Skip to main content
Erschienen in: Metallurgical and Materials Transactions A 7/2012

01.07.2012

The Inhibition of Hydrogen Embrittlement in SAE 4340 Steel in an Aqueous Environment with the Rare Earth Compound Lanthanum 4 Hydroxy Cinnamate

verfasst von: B. R. W. Hinton, M. Behrouzvaziri, M. Forsyth, R. K. Gupta, M. Seter, P. G. Bushell

Erschienen in: Metallurgical and Materials Transactions A | Ausgabe 7/2012

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

A preliminary study showed that the inhibitor lanthanum 4-hydroxy cinnamate ((La4OHcin)3) at a concentration of 400 ppm prevented the hydrogen embrittlement (HE) of SAE 4340 steel tensile specimens when tested under slow strain rate conditions in a 0.01M NaCl. In the presence of the inhibitor, a complex film formed on the surface of specimens during the slow strain rate test (SSRT), and no corrosion pits were detected. Electrochemical polarization studies indicated that the La(4OHcin)3 acted as an anodic inhibitor in the NaCl solution. This article also discusses the mechanism of HE inhibition by La(4OHcin)3.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Fußnoten
1
LACOMIT is a trademark of W. Canning & Co Ltd, Sheffield, UK.
 
2
JEOL is a trademark of Japan Electron Optics Ltd., Tokyo.
 
Literatur
1.
2.
Zurück zum Zitat B.R.W. Hinton, D.A. Arnott, and N.E. Ryan: Met. Forum, 1984, vol. 7 (4), pp. 211–12. B.R.W. Hinton, D.A. Arnott, and N.E. Ryan: Met. Forum, 1984, vol. 7 (4), pp. 211–12.
3.
Zurück zum Zitat B.R.W. Hinton: J. Alloys Compd., 1992, vol. 180 (1–2), pp. 15–25.CrossRef B.R.W. Hinton: J. Alloys Compd., 1992, vol. 180 (1–2), pp. 15–25.CrossRef
4.
Zurück zum Zitat B.R.W. Hinton: Corrosion 89, NACE, New Orleans, LA, 1989, paper no. 170. B.R.W. Hinton: Corrosion 89, NACE, New Orleans, LA, 1989, paper no. 170.
5.
Zurück zum Zitat B.R.W. Hinton, P.N. Trathen, L. Wilson, and N.E. Ryan: 28th Ann. Conf. of Australasian Corrosion Association, Perth, 1988, Australasian Corrosion Association, Perth, Australia, 1988. B.R.W. Hinton, P.N. Trathen, L. Wilson, and N.E. Ryan: 28th Ann. Conf. of Australasian Corrosion Association, Perth, 1988, Australasian Corrosion Association, Perth, Australia, 1988.
6.
Zurück zum Zitat A.D. Mercer: Proc. 5th Eur. Symp. on Corrosion Inhibitors, Ferrara, Italy, 1980. A.D. Mercer: Proc. 5th Eur. Symp. on Corrosion Inhibitors, Ferrara, Italy, 1980.
7.
Zurück zum Zitat F. Blin, P. Koutsoukos, P. Klepetsianis, and M. Forsyth: Electrochim. Acta, 2007, vol. 52 (21), pp. 6212–20.CrossRef F. Blin, P. Koutsoukos, P. Klepetsianis, and M. Forsyth: Electrochim. Acta, 2007, vol. 52 (21), pp. 6212–20.CrossRef
8.
Zurück zum Zitat F. Blin, S.G. Leary, G.B. Deacon, P.C. Junk, and M. Forsyth: Corrosion & Prevention 04 2004, Perth, Australia, Nov. 21–24, 2004, Australasian Corrosion Association, Perth, Australia. F. Blin, S.G. Leary, G.B. Deacon, P.C. Junk, and M. Forsyth: Corrosion & Prevention 04 2004, Perth, Australia, Nov. 21–24, 2004, Australasian Corrosion Association, Perth, Australia.
9.
Zurück zum Zitat F. Blin, S.G. Leary, G.B. Deacon, P.C. Junk, and M. Forsyth: Corros. Sci., 2006, vol. 48 (2), pp. 404–19.CrossRef F. Blin, S.G. Leary, G.B. Deacon, P.C. Junk, and M. Forsyth: Corros. Sci., 2006, vol. 48 (2), pp. 404–19.CrossRef
10.
Zurück zum Zitat Corrosion Control & NDT Conf., Melbourne, 2003, F. Blin, S.G. Leary, K. Wilson, G.B. Deacon, P.C. Junk, and M. Forsyth, eds., Australasian Corrosion Association, Melbourne, Australia. Corrosion Control & NDT Conf., Melbourne, 2003, F. Blin, S.G. Leary, K. Wilson, G.B. Deacon, P.C. Junk, and M. Forsyth, eds., Australasian Corrosion Association, Melbourne, Australia.
11.
Zurück zum Zitat F. Blin, S.G. Leary, K. Wilson, G.B. Deacon, P.C. Junk, and M. Forsyth: J. Appl. Electrochem., 2004, pp. 591–99. F. Blin, S.G. Leary, K. Wilson, G.B. Deacon, P.C. Junk, and M. Forsyth: J. Appl. Electrochem., 2004, pp. 591–99.
12.
Zurück zum Zitat M. Forsyth, K. Wilson, T. Behrsing, C. Forsyth, G. Deacon, and A. Phansogoankar: Corrosion, 2002, vol. 58 (11), pp. 953–60.CrossRef M. Forsyth, K. Wilson, T. Behrsing, C. Forsyth, G. Deacon, and A. Phansogoankar: Corrosion, 2002, vol. 58 (11), pp. 953–60.CrossRef
13.
Zurück zum Zitat M. Behrouzvaziri, B.R.W. Hinton, and M. Forsyth: Corrosion and Prevention 2008, Wellington, New Zealand, Nov. 2008, Australasian Corrosion Association, Australia. M. Behrouzvaziri, B.R.W. Hinton, and M. Forsyth: Corrosion and Prevention 2008, Wellington, New Zealand, Nov. 2008, Australasian Corrosion Association, Australia.
14.
Zurück zum Zitat M. Behrouzvaziri: MEngSc Thesis, Monash University, Melbourne, 2009. M. Behrouzvaziri: MEngSc Thesis, Monash University, Melbourne, 2009.
15.
Zurück zum Zitat D.R. Gerrard: MEngSc Thesis, Monash University, Melbourne, Australia, 2002. D.R. Gerrard: MEngSc Thesis, Monash University, Melbourne, Australia, 2002.
16.
Zurück zum Zitat D.R. Gerrard, B.R.W. Hinton, E. Pereloma, and B.W. Cherry: Corrosion and Prevention 1998, Hobart, Nov. 1998, Australasian Corrosion Association, Blackburn, Australia, 1998, paper no. 38-012. D.R. Gerrard, B.R.W. Hinton, E. Pereloma, and B.W. Cherry: Corrosion and Prevention 1998, Hobart, Nov. 1998, Australasian Corrosion Association, Blackburn, Australia, 1998, paper no. 38-012.
17.
Zurück zum Zitat R.P. Gangloff: in Comprehensive Structural Integrity Elsevier Science, I. Milne, R.O. Ritchie, and B. Karihaloo, eds., Elsevier Science, New York, NY, 2003. R.P. Gangloff: in Comprehensive Structural Integrity Elsevier Science, I. Milne, R.O. Ritchie, and B. Karihaloo, eds., Elsevier Science, New York, NY, 2003.
18.
Zurück zum Zitat R.P. Gangloff, S.A. Shipilov, R.H. Jones, J.M. Olive, and R.B. Rebak: Environment-Induced Cracking of Materials, Elsevier, Amsterdam, 2008, pp. 141–65.CrossRef R.P. Gangloff, S.A. Shipilov, R.H. Jones, J.M. Olive, and R.B. Rebak: Environment-Induced Cracking of Materials, Elsevier, Amsterdam, 2008, pp. 141–65.CrossRef
19.
Zurück zum Zitat C. Barth, E. Steigerwald, and A. Troiano: Corrosion, 1969, vol. 25, pp. 353–58. C. Barth, E. Steigerwald, and A. Troiano: Corrosion, 1969, vol. 25, pp. 353–58.
20.
Zurück zum Zitat B.F. Brown: in The Theory of Stress Corrosion in Alloys, J.C. Scully, ed., NATO, Brussels, 1971. B.F. Brown: in The Theory of Stress Corrosion in Alloys, J.C. Scully, ed., NATO, Brussels, 1971.
21.
22.
Zurück zum Zitat N. Winzer, A. Atrens, W. Dietzel, G. Song, and K. Kainer: Mater. Sci. Eng. A, 2008, vol. 472, pp. 97–106.CrossRef N. Winzer, A. Atrens, W. Dietzel, G. Song, and K. Kainer: Mater. Sci. Eng. A, 2008, vol. 472, pp. 97–106.CrossRef
23.
Zurück zum Zitat S. Ramamurthy and A. Atrens: Corros. Sci., 2010, vol. 52, pp. 1042–51.CrossRef S. Ramamurthy and A. Atrens: Corros. Sci., 2010, vol. 52, pp. 1042–51.CrossRef
24.
Zurück zum Zitat S. Ramamurthy, W. Lau, and A. Atrens: Corros. Sci., 2011, vol. 53, pp. 2419–24.CrossRef S. Ramamurthy, W. Lau, and A. Atrens: Corros. Sci., 2011, vol. 53, pp. 2419–24.CrossRef
25.
Zurück zum Zitat L. Raymond: in ASM Materials Handbook, J.R. Davis, ed., ASM INTERNATIONAL, Metals Park, OH, 1987, p. 288. L. Raymond: in ASM Materials Handbook, J.R. Davis, ed., ASM INTERNATIONAL, Metals Park, OH, 1987, p. 288.
26.
Zurück zum Zitat Standard Test Method for Mechanical Hydrogen Embrittlement Evaluation of Plating/Coating Processes and Service Environments, ASTM F519-10. ASTM International, West Conshohocken, PA, 2008. Standard Test Method for Mechanical Hydrogen Embrittlement Evaluation of Plating/Coating Processes and Service Environments, ASTM F519-10. ASTM International, West Conshohocken, PA, 2008.
27.
Zurück zum Zitat W.J. Pollock: 4th Int. Conf. on Hydrogen in Metals, Beijing, 1988. W.J. Pollock: 4th Int. Conf. on Hydrogen in Metals, Beijing, 1988.
28.
Zurück zum Zitat Standard Practice for Slow Strain Rate Testing to Evaluate the Susceptibility of Metallic Materials to Environmentally Assisted Cracking ASTM G129-00(2006), ASTM International, West Conshohocken, PA, 2006. Standard Practice for Slow Strain Rate Testing to Evaluate the Susceptibility of Metallic Materials to Environmentally Assisted Cracking ASTM G129-00(2006), ASTM International, West Conshohocken, PA, 2006.
29.
Zurück zum Zitat Standard Reference Test Method for Making Potentiostatic and Potentiodynamic Anodic Polarization Measurements, ASTM G5-94(2004), ASTM International, West Conshohocken, PA, 2004. Standard Reference Test Method for Making Potentiostatic and Potentiodynamic Anodic Polarization Measurements, ASTM G5-94(2004), ASTM International, West Conshohocken, PA, 2004.
30.
Zurück zum Zitat G.B. Deacon, M. Forsyth, P.C. Junk, S.G. Leary, and W.W. Lee: Z. Anorgan. Allgem. Chemie, 2009, vol. 635 (6–7), pp. 833–39.CrossRef G.B. Deacon, M. Forsyth, P.C. Junk, S.G. Leary, and W.W. Lee: Z. Anorgan. Allgem. Chemie, 2009, vol. 635 (6–7), pp. 833–39.CrossRef
31.
Zurück zum Zitat W.J. Pollock and B.R.W. Hinton: in Galvanic Corrosion, ASTM STP 978. H.P. Hack, ed., ASTM, Philadelphia, PA, 1988, pp. 35–50. W.J. Pollock and B.R.W. Hinton: in Galvanic Corrosion, ASTM STP 978. H.P. Hack, ed., ASTM, Philadelphia, PA, 1988, pp. 35–50.
32.
Zurück zum Zitat R.J. Sanford: Principles of Fracture Mechanics, Prentice Hall, Englewood Cliffs, NJ, 2003. R.J. Sanford: Principles of Fracture Mechanics, Prentice Hall, Englewood Cliffs, NJ, 2003.
33.
Zurück zum Zitat D. Broek: Elementary Engineering Fracture Mechanics, 4th ed., Kluwer Academic Publishers, Boston, MA, 1986.CrossRef D. Broek: Elementary Engineering Fracture Mechanics, 4th ed., Kluwer Academic Publishers, Boston, MA, 1986.CrossRef
34.
Zurück zum Zitat G.E. Dieter: Mechanical Metallurgy, 2nd ed., McGraw-Hill Kogakusha, Tokyo, 1961. G.E. Dieter: Mechanical Metallurgy, 2nd ed., McGraw-Hill Kogakusha, Tokyo, 1961.
35.
Zurück zum Zitat M.R. Louthan: in Tensile Testing, 2nd ed., J.R. Davis, ed., ASM INTERNATIONAL, Materials Park, OH, 2004, pp. 115–36. M.R. Louthan: in Tensile Testing, 2nd ed., J.R. Davis, ed., ASM INTERNATIONAL, Materials Park, OH, 2004, pp. 115–36.
36.
Zurück zum Zitat G. Wranglen: An Introduction to Corrosion and Protection of Metals, Chapman and Hall, London, 1985. G. Wranglen: An Introduction to Corrosion and Protection of Metals, Chapman and Hall, London, 1985.
37.
Zurück zum Zitat J.R. Scully and P.J. Moran: Corrosion, 1988, vol. 44 (3), pp. 176–86.CrossRef J.R. Scully and P.J. Moran: Corrosion, 1988, vol. 44 (3), pp. 176–86.CrossRef
Metadaten
Titel
The Inhibition of Hydrogen Embrittlement in SAE 4340 Steel in an Aqueous Environment with the Rare Earth Compound Lanthanum 4 Hydroxy Cinnamate
verfasst von
B. R. W. Hinton
M. Behrouzvaziri
M. Forsyth
R. K. Gupta
M. Seter
P. G. Bushell
Publikationsdatum
01.07.2012
Verlag
Springer US
Erschienen in
Metallurgical and Materials Transactions A / Ausgabe 7/2012
Print ISSN: 1073-5623
Elektronische ISSN: 1543-1940
DOI
https://doi.org/10.1007/s11661-012-1103-y

Weitere Artikel der Ausgabe 7/2012

Metallurgical and Materials Transactions A 7/2012 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.