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15.11.2019 | Original Research

Effects of hemicellulose content on TEMPO-mediated selective oxidation, and the properties of films prepared from bleached chemical pulp

verfasst von: Changmei Lin, Qidu Deng, Yuantao Hu, Liulian Huang, Yonghao Ni, Shilin Cao, Xiaojuan Ma

Erschienen in: Cellulose | Ausgabe 2/2020

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Abstract

In this work, chemical pulp was used to prepare hazy transparent films, and the effects of hemicellulose content on carboxyl group formation during TEMPO-(2,2,6,6-tetramethylpiperidine-1-oxyl) mediated oxidation, and the properties of the film prepared from the chemical pulp were evaluated. The hemicellulose content exhibited a negligible effect on carboxyl content formation, while prior alkaline extraction significantly enhanced the selective oxidation indicating a substantial increase of carboxyl group. The prior alkaline extraction and TEMPO-mediated oxidation initiated severe hemicellulose removal and fiber swelling, and therefore promoted the subsequent ultrasonic fibrillation. The optical transmittance of the film prepared from the chemical pulp was near-constant at ~ 89%, while the haze increased slightly from 85 to 94%, when the hemicellulose content was increased from 6.7 to 19.2%. Conversely, the presence of hemicellulose significantly impaired the film surface properties, possibly due to the large size of the cellulose fibers.

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Vorheriger Artikel High-performance solid-state supercapacitors with designable patterns based on used newspaper

Nächster Artikel Silicone quaternary ammonium salt based nanocomposite: a long-acting antibacterial cotton fabric finishing agent with good softness and air permeability

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Titel: Effects of hemicellulose content on TEMPO-mediated selective oxidation, and the properties of films prepared from bleached chemical pulp
verfasst von: Changmei Lin
Qidu Deng
Yuantao Hu
Liulian Huang
Yonghao Ni
Shilin Cao
Xiaojuan Ma
Publikationsdatum: 15.11.2019
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 2/2020
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-019-02844-9

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