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Erschienen in: Rare Metals 7/2022

19.04.2022 | Original Article

Ultrafast photocatalytic degradation of nitenpyram by 2D ultrathin Bi2WO6: mechanism, pathways and environmental factors

verfasst von: Yuan-Hao Cheng, Juan Chen, Hui-Nan Che, Yan-Hui Ao, Bin Liu

Erschienen in: Rare Metals | Ausgabe 7/2022

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Abstract

As a common insecticide, nitenpyram (NTP) seriously threatens the human health and environmental safety. In this work, a visible-light-responsive photocatalyst two-dimensional (2D) Bi2WO6 was synthesized and applied to degrade NTP. Compared with bulk Bi2WO6, the 2D Bi2WO6 exhibits better photocatalytic performance for NTP degradation under visible-light irradiation. The enhanced activity can be ascribed to the unique 2D structure which would induce to higher efficiency of carrier separation. Moreover, hole (h+) plays a major role (and ·O2) in the degradation of NTP. Based on the intermediates detected by high-performance liquid chromatography–mass spectrometry (HPLC–MS), the degradation pathway of NTP was proposed. In addition, the influence of typical environmental factors (pH, water matrix, inorganic cations and common anions) on the degradation of NTP was also investigated. This work not only helps people to understand the degradation of pesticides in actual water bodies, but also provides reference for the subsequent treatment of agricultural wastewater.

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Metadaten
Titel
Ultrafast photocatalytic degradation of nitenpyram by 2D ultrathin Bi2WO6: mechanism, pathways and environmental factors
verfasst von
Yuan-Hao Cheng
Juan Chen
Hui-Nan Che
Yan-Hui Ao
Bin Liu
Publikationsdatum
19.04.2022
Verlag
Nonferrous Metals Society of China
Erschienen in
Rare Metals / Ausgabe 7/2022
Print ISSN: 1001-0521
Elektronische ISSN: 1867-7185
DOI
https://doi.org/10.1007/s12598-022-01984-5

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