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Polymer Bulletin
Erschienen in: Polymer Bulletin 1/2018

20.04.2017 | Original Paper

Two new tercopolymers incorporating electron-rich benzodithiophene and electron-accepting pyrrolo[3,4-c]pyrrole-1,3-dione and difluorobenzothiadiazole derivatives for polymer solar cells

verfasst von: Vellaiappillai Tamilavan, Seungmin Kim, Rajalingam Agneeswari, Dal Yong Lee, Shinuk Cho, Junghyun Jeong, Youngeup Jin, Sung Heum Park, Myung Ho Hyun

Erschienen in: Polymer Bulletin | Ausgabe 1/2018

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Abstract

Two new tercopolymers (RP1 and RP2) containing electron-donating benzodithiophene, weak electron-accepting pyrrolo[3,4-c]pyrrole-1,3-dione derivative and strong electron-accepting 5,6-difluorobenzothiadiazole derivative were prepared. The opto-electrical studies showed that RP1 and RP2 displayed identical optical band gaps (E g ~ 1.72 eV) and highest occupied/lowest unoccupied molecular orbital energy levels (HOMO/LUMO ~ −5.32 eV/−3.60 eV). The polymer solar cells prepared with the configuration of ITO/PEDOT:PSS/RP1:PC70BM (1:1.5 wt%) + 3 vol% DIO/Al and ITO/PEDOT:PSS/RP2:PC70BM (1:1.5 wt%) + 3 vol% DIO/Al exhibited a maximum power conversion efficiency (PCE) of 5.16% (V oc ~ 0.76 V, J sc ~ 10.93 mA/cm2, and FF ~ 0.62) and a PCE of 3.56% (V oc ~ 0.67 V, J sc ~ 9.67 mA/cm2, and FF ~ 0.55), respectively.
Vorheriger Artikel Effect of nature of chemical crosslinker on swelling and solubility parameter of a new stimuli-responsive cationic poly(N-acryloyl-N′-propyl piperazine) hydrogel
Nächster Artikel Physical properties of poly[(thiophene-2,5-diyl)-co-para-chloro benzylidene] doped with cobalt sulphate: synthesis and characterization

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Metadaten
Titel
Two new tercopolymers incorporating electron-rich benzodithiophene and electron-accepting pyrrolo[3,4-c]pyrrole-1,3-dione and difluorobenzothiadiazole derivatives for polymer solar cells
verfasst von
Vellaiappillai Tamilavan
Seungmin Kim
Rajalingam Agneeswari
Dal Yong Lee
Shinuk Cho
Junghyun Jeong
Youngeup Jin
Sung Heum Park
Myung Ho Hyun
Publikationsdatum
20.04.2017
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 1/2018
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-017-2028-9

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