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24.02.2023 | Original Article

Direct reuse of oxide scrap from retired lithium-ion batteries: advanced cathode materials for sodium-ion batteries

verfasst von: Miao Du, Kai-Di Du, Jin-Zhi Guo, Yan Liu, Vanchiappan Aravindan, Jia-Lin Yang, Kai-Yang Zhang, Zhen-Yi Gu, Xiao-Tong Wang, Xing-Long Wu

Erschienen in: Rare Metals | Ausgabe 5/2023

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Abstract

The direct reuse of retired lithium-ion batteries (LIBs) cathode materials is one of the optimum choices for “waste-to-wealth” by virtue of sustainable and high economic efficiency. Considering the harmfulness of retired LIBs and the serious shortage of lithium resources, in this work, the spent oxide cathode materials after simple treatment are directly applied to the sodium-ion batteries (SIBs) and exhibit promising application possibilities in advanced SIBs. The spent oxide cathode shows an appropriate initial discharge capacity of 109 mAh·g⁻¹ and exhibits transition and activation processes at a current density of 25 mA·g⁻¹. Further, it demonstrates decent cycle performance and comparatively good electrode kinetics performance (the apparent ion diffusion coefficient at steady state is about 1 × 10^–12 cm²·s⁻¹). The “waste-to-wealth” concept of this work provides an economical and sustainable strategy for directly reusing the retired LIBs and supplies a large amount of raw material for the large-scale application of SIBs.

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Vorheriger Artikel Reasonable suppression of polysulfides/polyselenides shuttle based on MXene in Na-SeS2 batteries

Nächster Artikel Application of silica-alumina as hydrothermally stable supports for Pt catalysts for acid-assisted soot oxidation

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[1]

Lin J, Fan E, Zhang X, Li Z, Dai Y, Chen R, Wu F, Li L. Sustainable upcycling of spent lithium-ion batteries cathode materials: stabilization by in situ Li/Mn disorder. Adv Energy Mater. 2022;12(26):2201174. https://doi.org/10.1002/aenm.202201174.CrossRef

[2]

Tao R, Xing P, Li H, Cun Z, Sun Z, Wu Y. In situ reduction of cathode material by organics and anode graphite without additive to recycle spent electric vehicle LiMn₂O₄ batteries. J Power Sources. 2022;520:230827. https://doi.org/10.1016/j.jpowsour.2021.230827.CrossRef

[3]

Zhang Y, Li X, Chen X, Koivula R, Xu J. Tunnel manganese oxides prepared using recovered LiMn₂O₄ from spent lithium-ion batteries: Co adsorption behavior and mechanism. J Hazard Mater. 2022;425:127957. https://doi.org/10.1016/j.jhazmat.2021.127957.CrossRef

[4]

Li JL, Qin W, Xie JP, Lin R, Wang ZL, Pan LK, Mai WJ. Rational design of MoS₂-reduced graphene oxide sponges as free-standing anodes for sodium-ion batteries. Chem Eng J. 2018;332:260. https://doi.org/10.1016/j.cej.2017.09.088.CrossRef

[5]

Du K, Meng Y, Zhao X, Wang X, Luo X, Zhang W, Wu X. A unique co-recovery strategy of cathode and anode from spent LiFePO₄ battery. Sci China Mater. 2021;65(3):637. https://doi.org/10.1007/s40843-021-1772-6.CrossRef

[6]

Lin J, Fan E, Zhang X, Chen R, Wu F, Li L. Sustainable recycling of cathode scrap towards high-performance anode materials for Li-ion batteries. Adv Energy Mater. 2021;12(2):2103288. https://doi.org/10.1002/aenm.202103288.CrossRef

[7]

Du M, Guo J, Zheng S, Liu Y, Yang JL, Zhang K, Gu Z, Wang X, Wu XL. Direct reuse of LiFePO₄ cathode materials from spent lithium-ion batteries: extracting Li from brine. Chinese Chem Lett. 2022. https://doi.org/10.1016/j.cclet.2022.07.049.CrossRef

[8]

Yang J, Zhao X, Li WH, Liang H, Gu Z, Liu Y, Du M, Wu XL. Advanced cathode for dual-ion batteries: waste-to-wealth reuse of spent graphite from lithium-ion batteries. eScience. 2022;2(1):95. https://doi.org/10.1016/j.esci.2021.11.001.CrossRef

[9]

Liang H, Gu Z, Zheng X, Li W, Zhu L, Sun Z, Meng Y, Yu H, Hou X, Wu X. Tempura-like carbon/carbon composite as advanced anode materials for K-ion batteries. J Energy Chem. 2021;59:589.CrossRef

[10]

Meng Y, Liang H, Zhao C, Li W, Gu Z, Yu M, Zhao B, Hou X, Wu X. Concurrent recycling chemistry for cathode/anode in spent graphite/LiFePO₄ batteries: designing a unique cation/anion-co-workable dual-ion battery. J Energy Chem. 2022;64:166. https://doi.org/10.1016/j.jechem.2021.04.047.CrossRef

[11]

He YD, Du YF, Xin SY. Mechanism of hydrogen formation in aluminum solution affected by water carried by raw material. Chin J Rare Met. 2020;44(7):762. https://doi.org/10.13373/j.cnki.cjrm.XY18120022.html.CrossRef

[12]

Muhammad N, Mohtar M, Ramli M, Shafie S, Shaban S, Yusof Y. Enhancement of dye sensitized solar cell by adsorption of graphene quantum dots. Int J Min Met Mater. 2020;8(3):126. https://doi.org/10.1007/s12613-020-2115-z.CrossRef

[13]

Liu F, Zhang Z, Ye S, Yao Y, Yu Y. Challenges and improvement strategies progress of lithium metal anode. Acta Phys-Chim Sin. 2020;37(1):2006021.CrossRef

[14]

Xu P, Dai Q, Gao H, Liu H, Zhang M, Li M, Chen Y, An K, Meng YS, Liu P, Li Y, Spangenberger JS, Gaines L, Lu J, Chen Z. Efficient direct recycling of lithium-ion battery cathodes by targeted healing. Joule. 2020;4(12):2609. https://doi.org/10.1016/j.joule.2020.10.008.CrossRef

[15]

Zhang K, Xu Y, Lin Y, Xiong Y, Huang J, Wang L, Peng M, Hu T, Yuan K, Chen Y. Enriching redox active sites by interconnected nanowalls-like nickel cobalt phospho-sulfide nanosheets for high performance supercapacitors. Chinese Chem Lett. 2021;32(11):3553. https://doi.org/10.1016/j.cclet.2021.02.034.CrossRef

[16]

Zhang Y, Zhang Y, Zhang Y, Dong P, Meng Q, Xu M. Novel efficient regeneration of high-performance Li_1.2[Mn_0.56Ni_0.16Co_0.08]O₂ cathode materials from spent LiMn₂O₄ batteries. J Alloy Compd. 2019;783:357. https://doi.org/10.1016/j.jallcom.2018.12.359.CrossRef

[17]

Du K, Ang EH, Wu X, Liu Y. Progresses in sustainable recycling technology of spent lithium-ion batteries. Energy Environ Mater. 2022. https://doi.org/10.1002/eem2.12271.CrossRef

[18]

Gao H, Yan Q, Xu P, Liu H, Li M, Liu P, Luo J, Chen Z. Efficient direct recycling of degraded LiMn₂O₄ cathodes by one-step hydrothermal relithiation. ACS Appl Mater Interfaces. 2020;12(46):51546. https://doi.org/10.1021/acsami.0c15704.CrossRef

[19]

Zhang ZW, Zhong XB, Zhang YH, Tang MY, Li SX, Zhang HH, Hu PF, Liang JF. Scalable synthesis of mesoporous FeS₂ nanorods as high-performance anode materials for sodium-ion batteries. Rare Met. 2022;41(1):21. https://doi.org/10.1007/s12598-021-01835-9.CrossRef

[20]

Sun L, Liu B, Wu T, Wang G, Huang Q, Su Y, Wu F. Hydrometallurgical recycling of valuable metals from spent lithium-ion batteries by reductive leaching with stannous chloride. Int J Min Met Mater. 2021;28(6):991. https://doi.org/10.1007/s12613-020-2115-z.CrossRef

[21]

Wang XT, Gu ZY, Ang EH, Zhao XX, Wu XL, Liu Y. Prospects for managing end-of-life lithium-ion batteries: present and future. Interdisciplinary Materials. 2022;1(3):417. https://doi.org/10.1002/idm2.12041.CrossRef

[22]

Makuza B, Tian Q, Guo X, Chattopadhyay K, Yu D. Pyrometallurgical options for recycling spent lithium-ion batteries: a comprehensive review. J Power Sources. 2021;491:229622. https://doi.org/10.1016/j.jpowsour.2021.229622.CrossRef

[23]

Harper G, Sommerville R, Kendrick E, Driscoll L, Slater P, Stolkin R, Walton A, Christensen P, Heidrich O, Lambert S, Abbott A, Ryder K, Gaines L, Anderson P. Recycling lithium-ion batteries from electric vehicles. Nature. 2019;575(7781):75. https://doi.org/10.1038/s41586-019-1682-5.CrossRef

[24]

Zheng S, Wang X, Wu X, Xu H. Advances and challenges on recycling the electrode and electrolyte materials in spent lithium-ion batteries. Mater Lab. 2022;1:220036. https://doi.org/10.54227/mlab.20220036.CrossRef

[25]

Gupta S, Pant K, Corder G. An environmentally benign closed-loop process for the selective recovery of valuable metals from industrial end-of-life lithium-ion batteries. Chem Eng J. 2022;446:137397. https://doi.org/10.1016/j.cej.2022.137397.CrossRef

[26]

Zhao HS, Qi YL, Liang K, Zhu WK, Wu HB, Li JB, Ren YR. Phosphorus-doping and oxygen vacancy endowing anatase TiO₂ with excellent sodium storage performance. Rare Met. 2022;41(4):1284. https://doi.org/10.1007/s12598-021-01864-4.CrossRef

[27]

Wang J, Zhang Q, Sheng J, Liang Z, Maa J, Chenb Y, Zhou G, Chen H. Direct and green repairing of degraded LiCoO₂ for reuse in lithiumion batteries. Natl Sci Rev. 2022;9(8):nwac097. https://doi.org/10.1093/nsr/nwac097.CrossRef

[28]

Nie X, Xi X, Yang Y, Ning Q, Guo JZ, Wang M, Gu Z, Wu X. Recycled LiMn₂O₄ from the spent lithium ion batteries as cathode material for sodium ion batteries: electrochemical properties, structural evolution and electrode kinetics. Electrochim Acta. 2019;320:134626. https://doi.org/10.1016/j.electacta.2019.134626.CrossRef

[29]

Gangaja B, Nair S, Santhanagopalan D. Reuse, recycle, and regeneration of LiFePO₄ cathode from spent lithium-ion batteries for rechargeable lithium- and sodium-ion batteries. ACS Sustain Chem Eng. 2021;9(13):4711. https://doi.org/10.1021/acssuschemeng.0c08487.CrossRef

[30]

Wang D, Cai P, Zou GQ, Hou HS, Ji XB, Tian Y, Long Z. Ultra-stable carbon-coated sodium vanadium phosphate as cathode material for sodium-ion battery. Rare Met. 2022;41(1):115. https://doi.org/10.1007/s12598-021-01743-y.CrossRef

[31]

Jiao M, Zhang Q, Ye C, Liu Z, Zhong X, Wang J, Li C, Dai L, Zhou G, Cheng H. Recycling spent LiNi_1-_x_-_yMn_xCoyO₂ cathodes to bifunctional NiMnCo catalysts for zinc-air batteries. P Natl Acad Sci USA. 2022;119(20): e2202202119. https://doi.org/10.1073/pnas.2202202119.CrossRef

[32]

Natarajan S, Aravindan V. Burgeoning prospects of spent lithium- ion batteries in multifarious applications. Adv Energy Mater. 2018;8(33):1802303. https://doi.org/10.1002/aenm.201802303.CrossRef

[33]

Li W, Han C, Wang W, Gebert F, Chou S, Liu H, Zhang X, Dou S. Commercial prospects of existing cathode materials for sodium ion storage. Adv Energy Mater. 2017;7(24):1700274. https://doi.org/10.1002/aenm.201700274.CrossRef

[34]

Li Y, Zhou Q, Weng S, Ding F, Qi X, Lu J, Li Y, Zhang X, Rong X, Lu Y, Wang X, Xiao R, Li H, Huang X, Chen L, Hu YS. Interfacial engineering to achieve an energy density of over 200 Wh kg⁻¹ in sodium batteries. Nat Energy. 2022;7(6):511. https://doi.org/10.1038/s41560-022-01033-6.CrossRef

[35]

Heng Y, Gu Z, Guo J, Wu X. Research progresses on vanadium-based cathode materials for aqueous zinc-ion batteries. Acta Phys-Chim Sin. 2020;37(3):2005013. https://doi.org/10.3866/PKU.WHXB202005013.CrossRef

[36]

Gu Z, Guo J, Zhao X, Wang T, Xie D, Sun Z, Zhao C, Liang H, Li W, Wu X. High-ionicity fluorophosphate lattice via aliovalent substitution as advanced cathode materials in sodium-ion batteries. InfoMat. 2021;3(6):694. https://doi.org/10.1002/inf2.12184.CrossRef

[37]

Li JB, Ding ZB, Pan LK, Li JL, Wang CY, Wang GX. Facile self-templating synthesis of layered carbon with N, S dual doping for highly efficient sodium storage. Carbon. 2021;173:31. https://doi.org/10.1016/j.carbon.2020.10.092.CrossRef

[38]

Zhang YJ, Li JL, Ma L, Li HB, Xu XT, Liu XJ, Lu T, Pan LK. Insights into the storage mechanism of 3D nanoflower-like V₃S₄ anode in sodium-ion batteries. Chem Eng J. 2022;427: 130936. https://doi.org/10.1016/j.cej.2021.130936.CrossRef

[39]

Yang M, Sun Z, Nie P, Yu H, Zhao C, Yu M, Luo Z, Geng H, Wu X. SbPS₄: a novel anode for high-performance sodium-ion batteries. Chinese Chem Lett. 2022;33(1):470. https://doi.org/10.1016/j.cclet.2021.06.065.CrossRef

[40]

Kong Q, Wu X, Guo Y, Wang Y. Preparation of ZnO nanostructures by thermal degradation of zinc alginate fibers. Acta Phys-Chim Sin. 2008;24(12):2179. https://doi.org/10.3866/PKU.WHXB20081206.CrossRef

[41]

Liu K, Yang S, Lai F, Wang H, Huang Y, Zheng F, Wang S, Zhang X, Li Q. Innovative electrochemical strategy to recovery of cathode and efficient lithium leaching from spent lithium-ion batteries. ACS Appl Energ Mater. 2020;3(5):4767. https://doi.org/10.1021/acsaem.0c00395.CrossRef

[42]

Liang Q, Yue H, Zhou W, Wei Q, Ru Q, Huang Y, Lou H, Chen F, Hou X. Structure recovery and recycling of used LiCoO₂ cathode material. Chem Eur J. 2021;27(57):14225. https://doi.org/10.1002/chem.202102015.CrossRef

[43]

Zhou S, Fei Z, Meng Q, Dong P, Zhang Y, Zhang M. Collaborative regeneration of structural evolution for high- performance of LiCoO₂ materials from spent lithium-ion batteries. ACS Appl Energ Mater. 2021;4(11):12677. https://doi.org/10.1021/acsaem.1c02396.CrossRef

[44]

Fan M, Meng Q, Chang X, Gu C, Meng X, Yin Y, Li H, Wan L, Guo Y. In situ electrochemical regeneration of degraded lifepo₄ electrode with functionalized prelithiation separator. Adv Energy Mater. 2022;12(18):2103630. https://doi.org/10.1002/aenm.202103630.CrossRef

[45]

Zhou S, Zhang Y, Meng Q, Dong P, Fei Z, Li Q. Recycling of LiCoO₂ cathode material from spent lithium ion batteries by ultrasonic enhanced leaching and one-step regeneration. J Environ Manage. 2021;277:111426. https://doi.org/10.1016/j.jenvman.2020.111426.CrossRef

[46]

Meng Q, Duan J, Zhang Y, Dong P. Novel efficient and environmentally friendly recovering of high performance nano-LiMnPO₄/C cathode powders from spent LiMn₂O₄ batteries. J Ind Eng Chem. 2019;80:633. https://doi.org/10.1016/j.jiec.2019.08.051.CrossRef

[47]

Zuo C, Hu Z, Qi R, Liu J, Li Z, Lu J, Dong C, Yang K, Huang W, Chen C, Song Z, Song S, Yu Y, Zheng J, Pan F. Double the capacity of manganese spinel for lithium-ion storage by suppression of cooperative Jahn-Teller distortion. Adv Energy Mater. 2020;10(34):2000363. https://doi.org/10.1002/aenm.202000363.CrossRef

[48]

Zhao C, Guo J, Gu Z, Wang X, Zhao X, Li W, Yu H, Wu X. Flexible quasi-solid-state sodium-ion full battery with ultralong cycle life, high energy density and high-rate capability. Nano Res. 2021;15(2):925. https://doi.org/10.1007/s12274-021-3577-7.CrossRef

[49]

Gu Z, Guo J, Cao J, Wang X, Zhao X, Zheng X, Li W, Sun Z, Liang H, Wu X. An advanced high-entropy fluorophosphate cathode for sodium-ion batteries with increased working voltage and energy Density. Adv Mater. 2022;34(14): e2110108. https://doi.org/10.1002/adma.202110108.CrossRef

Titel: Direct reuse of oxide scrap from retired lithium-ion batteries: advanced cathode materials for sodium-ion batteries
verfasst von: Miao Du
Kai-Di Du
Jin-Zhi Guo
Yan Liu
Vanchiappan Aravindan
Jia-Lin Yang
Kai-Yang Zhang
Zhen-Yi Gu
Xiao-Tong Wang
Xing-Long Wu
Publikationsdatum: 24.02.2023
Verlag: Nonferrous Metals Society of China
Erschienen in: Rare Metals / Ausgabe 5/2023
Print ISSN: 1001-0521
Elektronische ISSN: 1867-7185
DOI: https://doi.org/10.1007/s12598-022-02230-8

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