nach oben

Cellulose

Erschienen in:

06.06.2019 | Original Research

Composite nanofiber membranes of bacterial cellulose/halloysite nanotubes as lithium ion battery separators

verfasst von: Chenghao Huang, Hui Ji, Bin Guo, Lei Luo, Weilin Xu, Jinping Li, Jie Xu

Erschienen in: Cellulose | Ausgabe 11/2019

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

Composite nanofiber membranes comprising bacterial cellulose (BC) and halloysite nanotubes (HNTs) were prepared by vacuum filtration. The tensile strength and ionic conductivity of the nanofiber membranes were improved by the blending of HNTs. The BC/HNTs nanofiber membrane with m(BC): m(HNTs) = 150: 1 (denoted as BC/HNTs-150) exhibited superior tensile strength (84.4 MPa), high porosity (83.0%), outstanding thermal stability as well as good electrolyte retention (369% electrolyte uptake). In addition, the BC/HNTs-150 membrane delivered a higher ionic conductivity (5.13 mS cm⁻¹) than that of the BC (2.88 mS cm⁻¹) and commercial PP–PE–PP (2.05 mS cm⁻¹) separators. The battery containing the BC/HNTs-150 separator also showed better capacity (162 mAh g⁻¹) and cycling property (95% after 100 cycles) than the battery using the BC separator, demonstrating the BC/HNTs composite membranes to be hopeful candidates used in high-performance lithium-ion batteries.

Graphic abstract

Vorheriger Artikel Anisotropic nanocellulose aerogels with ordered structures fabricated by directional freeze-drying for fast liquid transport

Nächster Artikel A hierarchical Ag2O-nanoparticle/TiO2-nanotube composite derived from natural cellulose substance with enhanced photocatalytic performance

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Alcoutlabi M, Lee H, Watson JV, Zhang X (2013) Preparation and properties of nanofiber-coated composite membranes as battery separators via electrospinning. J Mater Sci 48:2690–2700CrossRef

Arora P, Zhang Z (2004) Battery Separators. Chem Rev 104:4419–4462CrossRef

Attia NF, Menemparabath MM, Arepalli S, Geckeler KE (2013) Inorganic nanotube composites based on polyaniline: potential room-temperature hydrogen storage materials. Int J Hydrogen Energ 38:9251–9262CrossRef

Choi JW, Aurbach D (2016) Promise and reality of post-lithium-ion batteries with high energy densities. Nat Rev Mater 1:16013CrossRef

Deng S, Zhang J, Ye L, Wu J (2008) Toughening epoxies with halloysite nanotubes. Polymer 49:5119–5127CrossRef

French AD (2014) Idealized powder diffraction patterns for cellulose polymorphs. Cellulose 21:885–896CrossRef

Hao J, Xiao Q, Lei G, Li Z, Wu L (2014) A novel polyvinylidene fluoride/microfiber composite gel polymer electrolyte with an interpenetrating network structure for lithium ion battery. Electrochem Acta 125:450–456CrossRef

Hu W, Chen S, Yang J, Li Z, Wang H (2014) Functionalized bacterial cellulose derivatives and nanocomposites. Carbohyd Polym 101:1043–1060CrossRef

Huang X (2011) Separator technologies for lithium-ion batteries. J Solid State Electrochem 15:649–662CrossRef

Huang Y, Zhu C, Yang J, Nie Y, Chen C, Sun D (2014) Recent advances in bacterial cellulose. Cellulose 21:1–30CrossRef

Huang F, Xu Y, Peng B, Su Y, Jiang F, Hsieh YL, Wei Q (2015) Coaxial electrospun cellulose-core fluoropolymer-shell fibrous membrane from recycled cigarette filter as separator for high performance lithium-ion battery. ACS Sustain Chem Eng 3:932–940CrossRef

Jabbour L, Bongiovanni R, Chaussy D, Gerbaldi C, Beneventi D (2013) Cellulose-based Li-ion batteries: a review. Cellulose 20:1523–1545CrossRef

Jiang F, Yin L, Yu Q, Zhong C, Zhang J (2015) Bacterial cellulose nanofibrous membrane as thermal stable separator for lithium-ion batteries. J Power Sources 279:21–27CrossRef

Jiang F, Yu N, Lei Y, Yuan F, Yu Q, Zhong C (2016) Core-shell-structured nanofibrous membrane as advanced separator for lithium-ion batteries. J Membrane Sci 510:1–9CrossRef

Kimura N, Sakumoto T, Mori Y, Wei K, Kim BS, Song KH, Kim IS (2014) Fabrication and characterization of reinforced electrospun poly(vinylidene fluoride-co-hexafluoropropylene) nanofiber membranes. Compos Sci Technol 92:120–125CrossRef

Lee H, Alcoutlabi M, Watson JV, Zhang X (2013) Electrospun nanofiber-coated separator membranes for lithium-ion rechargeable batteries. J Appl Polym Sci 129:1939–1951CrossRef

Li X, He J, Wu D, Zhang M, Meng J, Ni P (2015) Development of plasma-treated polypropylene nonwoven-based composites for high-performance lithium-ion battery separators. Electrochim Acta 167:396–403CrossRef

Liang J, Tan H, Xiao C, Zhou G, Guo S, Ding S (2015) Hydroxyl-riched halloysite clay nanotubes serving as substrate of NiO nanosheets for high-performance supercapacitor. J Power Sources 285:210–216CrossRef

Liao H, Hong H, Zhang H, Li Z (2016) Preparation of hydrophilic polyethylene/methylcellulose blend microporous membranes for separator of lithium-ion batteries. J Membrane Sci 498:147–157CrossRef

Liu Y, Liu M (2017) Conductive carboxylated styrene butadiene rubber composites by incorporation of polypyrrole-wrapped halloysite nanotubes. Compos Sci Technol 143:56–66CrossRef

Luo P, Zhao Y, Bing Z, Liu J, Yong Y, Liu J (2010) Study on the adsorption of neutral red from aqueous solution onto halloysite nanotubes. Water Res 44:1489–1497CrossRefPubMed

Pan R, Cheung O, Wang Z, Tammela P, Huo J, Lindh J, Edström K, Strømme M, Nyholm L (2016) Mesoporous Cladophora cellulose separators for lithium-ion batteries. J Power Sources 321:185–192CrossRef

Pan R, Wang Z, Rui S, Lindh J, Kristina Edström K, Strømme M, Nyholm L (2017) Thickness difference induced pore structure variations in cellulosic separators for lithium-ion batteries. Cellulose 24:2903–2911CrossRef

Ryou MH, Yong ML, Park JK, Choi JW (2011) Mussel-inspired polydopamine-treated polyethylene separators for high-power li-ion batteries. Adv Mater 23:3066–3070CrossRef

Schadler LSG, Giannaris SC, Ajayan PM (1998) Load transfer in carbon nanotube epoxy composites. Appl Phys Lett 73:3842–3844CrossRef

Sheng J, Tong S, He Z, Yang R (2017) Recent developments of cellulose materials for lithium-ion battery separators. Cellulose 24:4103–4122CrossRef

Tang Y, Ye L, Zhang Z, Friedrich K (2013) Interlaminar fracture toughness and CAI strength of fibre-reinforced composites with nanoparticles? A review. Compos Sci Technol 86:26–37CrossRef

Wang H, Zhang S, Zhu M, Sui G, Yang X (2018) Remarkable heat-resistant halloysite nanotube/polyetherimide composite nanofiber membranes for high performance gel polymer electrolyte in lithium ion batteries. J Electroanal Chem 808:303–310CrossRef

Weng B, Xu F, Alcoutlabi M, Mao Y, Lozano K (2015) Fibrous cellulose membrane mass produced via forcespinning^® for lithium-ion battery separators. Cellulose 22:1311–1320CrossRef

Xiao S, Wang F, Yang Y, Chang Z, Wu Y (2014) An environmentally friendly and economic membrane based on cellulose as a gel polymer electrolyte for lithium ion batteries. RSC Adv 4:76–81CrossRef

Xiao C, Yuan F, Zhang H, Yang H, Yang J, Sun D (2016) Recent approaches and future prospects of bacterial cellulose-based electroconductive materials. J Mater Sci 51:5573–5588CrossRef

Xu Q, Kong Q, Liu Z, Wang X, Liu R, Zhang J, Yue L, Duan Y, Cui G (2014a) Cellulose/polysulfonamide composite membrane as a high performance lithium-ion battery separator. ACS Sustain Chem Eng 2:194–199CrossRef

Xu Q, Kong Q, Liu Z, Zhang J, Wang X, Liu R, Yue L, Cui G (2014b) Polydopamine-coated cellulose microfibrillated membrane as high performance lithium-ion battery separator. RSC Adv 4:7845–7850CrossRef

Xu Q, Wei C, Fan L, Peng S, Xu W, Xu J (2017) A bacterial cellulose/Al₂O₃ nanofibrous composite membrane for a lithium-ion battery separator. Cellulose 24:1889–1899CrossRef

Xue J, Niu Y, Gong M, Shi R, Chen D, Zhang L, Lvov Y (2015) Electrospun microfiber membranes embedded with drug-loaded clay nanotubes for sustained antimicrobial protection. ACS Nano 9:1600–1612CrossRefPubMed

Yang M, Hou J (2014) Membranes in lithium ion batteries. Membranes 2:367–383CrossRef

Yang C, Liu P, Zhao Y (2010) Preparation and characterization of coaxial halloysite/polypyrrole tubular nanocomposites for electrochemical energy storage. Electrochem Acta 55:6857–6864CrossRef

Yanilmaz M, Lu Y, Dirican M, Fu K, Zhang X (2014) Nanoparticle-on-nanofiber hybrid membrane separators for lithium-ion batteries via combining electrospraying and electrospinning techniques. J Membrane Sci 456:57–65CrossRef

Yanilmaz M, Yao L, Ying L, Zhang X (2015) SiO₂/polyacrylonitrile membranes via centrifugal spinning as a separator for Li-ion batteries. J Power Sources 273:1114–1119CrossRef

Yuan P, Southon PD, Liu Z, Green MER, Hook JM, Antill SJ, Kepert CJ (2008) Functionalization of halloysite clay nanotubes by grafting with γ-aminopropyltriethoxysilane. J Phys Chem C 112:15742–15751CrossRef

Yvonne T, Zhang C, Changhuan O, Edison N (2014) Properties of electrospun PVDF/PMMA/CA membrane as lithium based battery separator. Cellulose 21:2811–2818CrossRef

Zhang F, Ma X, Cao C, Li J, Zhu Y (2014) Poly(vinylidene fluoride)/SiO₂ composite membranes prepared by electrospinning and their excellent properties for nonwoven separators for lithium-ion batteries. J Power Sources 251:423–431CrossRef

Zhao Y, Wang S, Guo Q, Shen M, Shi X (2013) Hemocompatibility of electrospun halloysite nanotube- and carbon nanotube-doped composite poly(lactic-co-glycolic acid) nanofibers. J Appl Polym Sci 127:4825–4832CrossRef

Zhu Y, Xiao S, Shi Y, Yang Y, Wu Y (2013) A trilayer poly(vinylidene fluoride)/polyborate/poly(vinylidene fluoride) gel polymer electrolyte with good performance for lithium ion batteries. J Mater Chem A 1:7790–7797CrossRef

Zhu M, Lan J, Tan C, Sui G, Yang X (2016) Degradable cellulose acetate/poly-L-lacticacid/halloysite nanotube composite nanofiber membranes with outstanding performance for gel polymer electrolytes. J Mater Chem A 4:12136–12143CrossRef

Zolin L, Destro M, Chaussy D, Penazzi N, Gerbaldi C, Beneventi D (2015) Aqueous processing of paper separators by filtration dewatering: towards Li-ion paper batteries. J Mater Chem A 28:14894–14901CrossRef

Titel: Composite nanofiber membranes of bacterial cellulose/halloysite nanotubes as lithium ion battery separators
verfasst von: Chenghao Huang
Hui Ji
Bin Guo
Lei Luo
Weilin Xu
Jinping Li
Jie Xu
Publikationsdatum: 06.06.2019
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 11/2019
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-019-02558-y

Springer Professional

Abstract

Graphic abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Springer Professional "Wirtschaft+Technik"

Weitere Artikel der Ausgabe 11/2019

Smart cellulose-derived magnetic hydrogel with rapid swelling and deswelling properties for remotely controlled drug release

Electrospinning of photo-responsive Azo-Cellulose: towards smart fibrous materials

Localization of cellulosic fines in paper via fluorescent labeling

Evaluation of properties and specific energy consumption of spinifex-derived lignocellulose fibers produced using different mechanical processes

Characterization of cellulose microfibrils, cellulose molecules, and hemicelluloses in buckwheat and rice husks

Effect of the particle size of magnesium hydroxide on the cellulose polymerization during the oxygen delignification of radiata pine kraft pulp