006) Field test of resistance of modified wood to marine borers. Wood Mater Sci Eng 1:34–38CrossRef Westin M, Rapp A, Nilsson T (2006) Field test of resistance of modified wood to marine borers. Wood Mater Sci Eng 1:34–38CrossRef
Zurück zum Zitat Wewerka EM (1968) Investigation of the polymerization of furfuryl alcohol with gel permeation chromatography. J Appl Polym Sci 12:1671–1681CrossRef Wewerka EM (1968) Investigation of the polymerization of furfuryl alcohol with gel permeation chromatography. J Appl Polym Sci 12:1671–1681CrossRef
Zurück zum Zitat Xie Y, Fu Q, Wang Q, Militz H (2013) Effects of chemical modification on the mechanical properties of wood. Eur J Wood Prod 71:401–416CrossRef Xie Y, Fu Q, Wang Q, Militz H (2013) Effects of chemical modification on the mechanical properties of wood. Eur J Wood Prod 71:401–416CrossRef
Metadaten
Titel
Tartaric acid catalyzed furfurylation of beech wood
verfasst von
Prabu Satria Sejati
Aurélia Imbert
Christine Gérardin-Charbonnier
Stéphane Dumarçay
Emmanuel Fredon
Eric Masson
Dodi Nandika
Trisna Priadi
Phillipe Gérardin
Publikationsdatum
01.10.2016
Verlag
Springer Berlin Heidelberg
Erschienen in
Wood Science and Technology / Ausgabe 2/2017
Print ISSN: 0043-7719
Elektronische ISSN: 1432-5225
DOI
https://doi.org/10.1007/s00226-016-0871-8

Weitere Artikel der Ausgabe 2/2017

Wood Science and Technology 2/2017 Zur Ausgabe