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Biomass Conversion and Biorefinery

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09.03.2020 | Original Article

Enhanced catalytic conversion of 5-hydroxymethylfurfural to 2,5-diformylfuran by HKUST-1/TEMPO under microwave irradiation

verfasst von: Jia-Yin Lin, Bui Xuan Thanh, Eilhann Kwon, Kun-Yi Andrew Lin

Erschienen in: Biomass Conversion and Biorefinery | Ausgabe 6/2021

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Abstract

For developing more effective oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-diformylfuran (DFF), a Cu-based metal organic framework, HKUST-1, is proposed to incorporate with 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) under microwave (MW) for enhancing HMF oxidation to DFF. In comparison to oxidation of HMF by a conventional heating (CH), MW is validated to shorten reaction time (< 1 h) and enhance HMF conversion (> 99%) and yield of DFF (> 99%). HKUST-1 is reusable for HMF conversion using MW over multiple cycles. These results indicate that HKUST-1 is a highly effective catalyst for HMF conversion, and MW further enhances HMF conversion and increases yield of DFF significantly.

Vorheriger Artikel Geospatial investigation of physicochemical properties and thermodynamic parameters of biomass residue for energy generation

Nächster Artikel Torrefaction of biomass pellets using the thermogravimetric analyser

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Titel: Enhanced catalytic conversion of 5-hydroxymethylfurfural to 2,5-diformylfuran by HKUST-1/TEMPO under microwave irradiation
verfasst von: Jia-Yin Lin
Bui Xuan Thanh
Eilhann Kwon
Kun-Yi Andrew Lin
Publikationsdatum: 09.03.2020
Verlag: Springer Berlin Heidelberg
Erschienen in: Biomass Conversion and Biorefinery / Ausgabe 6/2021
Print ISSN: 2190-6815
Elektronische ISSN: 2190-6823
DOI: https://doi.org/10.1007/s13399-020-00648-7

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