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Rare Metals

Erschienen in:

21.05.2019

Uniform small metal nanoparticles anchored on CeO₂ nanorods driven by electroless chemical deposition

verfasst von: Zheng Chen, Fang-Xian Cao, Wei Gao, Qing-Chen Dong, Yong-Quan Qu

Erschienen in: Rare Metals | Ausgabe 7/2020

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Abstract

We report a facile electroless chemical deposition (ECD) method to deposit uniform Pd nanoparticles ((2.5 ± 0.6) nm) on CeO₂ nanorods (PdNPs/CeO₂-ECD) through the interface redox reaction between the reduced CeO₂ and Na₂PdCl₄. PdNPs/CeO₂-ECD exhibits a stronger electronic metal–support interaction (EMSI) evidenced by higher reducibility and stronger anti-sintering capability at high temperatures, compared to that prepared by the conventional impregnation method. Such an EMSI effect of PdNPs/CeO₂-ECD significantly improves its catalytic activity in CO oxidation. Besides, the chlorine residue-free catalysts through ECD process avoid the deleterious effect of chlorine on CO oxidation. This ECD process can further be extended to deposit various uniform nanoscaled noble metals (Au, Ag, Pt, Ru, Rh, etc.) on CeO₂, which may deliver their potentials in advanced catalysis.

Graphical abstract

Vorheriger Artikel CO catalytic oxidation over Pd/CeO2 with different chemical states of Pd

Nächster Artikel Bifunctional iron-phtalocyanine metal–organic framework catalyst for ORR, OER and rechargeable zinc–air battery

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Titel: Uniform small metal nanoparticles anchored on CeO2 nanorods driven by electroless chemical deposition
verfasst von: Zheng Chen
Fang-Xian Cao
Wei Gao
Qing-Chen Dong
Yong-Quan Qu
Publikationsdatum: 21.05.2019
Verlag: Nonferrous Metals Society of China
Erschienen in: Rare Metals / Ausgabe 7/2020
Print ISSN: 1001-0521
Elektronische ISSN: 1867-7185
DOI: https://doi.org/10.1007/s12598-019-01266-7

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Abstract

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