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Erschienen in: Rare Metals 2/2020

23.09.2019

Evolution of microstructure and hardness in a dual-phase Al0.5CoCrFeNi high-entropy alloy with different grain sizes

verfasst von: Hao-Xue Yang, Jin-Shan Li, Tong Guo, William-Yi Wang, Hong-Chao Kou, Jun Wang

Erschienen in: Rare Metals | Ausgabe 2/2020

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Abstract

Cold-rolling with subsequent annealing was carried out to produce recrystallized structures with different grain sizes in an Al0.5CoCrFeNi high-entropy alloy to systematically investigate the grain growth behavior and varying properties. The results show that recrystallized microstructures can be achieved through an annealing process at 1200 °C for 75 min to 16 h, and the average grain size in this study ranges from 5.33 to 30.03 µm. The hardness shown to be affected through grain coarsening was then measured as a function of the grain size, and it is found to follow the classical Hall–Petch strengthening.

Graphic abstract

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Literatur
[1]
Zurück zum Zitat Cantor B, Chang ITH, Knight P, Vincent AJB. Microstructural development in equiatomic multicomponent alloys. Mater Sci Eng, A. 2004;375–377:213.CrossRef Cantor B, Chang ITH, Knight P, Vincent AJB. Microstructural development in equiatomic multicomponent alloys. Mater Sci Eng, A. 2004;375–377:213.CrossRef
[2]
Zurück zum Zitat Yeh JW, Sk Chen, Lin SJ, Gan JY, Chin TS. Nanostructured high-entropy alloys with multiple principal elements: novel alloy design concepts and outcomes. Adv Eng Mater. 2004;6(5):299.CrossRef Yeh JW, Sk Chen, Lin SJ, Gan JY, Chin TS. Nanostructured high-entropy alloys with multiple principal elements: novel alloy design concepts and outcomes. Adv Eng Mater. 2004;6(5):299.CrossRef
[3]
Zurück zum Zitat Lu YP, Gao XX, Dong Y, Wang TM, Chen HL, Mao HH, Zhao YH, Jiang H, Cao ZQ, Li TJ, Guo S. Preparing bulk ultrafine-microstructure high-entropy alloys via direct solidification. Nanoscale. 2018;10(4):1912.CrossRef Lu YP, Gao XX, Dong Y, Wang TM, Chen HL, Mao HH, Zhao YH, Jiang H, Cao ZQ, Li TJ, Guo S. Preparing bulk ultrafine-microstructure high-entropy alloys via direct solidification. Nanoscale. 2018;10(4):1912.CrossRef
[4]
Zurück zum Zitat Yuan Y, Wu Y, Tong X, Zhang H, Wang H, Liu XJ, Ma L, Suo HL, Lu ZP. Rare-earth high-entropy alloys with giant magnetocaloric effect. Acta Mater. 2017;125:481.CrossRef Yuan Y, Wu Y, Tong X, Zhang H, Wang H, Liu XJ, Ma L, Suo HL, Lu ZP. Rare-earth high-entropy alloys with giant magnetocaloric effect. Acta Mater. 2017;125:481.CrossRef
[5]
Zurück zum Zitat Senkov ON, Wilks GB, Miracle DB, Chuang CP, Liaw PK. Refractory high-entropy alloys. Intermetallics. 2010;18(9):1758.CrossRef Senkov ON, Wilks GB, Miracle DB, Chuang CP, Liaw PK. Refractory high-entropy alloys. Intermetallics. 2010;18(9):1758.CrossRef
[6]
Zurück zum Zitat Hy YM, Liu XD, Guo NN, Wang L, Su YQ, Guo JJ. Microstructure and mechanical properties of NbZrTi and NbHfZrTi alloys. Rare Met. 2019;38(9):840.CrossRef Hy YM, Liu XD, Guo NN, Wang L, Su YQ, Guo JJ. Microstructure and mechanical properties of NbZrTi and NbHfZrTi alloys. Rare Met. 2019;38(9):840.CrossRef
[7]
Zurück zum Zitat Jiang SY, Lin ZF, Xu HM. Microstructure and properties of as-cast and annealed AlCoCrFeNi high-entropy alloys. Chin J Rare Met. 2018;42(12):1241. Jiang SY, Lin ZF, Xu HM. Microstructure and properties of as-cast and annealed AlCoCrFeNi high-entropy alloys. Chin J Rare Met. 2018;42(12):1241.
[8]
Zurück zum Zitat Huang HL, Wu Y, He JY, Wang H, Liu XJ, An K, Wu W, Lu ZP. Phase-transformation ductilization of brittle high-entropy alloys via metastability engineering. Adv Mater. 2017;29(30):7.CrossRef Huang HL, Wu Y, He JY, Wang H, Liu XJ, An K, Wu W, Lu ZP. Phase-transformation ductilization of brittle high-entropy alloys via metastability engineering. Adv Mater. 2017;29(30):7.CrossRef
[9]
Zurück zum Zitat Shun TT, Hsieh CY, Hung WJ, Lee CF. Age heat treatment of the CoCrFeNiTi0.3 high-entropy alloy. Mater Trans. 2018;59(5):730.CrossRef Shun TT, Hsieh CY, Hung WJ, Lee CF. Age heat treatment of the CoCrFeNiTi0.3 high-entropy alloy. Mater Trans. 2018;59(5):730.CrossRef
[10]
Zurück zum Zitat Wu CL, Zhang S, Zhang CH, Zhang H, Dong SY. Phase evolution and cavitation erosion-corrosion behavior of FeCoCrAlNiTix high entropy alloy coatings on 304 stainless steel by laser surface alloying. J Alloys Compd. 2017;698:761.CrossRef Wu CL, Zhang S, Zhang CH, Zhang H, Dong SY. Phase evolution and cavitation erosion-corrosion behavior of FeCoCrAlNiTix high entropy alloy coatings on 304 stainless steel by laser surface alloying. J Alloys Compd. 2017;698:761.CrossRef
[11]
Zurück zum Zitat Chen MR, Lin SJ, Yeh JW, Chuang MH, Chen SK, Huang YS. Effect of vanadium addition on the microstructure hardness, and wear resistance of Al0.5CoCrCuFeNi high-entropy alloy. Metall Mater Trans A. 2006;37(5):1363.CrossRef Chen MR, Lin SJ, Yeh JW, Chuang MH, Chen SK, Huang YS. Effect of vanadium addition on the microstructure hardness, and wear resistance of Al0.5CoCrCuFeNi high-entropy alloy. Metall Mater Trans A. 2006;37(5):1363.CrossRef
[12]
Zurück zum Zitat Laplanche G, Gadaud P, Horst O, Otto F, Eggeler G, George EP. Temperature dependencies of the elastic moduli and thermal expansion coefficient of an equiatomic, single-phase CoCrFeMnNi high-entropy alloy. J Alloys Compd. 2015;623:348.CrossRef Laplanche G, Gadaud P, Horst O, Otto F, Eggeler G, George EP. Temperature dependencies of the elastic moduli and thermal expansion coefficient of an equiatomic, single-phase CoCrFeMnNi high-entropy alloy. J Alloys Compd. 2015;623:348.CrossRef
[13]
Zurück zum Zitat Zhang AJ, Han JS, Su B, Meng JH. A promising new high temperature self-lubricating material: CoCrFeNiS0.5 high entropy alloy. Mater Sci Eng, A. 2018;731:36.CrossRef Zhang AJ, Han JS, Su B, Meng JH. A promising new high temperature self-lubricating material: CoCrFeNiS0.5 high entropy alloy. Mater Sci Eng, A. 2018;731:36.CrossRef
[14]
Zurück zum Zitat Satake M, Bitoh T. Synthesis of Fe-Co-Ni-(B, Si, C) ferromagnetic high entropy amorphous alloys and their thermal and magnetic properties. J Jpn Soc Powder Powder Metall. 2018;65(7):401.CrossRef Satake M, Bitoh T. Synthesis of Fe-Co-Ni-(B, Si, C) ferromagnetic high entropy amorphous alloys and their thermal and magnetic properties. J Jpn Soc Powder Powder Metall. 2018;65(7):401.CrossRef
[15]
Zurück zum Zitat Lim KR, Lee KS, Lee JS, Kim JY, Chang HJ, Na YS. Dual-phase high-entropy alloys for high-temperature structural applications. J Alloys Compd. 2017;728:1235.CrossRef Lim KR, Lee KS, Lee JS, Kim JY, Chang HJ, Na YS. Dual-phase high-entropy alloys for high-temperature structural applications. J Alloys Compd. 2017;728:1235.CrossRef
[16]
Zurück zum Zitat Li ZM, Tasan CC, Pradeep KG, Raabe D. A TRIP-assisted dual-phase high-entropy alloy: grain size and phase fraction effects on deformation behavior. Acta Mater. 2017;131:323.CrossRef Li ZM, Tasan CC, Pradeep KG, Raabe D. A TRIP-assisted dual-phase high-entropy alloy: grain size and phase fraction effects on deformation behavior. Acta Mater. 2017;131:323.CrossRef
[17]
Zurück zum Zitat Sriharitha R, Murty BS, Kottada RS. Phase formation in mechanically alloyed AlxCoCrCuFeNi (x = 0.45, 1, 2.5, 5 mol) high entropy alloys. Intermetallics. 2013;32:119.CrossRef Sriharitha R, Murty BS, Kottada RS. Phase formation in mechanically alloyed AlxCoCrCuFeNi (x = 0.45, 1, 2.5, 5 mol) high entropy alloys. Intermetallics. 2013;32:119.CrossRef
[18]
Zurück zum Zitat Guo S, Chun N, Lu J, Liu CT. Effect of valence electron concentration on stability of fcc or bcc phase in high entropy alloys. J Appl Phys. 2011;109(10):103505.CrossRef Guo S, Chun N, Lu J, Liu CT. Effect of valence electron concentration on stability of fcc or bcc phase in high entropy alloys. J Appl Phys. 2011;109(10):103505.CrossRef
[19]
Zurück zum Zitat Ogura M, Fukushima T, Zeller R, Dederichs PH. Structure of the high-entropy alloy AlxCrFeCoNi: fcc versus bcc. J Alloys Compd. 2017;715:454.CrossRef Ogura M, Fukushima T, Zeller R, Dederichs PH. Structure of the high-entropy alloy AlxCrFeCoNi: fcc versus bcc. J Alloys Compd. 2017;715:454.CrossRef
[20]
Zurück zum Zitat Rao JC, Diao HY, Ocelik V, Vainchtein D, Zhang C, Kuo C, Tang Z, Guo W, Poplawsky JD, Zhou Y, Liaw PK, De Hosson JTM. Secondary phases in AlxCoCrFeNi high-entropy alloys: an in situ TEM heating study and thermodynamic appraisal. Acta Mater. 2017;131:206.CrossRef Rao JC, Diao HY, Ocelik V, Vainchtein D, Zhang C, Kuo C, Tang Z, Guo W, Poplawsky JD, Zhou Y, Liaw PK, De Hosson JTM. Secondary phases in AlxCoCrFeNi high-entropy alloys: an in situ TEM heating study and thermodynamic appraisal. Acta Mater. 2017;131:206.CrossRef
[21]
Zurück zum Zitat Sheng WJ, Yang X, Zhu J, Wang C, Zhang Y. Amorphous phase stability of NbTiAlSiNx high-entropy films. Rare Met. 2018;37(8):682.CrossRef Sheng WJ, Yang X, Zhu J, Wang C, Zhang Y. Amorphous phase stability of NbTiAlSiNx high-entropy films. Rare Met. 2018;37(8):682.CrossRef
[22]
Zurück zum Zitat Zhu JM, Meng JL, Liang JL. Microstructure and mechanical properties of multi-principal component AlCoCrFeNiCux alloy. Rare Met. 2016;35(5):385.CrossRef Zhu JM, Meng JL, Liang JL. Microstructure and mechanical properties of multi-principal component AlCoCrFeNiCux alloy. Rare Met. 2016;35(5):385.CrossRef
[23]
Zurück zum Zitat Yang TF, Xia SQ, Liu S, Wang CX, Liu SS, Zhang Y, Xue JM, Yan S, Wang YG. Effects of Al addition on microstructure and mechanical properties of AlxCoCrFeNi High-entropy alloy. Mater Sci Eng, A. 2015;648:15.CrossRef Yang TF, Xia SQ, Liu S, Wang CX, Liu SS, Zhang Y, Xue JM, Yan S, Wang YG. Effects of Al addition on microstructure and mechanical properties of AlxCoCrFeNi High-entropy alloy. Mater Sci Eng, A. 2015;648:15.CrossRef
[24]
Zurück zum Zitat Hou JX, Zhang M, Ma SG, Liaw PK, Qiao JW. Strengthening in Al0.25CoCrFeNi high-entropy alloys by cold rolling. Mater Sci Eng, A. 2017;707:593.CrossRef Hou JX, Zhang M, Ma SG, Liaw PK, Qiao JW. Strengthening in Al0.25CoCrFeNi high-entropy alloys by cold rolling. Mater Sci Eng, A. 2017;707:593.CrossRef
[25]
Zurück zum Zitat Wang Z, Gao MC, Ma SG, Yang HJ, Wang ZH, Ziomek-Moroz M, Qiao JW. Effect of cold rolling on the microstructure and mechanical properties of Al0.25CoCrFe1.25Ni1.25 high-entropy alloy. Mater Sci Eng, A. 2015;645:163.CrossRef Wang Z, Gao MC, Ma SG, Yang HJ, Wang ZH, Ziomek-Moroz M, Qiao JW. Effect of cold rolling on the microstructure and mechanical properties of Al0.25CoCrFe1.25Ni1.25 high-entropy alloy. Mater Sci Eng, A. 2015;645:163.CrossRef
[26]
Zurück zum Zitat Nourbakhsh S, Nutting J. The high strain deformation of an aluminium-4% copper alloy in the supersaturated and aged conditions. Acta Metall. 1980;28(3):357.CrossRef Nourbakhsh S, Nutting J. The high strain deformation of an aluminium-4% copper alloy in the supersaturated and aged conditions. Acta Metall. 1980;28(3):357.CrossRef
[27]
Zurück zum Zitat Guo T, Li JS, Wang J, Wang WY, Liu Y, Luo XM, Kou HC, Beaugnon E. Microstructure and properties of bulk Al0.5CoCrFeNi high-entropy alloy by cold rolling and subsequent annealing. Mater Sci Eng, A. 2018;729:141.CrossRef Guo T, Li JS, Wang J, Wang WY, Liu Y, Luo XM, Kou HC, Beaugnon E. Microstructure and properties of bulk Al0.5CoCrFeNi high-entropy alloy by cold rolling and subsequent annealing. Mater Sci Eng, A. 2018;729:141.CrossRef
[28]
Zurück zum Zitat Ma LL, Wang L, Nie ZH, Wang FC, Xue YF, Zhou JL, Cao TQ, Wang YD, Ren Y. Reversible deformation-induced martensitic transformation in Al0.6CoCrFeNi high-entropy alloy investigated by in situ synchrotron-based high-energy X-ray diffraction. Acta Mater. 2017;128:12.CrossRef Ma LL, Wang L, Nie ZH, Wang FC, Xue YF, Zhou JL, Cao TQ, Wang YD, Ren Y. Reversible deformation-induced martensitic transformation in Al0.6CoCrFeNi high-entropy alloy investigated by in situ synchrotron-based high-energy X-ray diffraction. Acta Mater. 2017;128:12.CrossRef
[29]
Zurück zum Zitat Ma SG, Qiao JW, Wang ZH, Yang HJ, Zhang Y. Microstructural features and tensile behaviors of the Al0.5CrCuFeNi2 high-entropy alloys by cold rolling and subsequent annealing. Mater Des. 2015;88:1057.CrossRef Ma SG, Qiao JW, Wang ZH, Yang HJ, Zhang Y. Microstructural features and tensile behaviors of the Al0.5CrCuFeNi2 high-entropy alloys by cold rolling and subsequent annealing. Mater Des. 2015;88:1057.CrossRef
[30]
Zurück zum Zitat Zener C, Smith CS. Grains, phases and interfaces: an interpretation of microstructure. Trans Metall Soc AIME. 1948;175:11. Zener C, Smith CS. Grains, phases and interfaces: an interpretation of microstructure. Trans Metall Soc AIME. 1948;175:11.
[31]
Zurück zum Zitat Nishizawa T, Ohnuma I, Ishida K. Examination of the Zener relationship between grain size and particle dispersion. Mater Trans, JIM. 1997;38(11):950.CrossRef Nishizawa T, Ohnuma I, Ishida K. Examination of the Zener relationship between grain size and particle dispersion. Mater Trans, JIM. 1997;38(11):950.CrossRef
[32]
Zurück zum Zitat Li DY, Gao MC, Hawk JA, Zhang Y. Annealing effect for the Al0.3CoCrFeNi high-entropy alloy fibers. J Alloys Compd. 2019;778:23.CrossRef Li DY, Gao MC, Hawk JA, Zhang Y. Annealing effect for the Al0.3CoCrFeNi high-entropy alloy fibers. J Alloys Compd. 2019;778:23.CrossRef
[33]
Zurück zum Zitat Hall EO. The deformation and ageing of mild steel: III discussion of results. Proc Phys Soc B. 1951;64:747.CrossRef Hall EO. The deformation and ageing of mild steel: III discussion of results. Proc Phys Soc B. 1951;64:747.CrossRef
[34]
Zurück zum Zitat Sriharitha R, Murt BS, Kottada RS. Alloying, thermal stability and strengthening in spark plasma sintered AlxCoCrCuFeNi high entropy alloys. J Alloys Compd. 2014;583:419.CrossRef Sriharitha R, Murt BS, Kottada RS. Alloying, thermal stability and strengthening in spark plasma sintered AlxCoCrCuFeNi high entropy alloys. J Alloys Compd. 2014;583:419.CrossRef
[35]
Zurück zum Zitat Gwalani B, Soni V, Lee M, Mantri S, Ren Y, Banerjee R. Optimizing the coupled effects of Hall-Petch and precipitation strengthening in a Al0.3CoCrFeNi high entropy alloy. Mater Des. 2017;121:254.CrossRef Gwalani B, Soni V, Lee M, Mantri S, Ren Y, Banerjee R. Optimizing the coupled effects of Hall-Petch and precipitation strengthening in a Al0.3CoCrFeNi high entropy alloy. Mater Des. 2017;121:254.CrossRef
[36]
Zurück zum Zitat Wu Z, Bei H, Otto F, Pharr GM, George EP. Recovery, recrystallization, grain growth and phase stability of a family of FCC-structured multi-component equiatomic solid solution alloys. Intermetallics. 2014;46:131.CrossRef Wu Z, Bei H, Otto F, Pharr GM, George EP. Recovery, recrystallization, grain growth and phase stability of a family of FCC-structured multi-component equiatomic solid solution alloys. Intermetallics. 2014;46:131.CrossRef
Metadaten
Titel
Evolution of microstructure and hardness in a dual-phase Al0.5CoCrFeNi high-entropy alloy with different grain sizes
verfasst von
Hao-Xue Yang
Jin-Shan Li
Tong Guo
William-Yi Wang
Hong-Chao Kou
Jun Wang
Publikationsdatum
23.09.2019
Verlag
Nonferrous Metals Society of China
Erschienen in
Rare Metals / Ausgabe 2/2020
Print ISSN: 1001-0521
Elektronische ISSN: 1867-7185
DOI
https://doi.org/10.1007/s12598-019-01320-4

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