Introduction
Materials and methods
Microfibrillated cellulose
Total and surface charge determination
Fractionation
Scanning electron microscopy
Vacuum-assisted dewatering and film fabrication
Mechanical testing of films
Results and discussion
Fractionation
Size and charge characterisation
Fabrication of films and their characterisation
MFC A | MFC B | |||||||
---|---|---|---|---|---|---|---|---|
F1 | F2 | F3 | F4 | F1b | F2 | F3 | F4 | |
Volume (l) | 0.37 | 0.37 | 0.37 | 3.65a | – | 0.37 | 0.37 | 3.65a |
Concentration (g/l) | 0.50 | 0.50 | 0.50 | 0.05 | – | 0.50 | 0.50 | 0.05 |
Filtration time (min) | 0.5 | 3.3 | 18 | 530 | – | 2 | 18 | 492 |
Dry thickness (µl) | 43 | 37 | 33 | 36 | – | 33 | 34 | 34 |
Dry density (g/cm3) | 1.11 | 1.35 | 1.49 | 1.50 | – | 1.45 | 1.47 | 1.50 |
Dry total transmittance | 40 ± 4 | 34 ± 0 | 45 ± 2 | 66 ± 1 | – | 26 ± 1 | 45 ± 2 | 69 ± 9 |
Dry haze (%) | 98 ± 0 | 99 ± 0 | 98 ± 0 | 83 ± 5 | – | 98 ± 1 | 99 ± 0 | 79 ± 8 |
MFC A | MFC B | |||||||||
---|---|---|---|---|---|---|---|---|---|---|
F1 | F2 | F3 | F4 | MFC Aa | F1b | F2 | F3 | F4 | MFC Ba | |
Stress-at-break (MPa) | 72 ± 7 | 163 ± 9 | 195 ± 17 | 190 ± 14 | 171 ± 5 | – | 173 ± 12 | 203 ± 10 | 190 ± 28 | 206 ± 6 |
Strain-at-break (%) | 2.2 ± 0.2 | 5.8 ± 0.5 | 6.6 ± 1.1 | 5.1 ± 0.5 | 6.2 ± 0.5 | – | 5.8 ± 0.8 | 6.3 ± 0.6 | 4.7 ± 1.2 | 7.2 ± 0.6 |
E-modulus (GPa) | 8.8 ± 0.9 | 13.0 ± 1.9 | 13.8 ± 0.8 | 13.4 ± 1.0 | 12.1 ± 1.7 | – | 12.9 ± 1.2 | 13.5 ± 0.7 | 13.8 ± 1.2 | 12.6 ± 0.7 |