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Rare Metals
Erschienen in: Rare Metals 2/2020

09.12.2019

Ultra-stable metal nano-catalyst synthesis strategy: a perspective

verfasst von: Xiao-Qing Cao, Jun Zhou, Song Li, Gao-Wu Qin

Erschienen in: Rare Metals | Ausgabe 2/2020

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Abstract

Supported metal nanoparticles (NPs) as an important heterogeneous catalyst have been widely applied in various industrial processes. During the catalytic reaction, size of the particles plays an important role in determining their catalytic performance. Generally, the small particles exhibit superior catalytic activity in comparison with the larger particles because of an increase in low-coordinated metal atoms on the particle surface that work as active sites, such as edges and corner atoms. However, these small NPs are typically unstable and tend to migrate and coalescence to reduce their surface free energy during the real catalytic processes, particularly in high-temperature reactions. Therefore, a means to fabricate stable small metal NP catalysts with excellent sinter-resistant performance is necessary for maintaining their high catalytic activity. In this study, we have summarized recent advances in stabilizing metal NPs from two aspects including thermodynamic and kinetic strategies. The former mainly involve preparing uniform NPs (with an identical size and homogeneous distribution) in order to restrain Ostwald ripening to achieve stability, while the latter primarily involves fixing metal NPs in some special confinement materials (e.g., zeolites, mesoporous silica and mesoporous carbons), encapsulating NPs using an oxide-coating film (e.g., forming core–shell structures), or constructing strong metal–support interactions to improve stability. At the end of this review, we highlight our recent work on the preparation of high-stability metal catalysts via a unique interfacial plasma electrolytic oxidation technology, that is, metal NPs are well embedded in a porous MgO layer that has both high thermal stability and excellent catalytic activity.
Vorheriger Artikel Noncollinear spintronics and electric-field control: a review
Nächster Artikel Improved open-circuit voltage and ambient stability of CsPbI2Br perovskite solar cells by incorporating CH3NH3Cl

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Metadaten
Titel
Ultra-stable metal nano-catalyst synthesis strategy: a perspective
verfasst von
Xiao-Qing Cao
Jun Zhou
Song Li
Gao-Wu Qin
Publikationsdatum
09.12.2019
Verlag
Nonferrous Metals Society of China
Erschienen in
Rare Metals / Ausgabe 2/2020
Print ISSN: 1001-0521
Elektronische ISSN: 1867-7185
DOI
https://doi.org/10.1007/s12598-019-01350-y

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