Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Bücher
Zeitschriften
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
MTZ-Fachkongress

Antriebe und Energiesysteme von morgen


Austausch von Automobil- und Energiewirtschaft

Am 14./15. Mai geht es in Chemnitz um die Mobilitätswende durch Elektro- und Wasserstofffahrzeuge.
Erweiterte Suche
Anmelden
nach oben
Rare Metals
Erschienen in: Rare Metals 7/2022

28.03.2022 | Original Article

Significantly improved photocatalysis-self-Fenton degradation performance over g-C3N4 via promoting Fe(III)/Fe(II) cycle

verfasst von: Le Chen, Xin-Xia He, Ze-Han Gong, Jia-Lian Li, Yang Liao, Xiao-Ting Li, Jun Ma

Erschienen in: Rare Metals | Ausgabe 7/2022

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Photocatalysis-self-Fenton system, i.e., photocatalytic H2O2 generation and utilization in situ for ·OH radials production to remove organic pollutants with high-fluent degradation and mineralization performance possesses such advantages as cleanliness, efficiency and safety. However, its degradation activity always suffers from the Fe(III)/Fe(II) cycle. For this reason, graphitic carbon interface-modified g-C3N4 (CUCN) was fabricated to remarkably improve photocatalysis-self-Fenton degradation activity. The experiment results indicated that CUCN-2% photocatalyst, in which the loading percentage of graphitic carbon was 2%, demonstrated the optimum degradation performance among all the counterparts. The mineralization degree for RhB in 3 h over CUCN-2% reached 63.77%, nearly 3.35-fold higher than the pristine g-C3N4. The significantly improved mineralization efficiency was ascribed to the promoted Fe(III)/Fe(II) cycle by photogenerated electrons, which leading to the higher utilization efficiency of H2O2 through Fenton reaction, thereby producing more hydroxyl radicals. It is anticipated that our work could provide new insights for the design of photocatalysis-self-Fenton system with exceptional degradation performance for actual photocatalytic applications.

Graphical abstract

Vorheriger Artikel Dual Z-scheme Bi3TaO7/Bi2S3/SnS2 photocatalyst with high performance for Cr(VI) reduction and TC degradation under visible light irradiation
Nächster Artikel Ultrafast photocatalytic degradation of nitenpyram by 2D ultrathin Bi2WO6: mechanism, pathways and environmental factors

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Anhänge
Nur mit Berechtigung zugänglich
Literatur
[1]
Li YX, Ouyang SX, Xu H, Wang X, Bi YP, Zhang YF, Ye JH. Constructing solid–gas-interfacial Fenton reaction over alkalinized-C3N4 photocatalyst to achieve apparent quantum yield of 49% at 420 nm. J Am Chem Soc. 2016;138(40):13289.CrossRef
[2]
Wang CY, Zhang X, Zhang YJ, Chen JJ, Huang GX, Jiang J, Wang WK, Yu HQ. Direct generation of hydroxyl radicals over bismuth oxybromide nanobelts with tuned band structure for photocatalytic pollutant degradation under visible light irradiation. Appl Catal B Environ. 2018;237:464.CrossRef
[3]
Zhou SQ, Wang Y, Zhou K, Ba DY, Ao YH, Wang PF. In-situ construction of Z-scheme g-C3N4/WO3 composite with enhanced visible-light responsive performance for nitenpyram degradation. Chin Chem Lett. 2021;32(7):2179.CrossRef
[4]
Ma J, Wang K, Wang C, Chen XJ, Zhu W, Zhu GX, Yao WQ, Zhu YF. Photocatalysis-self-Fenton system with high-fluent degradation and high mineralization ability. Appl Catal B Environ. 2020;276:119150.CrossRef
[5]
Jiang ZY, Wang LZ, Lei JY, Liu YD, Zhang JL. Photo-Fenton degradation of phenol by CdS/rGO/Fe2+ at natural pH with in-situ generated H2O2. Appl Catal B Environ. 2019;241:367.CrossRef
[6]
Zhao S, Zhao X, Zhang H, Li J, Zhu YF. Covalent combination of polyoxometalate and graphitic carbon nitride for light-driven hydrogen peroxide production. Nano Energy. 2017;100(35):405.CrossRef
[7]
Wei Z, Liu ML, Zhang ZJ, Yao WQ, Tan HW, Zhu YF. Efficient visible-light-driven selective oxygen reduction to hydrogen peroxide by oxygen-enriched graphitic carbon nitride polymers. Energy Environ Sci. 2018;11(9):2581.CrossRef
[8]
Li JY, Zhang ZY, Cui W, Wang H, Cen WL, Johnson G, Jiang GM, Zhang S, Dong F. The spatially oriented charge flow and photocatalysis mechanism on internal van der Waals heterostructures enhanced g-C3N4. ACS Catal. 2018;8(9):8376.CrossRef
[9]
Mu RH, Ao YH, Wu TF, Wang C, Wang PF. Synergistic effect of molybdenum nitride nanoparticles and nitrogen-doped carbon on enhanced photocatalytic hydrogen evolution performance of CdS nanorods. J Alloy Compd. 2020;812:151990.CrossRef
[10]
Huang S, Ouyang T, Zheng BF, Dan M, Liu ZQ. Enhanced photoelectrocatalytic activities for CH3OH-to-HCHO conversion on Fe2O3/MoO3: Fe-O-Mo covalency dominates the intrinsic activity. Angew Chem Int Ed. 2021;60(17):9546.CrossRef
[11]
Liu Q, Chen TX, Guo YR, Zhang ZG, Fang XM. Grafting Fe(III) species on carbon nanodots/Fe-doped g-C3N4 via interfacial charge transfer effect for highly improved photocatalytic performance. Appl Catal B Environ. 2017;205:173.CrossRef
[12]
Liu XE, Dai LM. Carbon-based metal-free catalysts. Nat Rev Mater. 2016;1(11):1.CrossRef
[13]
Fang S, Xia Y, Lv KL, Li Q, Sun J, Li M. Effect of carbon-dots modification on the structure and photocatalytic activity of g-C3N4. Appl Catal B Environ. 2016;185:225.CrossRef
[14]
Dhenadhayalan N, Lin KC, Saleh TA. Recent advances in functionalized carbon dots toward the design of efficient materials for sensing and catalysis applications. Small. 2020;16(1):1905767.CrossRef
[15]
Che W, Cheng WR, Yao T, Tang FM, Liu W, Su H, Huang YY, Liu QH, Liu JK, Hu FC. Fast photoelectron transfer in (Cring)–C3N4 plane heterostructural nanosheets for overall water splitting. J Am Chem Soc. 2017;139(8):3021.CrossRef
[16]
Han M, Lu SY, Qi F, Zhu SJ, Sun HZ, Yang B. Carbon dots–implanted graphitic carbon nitride nanosheets for photocatalysis: simultaneously manipulating carrier transport in inter-and intralayers. Sol RRL. 2020;4(4):1900517.CrossRef
[17]
Zhao S, Guo T, Li X, Xu TG, Yang B, Zhao X. Carbon nanotubes covalent combined with graphitic carbon nitride for photocatalytic hydrogen peroxide production under visible light. Appl Catal B Environ. 2018;224:725.CrossRef
[18]
Zhou HY, Zhang H, He YL, Huang BK, Zhou CY, Yao G, Lai B. Critical review of reductant-enhanced peroxide activation processes: trade-off between accelerated Fe3+/Fe2+ cycle and quenching reactions. Appl Catal B Environ. 2021;286:119900.CrossRef
[19]
Rincón AG, Pulgarin C. Absence of E. coli regrowth after Fe3+ and TiO2 solar photoassisted disinfection of water in CPC solar photoreactor. Catal Today. 2007;124(3–4):204.CrossRef
[20]
Khamboonrueang D, Srirattanapibul S, Tang IM, Thongmee S. TiO2·rGO nanocomposite as a photo catalyst for the reduction of Cr6+. Mater Res Bull. 2018;107:236.
[21]
Hunsom M, Pruksathorn K, Damronglerd S, Vergnes H, Duverneuil P. Electrochemical treatment of heavy metals (Cu2+, Cr6+, Ni2+) from industrial effluent and modeling of copper reduction. Water Res. 2005;39(4):610.CrossRef
[22]
Wang C, Wang K, He XX, Liao Y, Mao H, Zhao SL, Ma J. Constructing internal electric field in g-C3N4 significantly promotes the photocatalytic performance for H2O2 generation. Catal Lett. 2021;151(5):1225.CrossRef
[23]
Xu TF, Wang DN, Dong LL, Shen HB, Lu WY, Chen WX. Graphitic carbon nitride co-modified by zinc phthalocyanine and graphene quantum dots for the efficient photocatalytic degradation of refractory contaminants. Appl Catal B Environ. 2019;244:96.CrossRef
[24]
Tan LH, Xu JH, Zhang XJ, Hang ZS, Jia YQ, Wang SB. Synthesis of g-C3N4/CeO2 nanocomposites with improved catalytic activity on the thermal decomposition of ammonium perchlorate. Appl Surf Sci. 2015;356:447.CrossRef
[25]
Qin PL, Zeng K, Lan ZQ, Huang XT, Liu HZ, Guo J. Enhanced dydrogen storage properties of Mg–Al alloy catalyzed with reduced graphene oxide supported with LaClO. Chin J Rare Met. 2020;44(5):499.
[26]
Wang JF, Chen J, Wang PF, Hou J, Wang C, Ao YH. Robust photocatalytic hydrogen evolution over amorphous ruthenium phosphide quantum dots modified g-C3N4 nanosheet. Appl Catal B Environ. 2018;239:578.CrossRef
[27]
Zhu BC, Xia PF, Li Y, Ho WK, Yu JG. Fabrication and photocatalytic activity enhanced mechanism of direct Z-scheme g-C3N4/Ag2WO4 photocatalyst. Appl Surf Sci. 2017;391(B):175.
[28]
Huang HW, Xiao K, Tian N, Dong F, Zhang TR, Du X, Zhang YH. Template-free precursor-surface-etching route to porous, thin g-C3N4 nanosheets for enhancing photocatalytic reduction and oxidation activity. J Mater Chem A. 2017;5(33):17452.CrossRef
[29]
Zhang Y, Zhao SM, Su QW, Xu JL. Visible light response ZnO–C3N4 thin film photocatalyst. Rare Met. 2021;40(1):96.CrossRef
[30]
Yang Y, Zhang C, Huang DL, Zeng GM, Huang JH, Lai C, Zhou CY, Wang WJ, Guo H, Xue WJ. Boron nitride quantum dots decorated ultrathin porous g-C3N4: intensified exciton dissociation and charge transfer for promoting visible-light-driven molecular oxygen activation. Appl Catal B Environ. 2019;245:87.CrossRef
[31]
Li X, Xie J, Jiang CJ, Yu JG, Zhang PY. Review on design and evaluation of environmental photocatalysts. Front Env Sci Eng. 2018;12(5):1.CrossRef
[32]
Zhang JZ, Lang JY, Wei Y, Zheng Q, Liu LY, Hu YH, Zhou BX, Yuan CL, Long MC. Efficient photocatalytic H2O2 production from oxygen and pure water over graphitic carbon nitride decorated by oxidative red phosphorus. Appl Catal B Environ. 2021;298:120522.CrossRef
[33]
Chen X, Zhang WW, Zhang LX, Feng LP, Zhang CX, Jiang J, Yan TJ, Wang H. Sacrificial agent-free photocatalytic H2O2 evolution via two-electron oxygen reduction using a ternary α-Fe2O3/CQD@ g-C3N4 photocatalyst with broad-spectrum response. J Mater Chem A. 2020;8(36):18816.CrossRef
[34]
Yang LP, Dong GH, Jacobs DL, Wang YH, Zang L, Wang CY. Two-channel photocatalytic production of H2O2 over g-C3N4 nanosheets modified with perylene imides. J Catal. 2017;352:274.CrossRef
[35]
Che HN, Gao X, Chen J, Hou J, Ao YH, Wang PF. Iodide-induced fragmentation of polymerized hydrophilic carbon nitride for high performance quasi-homogeneous photocatalytic H2O2 production. Angew Chem Int Ed. 2021;60(48):2.CrossRef
[36]
He Z, Sun C, Yang SG, Ding YC, He H, Wang ZL. Photocatalytic degradation of rhodamine B by Bi2WO6 with electron accepting agent under microwave irradiation: mechanism and pathway. J Hazard Mater. 2009;162(2–3):1477.CrossRef
[37]
Liang LP, Cheng LB, Zhang YT, Wang Q, Wu Q, Xue YY, Meng X. Efficiency and mechanisms of Rhodamine B degradation in Fenton-like systems based on zero-valent iron. Rsc Adv. 2020;10(48):28509.CrossRef
[38]
Gu JY, Luo CH, Zhou WF, Tong ZP, Zhang HF, Zhang PH, Ren XD. Degradation of Rhodamine B in aqueous solution by laser cavitation. Ultrason Sonochem. 2020;68:105181.CrossRef
[39]
Shiraishi Y, Kanazawa S, Sugano Y, Tsukamoto D, Sakamoto H, Ichikawa S, Hirai T. Highly selective production of hydrogen peroxide on graphitic carbon nitride (g-C3N4) photocatalyst activated by visible light. Acs Catal. 2014;4(3):774.CrossRef
[40]
Samanta S, Yadav R, Kumar A, Sinha AK, Srivastava R. Surface modified C, O co-doped polymeric g-C3N4 as an efficient photocatalyst for visible light assisted CO2 reduction and H2O2 production. Appl Catal B Environ. 2019;259:118054.CrossRef
[41]
Yu FY, Wang K, Wang C, He XX, Liao Y, Zhao SL, Mao H, Li XT, Ma J. Anthraquinone covalently modified carbon nanotubes for efficient and steady electrocatalytic H2O2 generation. Chem Res Chin U. 2020;36(6):1332.CrossRef
[42]
He XX, Shang HY, Wang C, Chen L, Gong ZH, Wang J, Zhao SL, Ma J. Significantly influenced photocatalytic performance for H2O2 generation over ultrathin g-C3N4 through regulating the migration orientation of photogenerated charge carriers. Chin Chem Lett. 2021;32(11):3377.CrossRef
Metadaten
Titel
Significantly improved photocatalysis-self-Fenton degradation performance over g-C3N4 via promoting Fe(III)/Fe(II) cycle
verfasst von
Le Chen
Xin-Xia He
Ze-Han Gong
Jia-Lian Li
Yang Liao
Xiao-Ting Li
Jun Ma
Publikationsdatum
28.03.2022
Verlag
Nonferrous Metals Society of China
Erschienen in
Rare Metals / Ausgabe 7/2022
Print ISSN: 1001-0521
Elektronische ISSN: 1867-7185
DOI
https://doi.org/10.1007/s12598-022-01963-w

Weitere Artikel der Ausgabe 7/2022

Rare Metals 7/2022 Zur Ausgabe

Mini Review

Magnetic skyrmions in curved geometries

OriginalPaper

Hot deformation behavior and processing maps of Ti–15Al–12Nb alloy

OriginalPaper

Relation between microstructure and magnetic properties of shock wave-compressed Nd–Fe–B magnets

Original Article

Dual Z-scheme Bi3TaO7/Bi2S3/SnS2 photocatalyst with high performance for Cr(VI) reduction and TC degradation under visible light irradiation

Letter

Boron-doped three-dimensional MXene host for durable lithium-metal anode

Original Article

A novel Li-ion supercapattery by K-ion vacant ternary perovskite fluoride anode with pseudocapacitive conversion/insertion dual mechanisms

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise