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Erschienen in: Journal of Materials Science 19/2019

05.07.2019 | Electronic materials

Enhanced electroluminescent performance by doping organic conjugated ionic compound into graphene oxide hole-injecting layer

verfasst von: Pan Liu, Junna Liu, Bingbing Zhang, Wansheng Zong, Shengang Xu, Yingliang Liu, Shaokui Cao

Erschienen in: Journal of Materials Science | Ausgabe 19/2019

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Abstract

Organic conjugated ionic compound 10,10′-dimethyl-9,9′-biacridinum bis(monomethyl terephthalate) (MMT) is doped into graphene oxide (GO) hole-injecting layer to enhance the electroluminescent performance of organic light-emitting diodes (OLEDs). The composite films are characterized in detail by FTIR, SEM, XPS, and UPS. The XPS result indicates the evident ππ stacking interaction between the conjugated structures of GO and MMT. The UPS result shows the decrease in ionization potential of GO due to MMT-doping. As a result, at the optimal doping ratio of 4 wt%, the maximum luminous efficiency of OLEDs is increased to 15.46 cd/A, which is 3.4 times as 4.55 cd/A of the control device. Besides, the luminance is also enhanced to 19950 cd/m2, while the turn-on voltage is decreased to 2.5 V. Doping organic conjugated ionic compound into the GO hole-injecting layer is a facile and efficient approach to improve the electroluminescent performance of OLEDs.

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Literatur
1.
Zurück zum Zitat Walzer K, Maennig B, Pfeiffer M, Leo K (2007) Highly efficient organic devices based on electrically doped transport layers. Chem Rev 107(4):1233–1271CrossRef Walzer K, Maennig B, Pfeiffer M, Leo K (2007) Highly efficient organic devices based on electrically doped transport layers. Chem Rev 107(4):1233–1271CrossRef
2.
Zurück zum Zitat Liam SCP, MacLeod BA, Ginger DS (2008) The changing face of PEDOT:PSS films: substrate, bias, and processing effects on vertical charge transport. J Phys Chem C 112(21):7922–7927CrossRef Liam SCP, MacLeod BA, Ginger DS (2008) The changing face of PEDOT:PSS films: substrate, bias, and processing effects on vertical charge transport. J Phys Chem C 112(21):7922–7927CrossRef
3.
Zurück zum Zitat Hau SK, Yip HL, Zou JY, Jen AK (2009) Indium tin oxide-free semi-transparent inverted polymer solar cells using conducting polymer as both bottom and top electrodes. Org Electron 10(7):1401–1407CrossRef Hau SK, Yip HL, Zou JY, Jen AK (2009) Indium tin oxide-free semi-transparent inverted polymer solar cells using conducting polymer as both bottom and top electrodes. Org Electron 10(7):1401–1407CrossRef
4.
Zurück zum Zitat Wong KW, Yip HL, Luo Y, Wong KY, Lau KM, Chow HF, Gao ZQ, Yeung WL, Chang CC (2002) Blocking reactions between indium–tin oxide and poly (3,4-ethylene dioxythiophene):poly(styrene sulphonate) with a self-assembly monolayer. Appl Phys Lett 80(15):2788–2790CrossRef Wong KW, Yip HL, Luo Y, Wong KY, Lau KM, Chow HF, Gao ZQ, Yeung WL, Chang CC (2002) Blocking reactions between indium–tin oxide and poly (3,4-ethylene dioxythiophene):poly(styrene sulphonate) with a self-assembly monolayer. Appl Phys Lett 80(15):2788–2790CrossRef
5.
Zurück zum Zitat Kion N, Morton VM, Suren VG, Frederik CK (2010) Degradation patterns in water and oxygen of an inverted polymer solar cell. J Am Chem Soc 47(132):16883–16892 Kion N, Morton VM, Suren VG, Frederik CK (2010) Degradation patterns in water and oxygen of an inverted polymer solar cell. J Am Chem Soc 47(132):16883–16892
6.
Zurück zum Zitat Li SS, Tu KH, Lin CC, Chen CW, Manish C (2010) Solution-processable graphene oxide as an efficient hole transport layer in polymer solar cell. ACS Nano 4(6):3169–3174CrossRef Li SS, Tu KH, Lin CC, Chen CW, Manish C (2010) Solution-processable graphene oxide as an efficient hole transport layer in polymer solar cell. ACS Nano 4(6):3169–3174CrossRef
7.
Zurück zum Zitat Lee BR, Kim J, Kang D, Lee DW, Ko SJ, Lee HJ, Lee CL, Kim JY, Shin HC, Song MH (2012) Highly efficient polymer light-emitting diodes using graphene oxide as a hole transport layer. ACS Nano 6(4):2984–2991CrossRef Lee BR, Kim J, Kang D, Lee DW, Ko SJ, Lee HJ, Lee CL, Kim JY, Shin HC, Song MH (2012) Highly efficient polymer light-emitting diodes using graphene oxide as a hole transport layer. ACS Nano 6(4):2984–2991CrossRef
8.
Zurück zum Zitat Scholes GD, Rumbles G (2006) Excitons in nanoscale systems. Nat Mater 9(5):683–696CrossRef Scholes GD, Rumbles G (2006) Excitons in nanoscale systems. Nat Mater 9(5):683–696CrossRef
9.
Zurück zum Zitat Liu CC, Xu JK, Lu BY, Yue RR, Kong FF (2012) Simultaneous increases in electrical conductivity and Seebeck coefficient of PEDOT:PSS films by adding ionic liquids into a polymer solution. J Electron Mater 41(4):639–645CrossRef Liu CC, Xu JK, Lu BY, Yue RR, Kong FF (2012) Simultaneous increases in electrical conductivity and Seebeck coefficient of PEDOT:PSS films by adding ionic liquids into a polymer solution. J Electron Mater 41(4):639–645CrossRef
10.
Zurück zum Zitat Lee SK, Lee KK (2010) Conductivity enhancement of PEDOT:PSS films with ionic liquids as dopants. Adv Mater Res 93–94:501–504CrossRef Lee SK, Lee KK (2010) Conductivity enhancement of PEDOT:PSS films with ionic liquids as dopants. Adv Mater Res 93–94:501–504CrossRef
11.
Zurück zum Zitat Döbbelin M, Marcilla R, Salsamendi M, Pozo-Gonzalo C, Carrasco PM, Pomposo JA, Mecerreyes D (2007) Influnce of ionic liquids on the electrical conductivity and morphology of PEDOT:PSS films. Chem Mater 19(9):2147–2149CrossRef Döbbelin M, Marcilla R, Salsamendi M, Pozo-Gonzalo C, Carrasco PM, Pomposo JA, Mecerreyes D (2007) Influnce of ionic liquids on the electrical conductivity and morphology of PEDOT:PSS films. Chem Mater 19(9):2147–2149CrossRef
12.
Zurück zum Zitat Chantal B, Ludovic M, Ahmed MA, Lawrence AH (2012) Highly conductive poly(3,4-ethylenedioxy thiophene):poly(styrenesulfonate) films using 1-ethyl-3-methylimidazolium tetracyanoborate ionic liquid. Adv Funct Mater 22:2723–2727CrossRef Chantal B, Ludovic M, Ahmed MA, Lawrence AH (2012) Highly conductive poly(3,4-ethylenedioxy thiophene):poly(styrenesulfonate) films using 1-ethyl-3-methylimidazolium tetracyanoborate ionic liquid. Adv Funct Mater 22:2723–2727CrossRef
13.
Zurück zum Zitat Liu YL, Zhao Y, Xu SG, Cao SK (2015) Enhanced electroluminescent efficiency with ionic liquid doped into PEDOT:PSS hole-injecting layer. Polymer 77:42–47CrossRef Liu YL, Zhao Y, Xu SG, Cao SK (2015) Enhanced electroluminescent efficiency with ionic liquid doped into PEDOT:PSS hole-injecting layer. Polymer 77:42–47CrossRef
14.
Zurück zum Zitat Li CT, Lee CP, Fan MS, Chen PY, Vittal R, Ho KC (2014) Ionic liquid-doped poly(3,4-ethylenedioxy thiophene) counter electrodes for dye-sensitized solar cells: cationic and anionic effects on the photovoltaic performance. Nano Energy 9:1–14CrossRef Li CT, Lee CP, Fan MS, Chen PY, Vittal R, Ho KC (2014) Ionic liquid-doped poly(3,4-ethylenedioxy thiophene) counter electrodes for dye-sensitized solar cells: cationic and anionic effects on the photovoltaic performance. Nano Energy 9:1–14CrossRef
15.
Zurück zum Zitat Balandin AA, Ghosh S, Bao W, Calizo A, Teweldebrhan D, Miao F, Lau CN (2008) Superior thermal conductivity of single-layer graphene. Nano Lett 8(3):902–907CrossRef Balandin AA, Ghosh S, Bao W, Calizo A, Teweldebrhan D, Miao F, Lau CN (2008) Superior thermal conductivity of single-layer graphene. Nano Lett 8(3):902–907CrossRef
16.
Zurück zum Zitat Lee C, Wei X, Kysar JW, Honen J (2008) Measurement of the elastic properties and intrinsic strength of monolayer graphene. Science 321(5887):385–388CrossRef Lee C, Wei X, Kysar JW, Honen J (2008) Measurement of the elastic properties and intrinsic strength of monolayer graphene. Science 321(5887):385–388CrossRef
17.
Zurück zum Zitat Cheng TC, Ku TA, Huang KY, Chou AS, Chang PH, Chao C, Yue CF, Liu CW, Wang PH, Wong KT, Wu CI (2018) Surface modification of graphene using HBC-6ImBr in solution-processed OLEDs. J Appl Phys 123(2):024303(1–7)CrossRef Cheng TC, Ku TA, Huang KY, Chou AS, Chang PH, Chao C, Yue CF, Liu CW, Wang PH, Wong KT, Wu CI (2018) Surface modification of graphene using HBC-6ImBr in solution-processed OLEDs. J Appl Phys 123(2):024303(1–7)CrossRef
18.
Zurück zum Zitat Kim DH, Kim TW (2018) Highly-efficient organic light-emitting devices based on poly(N, N′-bis-4-butylphenyl-N, N′-bisphenyl) benzidine: octadecylamine-graphene quantum dots. Org Electron 57:305–310CrossRef Kim DH, Kim TW (2018) Highly-efficient organic light-emitting devices based on poly(N, N′-bis-4-butylphenyl-N, N′-bisphenyl) benzidine: octadecylamine-graphene quantum dots. Org Electron 57:305–310CrossRef
19.
Zurück zum Zitat Jesuraj PJ, Parameshwari R, Kanthasamy K, Koch J, Pfnür H, Jeganathan K (2017) Hole injection enhancement in organic light emitting devices using plasma treated graphene oxide. Appl Surf Sci 397:144–151CrossRef Jesuraj PJ, Parameshwari R, Kanthasamy K, Koch J, Pfnür H, Jeganathan K (2017) Hole injection enhancement in organic light emitting devices using plasma treated graphene oxide. Appl Surf Sci 397:144–151CrossRef
20.
Zurück zum Zitat Dou L, Cui F, Yu Y, Khanarian G, Eaton SW, Yang Q, Resasco J, Schildknecht C, Schierle-Arndt K, Yang P (2016) Solution-processed copper/reduced-graphene-oxide core/shell nanowire transparent conductors. ACS Nano 10:2600–2606CrossRef Dou L, Cui F, Yu Y, Khanarian G, Eaton SW, Yang Q, Resasco J, Schildknecht C, Schierle-Arndt K, Yang P (2016) Solution-processed copper/reduced-graphene-oxide core/shell nanowire transparent conductors. ACS Nano 10:2600–2606CrossRef
21.
Zurück zum Zitat Varghese SS, Lonkar S, Singh KK, Swaminathan S, Abdala A (2016) Recent advances in graphene based gas sensors. Sens Actuators B Chem 218:160–183CrossRef Varghese SS, Lonkar S, Singh KK, Swaminathan S, Abdala A (2016) Recent advances in graphene based gas sensors. Sens Actuators B Chem 218:160–183CrossRef
22.
Zurück zum Zitat Kim Y, Lee EY, Lee HH, Seo TS (2017) Characteristics of reduced graphene oxide quantum dots for a flexible memory thin film transistor. ACS Appl Mater Interfaces 9:16375–16380CrossRef Kim Y, Lee EY, Lee HH, Seo TS (2017) Characteristics of reduced graphene oxide quantum dots for a flexible memory thin film transistor. ACS Appl Mater Interfaces 9:16375–16380CrossRef
23.
Zurück zum Zitat Hou ZQ, Wang ZY, Yang LX (2017) Nitrogen-doped reduced graphene oxide intertwined with V2O3 nanoflakes as self-supported electrodes for flexible all-solid-state supercapacitors. RSC Adv 7:25732–25739CrossRef Hou ZQ, Wang ZY, Yang LX (2017) Nitrogen-doped reduced graphene oxide intertwined with V2O3 nanoflakes as self-supported electrodes for flexible all-solid-state supercapacitors. RSC Adv 7:25732–25739CrossRef
24.
Zurück zum Zitat Rafique S, Abdullah SM, Shahid MM, Ansari MO, Sulaiman K (2017) Significantly improved photovoltaic performance in polymer bulk heterojunction solar cells with graphene oxide/PEDOT:PSS double decked hole transport layer. Sci Rep 7:39555CrossRef Rafique S, Abdullah SM, Shahid MM, Ansari MO, Sulaiman K (2017) Significantly improved photovoltaic performance in polymer bulk heterojunction solar cells with graphene oxide/PEDOT:PSS double decked hole transport layer. Sci Rep 7:39555CrossRef
25.
Zurück zum Zitat Hafsi B, Boubaker A, Guerin D, Lenfant S, Kalboussi A, Lmimouni K (2017) N-type polymeric organic flash memory device: effect of reduced graphene oxide floating gate. Org Electron 45:81–88CrossRef Hafsi B, Boubaker A, Guerin D, Lenfant S, Kalboussi A, Lmimouni K (2017) N-type polymeric organic flash memory device: effect of reduced graphene oxide floating gate. Org Electron 45:81–88CrossRef
26.
Zurück zum Zitat Gao Y, Yip HL, Chen KS, O’Malley KM, Acton O, Sun Y, Ting G, Chen H, Jen AKY (2011) Surface doping of conjugated polymers by graphene oxide and its application for organic electronic device. Adv Mater 23:1903–1908CrossRef Gao Y, Yip HL, Chen KS, O’Malley KM, Acton O, Sun Y, Ting G, Chen H, Jen AKY (2011) Surface doping of conjugated polymers by graphene oxide and its application for organic electronic device. Adv Mater 23:1903–1908CrossRef
27.
Zurück zum Zitat Fernández-Merino MJ, Guardia L, Paredes JI, Villar-Rodil S, Solís-Fernández P, Martínez-Alonso A, Tascón JMD (2010) Vitamin C is an ideal substitute for hydrazine in the reduction of graphene oxide suspensions. J Phys Chem C 114:6426–6432CrossRef Fernández-Merino MJ, Guardia L, Paredes JI, Villar-Rodil S, Solís-Fernández P, Martínez-Alonso A, Tascón JMD (2010) Vitamin C is an ideal substitute for hydrazine in the reduction of graphene oxide suspensions. J Phys Chem C 114:6426–6432CrossRef
28.
Zurück zum Zitat Ruben R, Juan IP, Silvia VR, Amelia MA, Juan MDT (2013) Towards full repair of defects in reduced graphene oxide films by two-step graphitization. Nano Res 6:216–233CrossRef Ruben R, Juan IP, Silvia VR, Amelia MA, Juan MDT (2013) Towards full repair of defects in reduced graphene oxide films by two-step graphitization. Nano Res 6:216–233CrossRef
29.
Zurück zum Zitat Stankovich S, Dikin DA, Piner RD, Kohlhaas KA, Kleinhammes A, Jia Y, Wu Y, Nguyen ST, Ruoff RS (2007) Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide. Carbon 45:1558–1565CrossRef Stankovich S, Dikin DA, Piner RD, Kohlhaas KA, Kleinhammes A, Jia Y, Wu Y, Nguyen ST, Ruoff RS (2007) Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide. Carbon 45:1558–1565CrossRef
30.
Zurück zum Zitat Liu Z, Botana J, Hermann A, Valdez S, Zurek E, Yan DD, Lin HQ, Miao MS (2018) Reactivity of He with ionic compounds under high pressure. Nat Commun 9:951CrossRef Liu Z, Botana J, Hermann A, Valdez S, Zurek E, Yan DD, Lin HQ, Miao MS (2018) Reactivity of He with ionic compounds under high pressure. Nat Commun 9:951CrossRef
31.
Zurück zum Zitat Xu Z, Chen LM, Chen MH (2009) Energy level alignment of poly(3-hexylthiophene): [6,6]-phenyl C61 butyric acid methyl ester bulk heterojunction. Appl Phys Lett 95:013301CrossRef Xu Z, Chen LM, Chen MH (2009) Energy level alignment of poly(3-hexylthiophene): [6,6]-phenyl C61 butyric acid methyl ester bulk heterojunction. Appl Phys Lett 95:013301CrossRef
32.
Zurück zum Zitat Rebeca M, David M, Gustaf W, Sergio B, Maria MRY, Franco C (2010) Light-emitting electrochemical cells using polymeric ionic liquid_polyfluorene blends as luminescent material. Appl Phys Lett 96:043308CrossRef Rebeca M, David M, Gustaf W, Sergio B, Maria MRY, Franco C (2010) Light-emitting electrochemical cells using polymeric ionic liquid_polyfluorene blends as luminescent material. Appl Phys Lett 96:043308CrossRef
Metadaten
Titel
Enhanced electroluminescent performance by doping organic conjugated ionic compound into graphene oxide hole-injecting layer
verfasst von
Pan Liu
Junna Liu
Bingbing Zhang
Wansheng Zong
Shengang Xu
Yingliang Liu
Shaokui Cao
Publikationsdatum
05.07.2019
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 19/2019
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-019-03820-1

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