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Cellulose

Erschienen in:

01.08.2010

Characterisation of amino acid modified cellulose surfaces using ToF-SIMS and XPS

verfasst von: D. M. Kalaskar, R. V. Ulijn, J. E. Gough, M. R. Alexander, D. J. Scurr, W. W. Sampson, S. J. Eichhorn

Erschienen in: Cellulose | Ausgabe 4/2010

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Abstract

Cellulosic fibrous networks are modified using 3 different amino acids; small (Glycine, Gly), aliphatic (Leucine, Leu) and aromatic (Phenylalanine, Phe). The effect of amino acid functionality on chemical coupling to cellulose fibres in terms of their coverage and packing density are investigated. Different amino acid modified cellulose networks are characterised by using Time of Flight Secondary Ion Mass Spectrometry (ToF-SIMS) and X-ray Photoelectron Spectroscopy (XPS). The presence of amino acids is confirmed using ToF-SIMS. The quantitative distribution of different amino acids across the cellulose surface is assessed by using XPS. It is shown that the packing density of amino acids depends on the size of the side chain; smaller amino acids (Gly, Leu) tend to couple to the surface at higher density compared to larger ones (Phe). This study has implications for the functionalisation of polysaccharide materials for a wide range of applications.

Vorheriger Artikel Time-resolved X-ray diffraction microprobe studies of the conversion of cellulose I to ethylenediamine-cellulose I

Nächster Artikel Controlled accessibility Lewis acid catalysed thermal reactions of regenerated cellulosic fibres

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Titel: Characterisation of amino acid modified cellulose surfaces using ToF-SIMS and XPS
verfasst von: D. M. Kalaskar
R. V. Ulijn
J. E. Gough
M. R. Alexander
D. J. Scurr
W. W. Sampson
S. J. Eichhorn
Publikationsdatum: 01.08.2010
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 4/2010
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-010-9413-y

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