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Erschienen in: Metal Science and Heat Treatment 9-10/2024

19.02.2024 | STRUCTURE AND PHASE TRANSFORMATIONS

Transformation of Niobium Carbide in Heat-Resistant Alloys Based on Fe – 25Cr – 35Ni at 900°C and 1150°C

verfasst von: E. V. Zabavicheva, S. N. Petrov, S. Yu. Kondrat’ev

Erschienen in: Metal Science and Heat Treatment | Ausgabe 9-10/2024

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Abstract

Cross sections prepared using a focused ion beam are used for a transmission electron microscopy study of the microstructure and elemental composition of the intermetallic phases formed after long-term holding a 900 and 1150°C at the boundaries of dispersed particles of niobium carbide in a heat-resistant alloy of type HP40NbTi. Formation of a well-known G-phase is detected at 900°C. When the temperature is raised to 1150°C, an fcc intermetallic phase with parameter a = 1.084 nm (space group Fd3m) is detected. The elemental composition of the high-temperature intermetallic compound and participation of atmospheric nitrogen in its formation are established.

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Literatur
1.
Zurück zum Zitat G. D. Barbabela, L. H. De Almeida, T. L. Da Silveira, and I. Le May, “Phase characterization in two centrifugally cast HK stainless steel tubes,” Mater. Charact., 26, 1 – 7 (1991).CrossRef G. D. Barbabela, L. H. De Almeida, T. L. Da Silveira, and I. Le May, “Phase characterization in two centrifugally cast HK stainless steel tubes,” Mater. Charact., 26, 1 – 7 (1991).CrossRef
2.
Zurück zum Zitat Soares G. D. De Almeida, L. H. De Almeida, T. L. Da Silveira, and I. Le May, “Niobium additions in HP heat-resistant cast stainless steels,” Mater. Charact., 29, 387 – 396 (1992). Soares G. D. De Almeida, L. H. De Almeida, T. L. Da Silveira, and I. Le May, “Niobium additions in HP heat-resistant cast stainless steels,” Mater. Charact., 29, 387 – 396 (1992).
3.
Zurück zum Zitat M. Abbasi, I. Park, Y. Ro, et al., “G-phase formation in twenty-years aged heat-resistant cast austenitic steel reformer tube,” Mater. Charact., 148, 297 – 306 (2019).CrossRef M. Abbasi, I. Park, Y. Ro, et al., “G-phase formation in twenty-years aged heat-resistant cast austenitic steel reformer tube,” Mater. Charact., 148, 297 – 306 (2019).CrossRef
4.
Zurück zum Zitat M. Garbiak, W. Jasinski, and B. Piekarski, “Materials for reformer furnace tubes. History of evolution,” Arch. Foundry Eng., 11, Special Is. 2, 47 – 52 (2011). M. Garbiak, W. Jasinski, and B. Piekarski, “Materials for reformer furnace tubes. History of evolution,” Arch. Foundry Eng., 11, Special Is. 2, 47 – 52 (2011).
5.
Zurück zum Zitat L. Bonaccorsi, E. Guglielmino, E. Pino, et al., “Damage analysis in Fe – Cr – Ni centrifugally cast alloy tubes for reforming furnaces,” Eng. Fail. Anal., 36, 65 – 74 (2014).CrossRef L. Bonaccorsi, E. Guglielmino, E. Pino, et al., “Damage analysis in Fe – Cr – Ni centrifugally cast alloy tubes for reforming furnaces,” Eng. Fail. Anal., 36, 65 – 74 (2014).CrossRef
6.
Zurück zum Zitat L. H. De Almeida, A. F. Ribeiro and I. Le May., “Microstructural characterization of modified 25Cr – 35Ni centrifugally cast steel furnace tubes,” Mater. Charact., 49, 219 – 229 (2003). L. H. De Almeida, A. F. Ribeiro and I. Le May., “Microstructural characterization of modified 25Cr – 35Ni centrifugally cast steel furnace tubes,” Mater. Charact., 49, 219 – 229 (2003).
7.
Zurück zum Zitat Q. Z. Chen, C. W. Thomas, and D. M. Knowles, “Characterization of 20Cr32Ni1Nb alloys in as-cast and Ex-Service conditions by SEM, TEM and SDX,” Mater. Sci. Eng. A, 374, 398 – 408 (2004).CrossRef Q. Z. Chen, C. W. Thomas, and D. M. Knowles, “Characterization of 20Cr32Ni1Nb alloys in as-cast and Ex-Service conditions by SEM, TEM and SDX,” Mater. Sci. Eng. A, 374, 398 – 408 (2004).CrossRef
8.
Zurück zum Zitat A. Alvino, D. Lega, F. Giacobbe, et al., “Damage characterization in two reformer heater tubes after nearly 10 years of service at different operative and maintenance conditions,” Eng. Fail. Anal., 17, 1526 – 1541 (2010).CrossRef A. Alvino, D. Lega, F. Giacobbe, et al., “Damage characterization in two reformer heater tubes after nearly 10 years of service at different operative and maintenance conditions,” Eng. Fail. Anal., 17, 1526 – 1541 (2010).CrossRef
9.
Zurück zum Zitat V. N. Voevodin, “Structural materials of nuclear power industry — challenge of the 21st century,” Vopr. Atom. Nauki Tekh., Ser. Fiz. Radiats. Povrezhd. Radiats. Materialoved., 90(2), 10 – 22 (2007). V. N. Voevodin, “Structural materials of nuclear power industry — challenge of the 21st century,” Vopr. Atom. Nauki Tekh., Ser. Fiz. Radiats. Povrezhd. Radiats. Materialoved., 90(2), 10 – 22 (2007).
10.
Zurück zum Zitat S. Shi and J. C. Lippold, “Microstructure evolution during service exposure of two cast, heat-resisting stainless steels – HP-Nb modified and 20 – 32 Nb,” Mater. Charact., 59, 1029 – 1040 (2008).CrossRef S. Shi and J. C. Lippold, “Microstructure evolution during service exposure of two cast, heat-resisting stainless steels – HP-Nb modified and 20 – 32 Nb,” Mater. Charact., 59, 1029 – 1040 (2008).CrossRef
11.
Zurück zum Zitat I. A. Sustaita-Torres, S. Haro-Rodriguez, M. P. Guerrero-Mata, et al., “Aging of cast 35Cr – 45Ni heat resistant alloy,” Mater. Chem. Phys., 133, 1018 – 1023 (2012).CrossRef I. A. Sustaita-Torres, S. Haro-Rodriguez, M. P. Guerrero-Mata, et al., “Aging of cast 35Cr – 45Ni heat resistant alloy,” Mater. Chem. Phys., 133, 1018 – 1023 (2012).CrossRef
12.
Zurück zum Zitat A. F. Ribeiro, R. M. T. Borges, and L. H. De Almeida, “Phase transformation in heat resistant steel observed by STEM: (NbTi)C – NiNbSi (G-phase),” Acta Microsc., 11, 59 – 63 (2002). A. F. Ribeiro, R. M. T. Borges, and L. H. De Almeida, “Phase transformation in heat resistant steel observed by STEM: (NbTi)C – NiNbSi (G-phase),” Acta Microsc., 11, 59 – 63 (2002).
13.
Zurück zum Zitat J. Yan, Y. Gao, F. Yang, et al., “Effect of tungsten on the microstructure evolution and mechanical properties of yttrium modified HP40Nb alloy,” Mater. Sci. Eng. A, 529, 361 – 369 (2011).CrossRef J. Yan, Y. Gao, F. Yang, et al., “Effect of tungsten on the microstructure evolution and mechanical properties of yttrium modified HP40Nb alloy,” Mater. Sci. Eng. A, 529, 361 – 369 (2011).CrossRef
14.
Zurück zum Zitat K. G. Buchanan, M. V. Kral, and C. M. Bishop, “Crystallography and morphology of MC carbides in niobium-titanium modified as-cast HP alloys,” Metall. Mater. Trans. A, 45(8), 3373 – 3385 (2014).CrossRef K. G. Buchanan, M. V. Kral, and C. M. Bishop, “Crystallography and morphology of MC carbides in niobium-titanium modified as-cast HP alloys,” Metall. Mater. Trans. A, 45(8), 3373 – 3385 (2014).CrossRef
15.
Zurück zum Zitat J. Swaminathan, K. Guguloth, M. Gunjian, et al., “Failure analysis and remaining life assessment of service exposed primary reformer heater tubes,” Eng. Fail. Anal., 15, 311 – 331 (2008).CrossRef J. Swaminathan, K. Guguloth, M. Gunjian, et al., “Failure analysis and remaining life assessment of service exposed primary reformer heater tubes,” Eng. Fail. Anal., 15, 311 – 331 (2008).CrossRef
16.
Zurück zum Zitat X.-F. Guo, Y.-Y. Ni, J.-M. Gong, et al., “Formation of G-phase in 20Cr32Ni1Nb stainless steel and its effect on mechanical properties,” Acta Metall. Sin-Engl., 30, 829 – 839 (2017).CrossRef X.-F. Guo, Y.-Y. Ni, J.-M. Gong, et al., “Formation of G-phase in 20Cr32Ni1Nb stainless steel and its effect on mechanical properties,” Acta Metall. Sin-Engl., 30, 829 – 839 (2017).CrossRef
17.
Zurück zum Zitat C. J. Liu and Y. Chen, “Variations of the microstructure and mechanical properties of HP40Nb hydrogen reformer tube with time at elevated temperature,” Mater. Des., 32, 2507 – 2512 (2011).CrossRef C. J. Liu and Y. Chen, “Variations of the microstructure and mechanical properties of HP40Nb hydrogen reformer tube with time at elevated temperature,” Mater. Des., 32, 2507 – 2512 (2011).CrossRef
18.
Zurück zum Zitat A. I. Rudskoy, S. Yu. Kondrat’ev, G. P. Anastasiadi, et al., “Transformation of the structure of refractory alloy 0.45C – 26Cr – 33Ni – 2Si – 2Nb during long-term high-temperature hold,” Met. Sci. Heat Treat., 55(9 – 10), 517 – 525 (2014). A. I. Rudskoy, S. Yu. Kondrat’ev, G. P. Anastasiadi, et al., “Transformation of the structure of refractory alloy 0.45C – 26Cr – 33Ni – 2Si – 2Nb during long-term high-temperature hold,” Met. Sci. Heat Treat., 55(9 – 10), 517 – 525 (2014).
19.
Zurück zum Zitat E. A. Kemik, P. J. Maziasz, R. W. Swindeman, et al., “Structure and phase stability in cast modified-HP austenite after long-term ageing,” Scr. Mater., 49(2), 117 – 122 (2003).CrossRef E. A. Kemik, P. J. Maziasz, R. W. Swindeman, et al., “Structure and phase stability in cast modified-HP austenite after long-term ageing,” Scr. Mater., 49(2), 117 – 122 (2003).CrossRef
20.
Zurück zum Zitat R. Voicu, E. Andrieu, D. Poquillon, et al., “Microstructure evolution of HP40-Nb alloys during aging under air at 1000°C,” Mater. Charact., 60, 1020 – 1027 (2006).CrossRef R. Voicu, E. Andrieu, D. Poquillon, et al., “Microstructure evolution of HP40-Nb alloys during aging under air at 1000°C,” Mater. Charact., 60, 1020 – 1027 (2006).CrossRef
21.
Zurück zum Zitat A. S. Oryshchenko, Yu. A. Utkin, I. P. Popova, et al., “Investigation of heat resistance characteristics of the metal of centrifugally cast tubes produced from alloy 45Kh32N43SB and their welded joints at a temperature of up to 1150°C. Part 1. Heat resistance of tubes at up to 1100°C,” Vopr. Materialoved., No. 2(12), 1 – 13 (2020). A. S. Oryshchenko, Yu. A. Utkin, I. P. Popova, et al., “Investigation of heat resistance characteristics of the metal of centrifugally cast tubes produced from alloy 45Kh32N43SB and their welded joints at a temperature of up to 1150°C. Part 1. Heat resistance of tubes at up to 1100°C,” Vopr. Materialoved., No. 2(12), 1 – 13 (2020).
22.
Zurück zum Zitat V. V. Rybin, A. S. Rubtsov, and E. V. Nesterova, “Method of single reflections (SR) and its application to electron microscope analysis of fine phases,” Zavod. Lab., No. 5, 16 – 21 (1982). V. V. Rybin, A. S. Rubtsov, and E. V. Nesterova, “Method of single reflections (SR) and its application to electron microscope analysis of fine phases,” Zavod. Lab., No. 5, 16 – 21 (1982).
23.
Zurück zum Zitat J. M. Joubert, W. St-Fleur, J. Sarthou, et al., “Equilibrium characterization and thermodynamic calculations on highly alloyed refractory steels,” CALPHAD, 46, 55 – 61 (2014).CrossRef J. M. Joubert, W. St-Fleur, J. Sarthou, et al., “Equilibrium characterization and thermodynamic calculations on highly alloyed refractory steels,” CALPHAD, 46, 55 – 61 (2014).CrossRef
24.
Zurück zum Zitat T. Sourmail, “Precipitation in creep stainless austenitic steels,” Mater. Sci. Technol., 7, 1 – 14 (2001).ADSCrossRef T. Sourmail, “Precipitation in creep stainless austenitic steels,” Mater. Sci. Technol., 7, 1 – 14 (2001).ADSCrossRef
25.
Zurück zum Zitat R. F. A. Jargelius-Pettersson, “Precipitation trends in highly alloyed austenitic stainless steels,” Zeitschrift für Metallkunde, 89(3), 177 – 183 (1998). R. F. A. Jargelius-Pettersson, “Precipitation trends in highly alloyed austenitic stainless steels,” Zeitschrift für Metallkunde, 89(3), 177 – 183 (1998).
26.
Zurück zum Zitat R. F. A. Jargelius-Pettersson, “Precipitation in a nitrogen-alloyed stainless steel at 850°C,” Scr. Metall. Mater., 28, 1399 – 1403 (1993).CrossRef R. F. A. Jargelius-Pettersson, “Precipitation in a nitrogen-alloyed stainless steel at 850°C,” Scr. Metall. Mater., 28, 1399 – 1403 (1993).CrossRef
Metadaten
Titel
Transformation of Niobium Carbide in Heat-Resistant Alloys Based on Fe – 25Cr – 35Ni at 900°C and 1150°C
verfasst von
E. V. Zabavicheva
S. N. Petrov
S. Yu. Kondrat’ev
Publikationsdatum
19.02.2024
Verlag
Springer US
Erschienen in
Metal Science and Heat Treatment / Ausgabe 9-10/2024
Print ISSN: 0026-0673
Elektronische ISSN: 1573-8973
DOI
https://doi.org/10.1007/s11041-024-00977-8

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