Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Bücher
Zeitschriften
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
MTZ-Fachkongress

Antriebe und Energiesysteme von morgen


Austausch von Automobil- und Energiewirtschaft

Am 14./15. Mai geht es in Chemnitz um die Mobilitätswende durch Elektro- und Wasserstofffahrzeuge.
Erweiterte Suche
Anmelden
nach oben
Arabian Journal for Science and Engineering
Erschienen in: Arabian Journal for Science and Engineering 6/2023

25.12.2022 | Research Article-chemistry

Fabrication of Zinc Oxide and Zinc Oxide-Copper-Benzene Tricarboxylic Acid-Modified Carbon Paste Electrodes as Electrochemical Sensor for Cd (II) Ions

Erschienen in: Arabian Journal for Science and Engineering | Ausgabe 6/2023

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Electrochemical sensors based on carbon paste electrodes modified with Zinc oxide (ZC) and Zinc Oxide-Copper-Benzene Tricarboxylic acid (ZBC) were fabricated for voltammetric estimation of toxic Cd (II) ions in the matrix. Both the electrodes operate by showing interaction with Cd(II) ions and producing an electrical signal proportional to its concentration. The synthesized materials (ZnO and ZnO-Cu-BTC) were characterized by FTIR, XRD, SEM, EDX, TGA and electrochemical characterization by ElS and CV scans. Mixing appropriate amounts of graphite powder, synthesized material (ZnO or ZnO-Cu-BTC) and paraffin oil generated a variety of modified carbon paste electrodes as working electrodes. The electrochemical surface area for ZBC (1.1845cm2) was found to be much greater than for ZC (0.686 cm2). The fabricated working electrodes were utilized to optimize Cd(II) determination parameters (effect of modifier amount, accumulation media, pH, deposition potential, deposition time, and cadmium concentration) with potentiostat workstation using differential pulse method. The results revealed that 15% (w/w) ZnO and 1% (w/w) ZnO-Cu-BTC modifier amount, using HCl as supporting electrolyte at pH 4, and − 1.2 V deposition potential with 60 s deposition time were found to be the optimized conditions for Cd(II) ions determination. The LOQ was calculated to be 0.104 mgL−1 and 0.016 mgL−1, while LOD was found to be 0.034 mgL−1 and 0.0053 mgL−1 using ZC and ZBC, respectively. The ZBC was found to be better than ZC for Cd(II) ions determination as ZBC showed lower LOQ and LOQ, larger surface area, and smaller electrode modifier amount as compared to ZC.
Vorheriger Artikel Synthesis, Characterization, Thermodynamic Analysis and Quantum Chemical Approach of Branched N, N′-bis(p-hydroxybenzoyl)-Based Propanediamine and Triethylenetetramine for Carbon Steel Corrosion Inhibition in Hydrochloric Acid Medium
Nächster Artikel Spectral, Thermal and Photocatalytic Properties of Transition Metal Complexes Based on a Ligand Derived from Gallic Acid and Ethylenediamine

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
1.
Chadha, U.; Bhardwaj, P.; Agarwal, R.; Rawat, P.; Agarwal, R.; Gupta, I.; Panjwani, M.; Singh, S.; Ahuja, C.; Selvaraj, S.K.: Recent progress and growth in biosensors technology: a critical review. J. Ind. Eng. Chem. 109, 21 (2022)CrossRef
2.
Wang, Z.M.; Guo, H.W.; Liu, E.; Yang, G.C.; Khun, N.W.: Bismuth/polyaniline/glassy carbon electrodes prepared with different protocols for stripping voltammetric determination of trace Cd and Pb in solutions having surfactants. Electroanalysis (NYNY). 22, 209–215 (2010)CrossRef
3.
Zhou, W.; Li, C.; Sun, C.; Yang, X.: Simultaneously determination of trace Cd2+ and Pb2+ based on l-cysteine/graphene modified glassy carbon electrode. Food Chem. 192, 351–357 (2016)CrossRef
4.
Ranganathan, S.; McCreery, R.L.: Electroanalytical performance of carbon films with near-atomic flatness. Anal. Chem. 73, 893–900 (2001)CrossRef
5.
El Mhammedi, M.; Achak, M.; Bakasse, M.: Evaluation of a platinum electrode modified with hydroxyapatite in the lead (II) determination in a square wave voltammetric procedure. Arab. J. Chem. 6, 299–305 (2013)CrossRef
6.
Berlina, A.N.; Zherdev, A.V.; Dzantiev, B.B.: Progress in rapid optical assays for heavy metal ions based on the use of nanoparticles and receptor molecules. Microchim. Acta 186, 1–39 (2019)CrossRef
7.
Banks, C.E.; Davies, T.J.; Wildgoose, G.G.; Compton, R.G.: Electrocatalysis at graphite and carbon nanotube modified electrodes: edge-plane sites and tube ends are the reactive sites. Chem. Comm. 7, 829–841 (2005)CrossRef
8.
Wu, L.; Zhang, X.; Ju, H.: Detection of NADH and ethanol based on catalytic activity of soluble carbon nanofiber with low overpotential. Anal. Chem. 79, 453–458 (2007)CrossRef
9.
Zhou, M.; Ding, J.; Guo, L.-P.; Shang, Q.-K.: Electrochemical behavior of L-cysteine and its detection at ordered mesoporous carbon-modified glassy carbon electrode. Anal. Chem. 79, 5328–5335 (2007)CrossRef
10.
Rahman, M.A.; Song, G.; Bhatt, A.I.; Wong, Y.C.; Wen, C.: Nanostructured silicon anodes for high-performance lithium-ion batteries. Adv. Funct. Mater. 26, 647–678 (2016)CrossRef
11.
Reddy, M.; Prithvi, G.; Loh, K.P.; Chowdari, B.: Li storage and impedance spectroscopy studies on Co3O4, CoO, and CoN for Li-ion batteries. ACS Appl. Mater. Interfaces. 6, 680–690 (2013)CrossRef
12.
Zheng, F.; He, M.; Yang, Y.; Chen, Q.: Nano electrochemical reactors of Fe2O3 nanoparticles embedded in shells of nitrogen-doped hollow carbon spheres as high-performance anodes for lithium-ion batteries. Nanoscale 7, 3410–3417 (2015)CrossRef
13.
Choi, S.H.; Lee, J.-H.; Kang, Y.C.: One-pot rapid synthesis of core–shell structured NiO@ TiO2 nanopowders and their excellent electrochemical properties as anode materials for lithium ion batteries. Nanoscale 5, 12645–12650 (2013)CrossRef
14.
Zhang, Y.; Yan, Y.; Wang, X.; Li, G.; Deng, D.; Jiang, L.; Shu, C.; Wang, C.: Facile synthesis of porous Mn2O3 nanoplates and their electrochemical behavior as anode materials for lithium ion batteries. Chem. Eur. J. 20, 6126–6130 (2014)CrossRef
15.
Zheng, F.; Zhu, D.; Chen, Q.: Facile fabrication of porous NixCo3–xO4 nanosheets with enhanced electrochemical performance as anode materials for Li-ion batteries. ACS Appl. Mater Interfaces. 6, 9256–9264 (2014)CrossRef
16.
Mehta, S.; Singh, K.; Umar, A.; Chaudhary, G.; Singh, S.: Ultra-high sensitive hydrazine chemical sensor based on low-temperature grown ZnO nanoparticles. Electrochim. Acta. 69, 128–133 (2012)CrossRef
17.
Li, H.; Su, Y.; Sun, W.; Wang, Y.: Carbon Nanotubes rooted in porous ternary metal sulfide@ N/S-doped carbon dodecahedron: bimetal-organic-frameworks derivation and electrochemical application for high-capacity and long-life lithium-ion batteries. Adv. Funct. Mater. 26, 8345–8353 (2016)CrossRef
18.
Wang, Z.; Luan, D.; Madhavi, S.; Hu, Y.; Lou, X.W.D.: Assembling carbon-coated α-Fe2O3 hollow nanohorns on the CNT backbone for superior lithium storage capability. Energy Environ. Sci. 5, 5252–5256 (2012)CrossRef
19.
Kharangarh, P.R.; Gupta, V.; Singh, A.; Bhardwaj, P.; Grace, A.N.: An efficient pseudocapacitor electrode material with co-doping of iron (II) and sulfur in luminescent graphene quantum dots. Diam. Relat. Mater. 107, 107913 (2020)CrossRef
20.
Wang, Z.; Zhou, L.; Lou, X.W.: Metal oxide hollow nanostructures for lithium-ion batteries. Adv. Mater. 24, 1903–1911 (2012)CrossRef
21.
Bhardwaj, P.; Singh, S.; Kharangarh, P.R.; Grace, A.N.: Surfactant decorated polypyrrole-carbon materials composites electrodes for supercapacitor. Diam. Relat. Mater. 108, 107989 (2020)CrossRef
22.
Chaudhary, G.; Sharma, A.K.; Bhardwaj, P.; Kant, K.; Kaushal, I.; Mishra, A.K.: NiCo2O4 decorated PANI–CNTs composites as supercapacitive electrode materials. J. Energy Chem. 26, 175–181 (2017)CrossRef
23.
Suriyakumar, S.; Bhardwaj, P.; Grace, A.N.; Stephan, A.M.: Role of polymers in enhancing the performance of electrochemical supercapacitors: a review. Batter. Supercaps. 4, 571–584 (2021)CrossRef
24.
Bhardwaj, P.; Kaushik, S.; Gairola, P.; Gairola, S.: Polyaniline enfolded hybrid carbon array substrate electrode for high performance supercapacitors. J. Polym. Eng. 39, 228–238 (2019)CrossRef
25.
26.
Kumar Sharma, A.; Bhardwaj, P.; Kumar Dhawan, S.; Sharma, Y.: Oxidative synthesis and electrochemical studies of poly (aniline-co-pyrrole)-hybrid carbon nanostructured composite electrode materials for supercapacitor. Adv. Mater. Lett. 6, 414–420 (2015)CrossRef
27.
Venkateshalu, S.; Subashini, G.; Bhardwaj, P.; Jacob, G.; Sellappan, R.; Raghavan, V.; Jain, S.; Pandiaraj, S.; Natarajan, V.; Al Alwan, B.A.M.: Phosphorene, antimonene, silicene and siloxene based novel 2D electrode materials for supercapacitors-A brief review. J. Energy Storage. 48, 104027 (2022)CrossRef
28.
Chadha, U.; Bhardwaj, P.; Padmanaban, S.; Suneel, R.M.; Milton, K.; Subair, N.; Pandey, A.; Khanna, M.; Srivastava, D.; Mathew, R.M.: Contemporary progresses in carbon-based electrode material in Li-S batteries. J. Electrochem. Soc. 169, 020530 (2022)CrossRef
29.
Mnyipika, S.H.; Munonde, T.S.; Nomngongo, P.N.: MnO2@ reduced graphene oxide nanocomposite-based electrochemical sensor for the simultaneous determination of trace Cd (II), Zn (II) and Cu (II) in water samples. Membranes 11, 517 (2021)CrossRef
30.
Molina, J.; Cases, F.; Moretto, L.: Graphene-based materials for the electrochemical determination of hazardous ions. Anal. Chim. Acta 946, 9–39 (2016)CrossRef
31.
Guo, X.; Cui, R.; Huang, H.; Li, Y.; Liu, B.; Wang, J.; Zhao, D.; Dong, J.; Sun, B.: Insights into the role of pyrrole doped in three-dimensional graphene aerogels for electrochemical sensing Cd (II). J. Electroanal. Chem. 871, 114323 (2020)CrossRef
32.
Li, L.; Liu, D.; Shi, A.; You, T.: Simultaneous stripping determination of cadmium and lead ions based on the N-doped carbon quantum dots-graphene oxide hybrid. Sens. Actuators B Chem. 255, 1762–1770 (2018)CrossRef
33.
Xu, X.; Cao, R.; Jeong, S.; Cho, J.: Spindle-like mesoporous α-Fe2O3 anode material prepared from MOF template for high-rate lithium batteries. Nano Lett. 12, 4988–4991 (2012)CrossRef
34.
Mikuriya, M.; Yoshioka, D.; Handa, M.: Magnetic interactions in one-, two-, and three-dimensional assemblies of dinuclear ruthenium carboxylates. Coord. Chem. Rev. 250, 2194–2211 (2006)CrossRef
35.
Cao, Y.; Ma, Y.; Wang, T.; Wang, X.; Huo, Q.; Liu, Y.: Facile fabricating hierarchically porous metal–organic frameworks via a template-free strategy. Cryst. Growth Des. 16, 504–510 (2016)CrossRef
36.
37.
Ye, W.; Li, Y.; Wang, J.; Li, B.; Cui, Y.; Yang, Y.; Qian, G.: Electrochemical detection of trace heavy metal ions using a Ln-MOF modified glass carbon electrode. J. Solid State Chem. 281, 121032 (2020)CrossRef
38.
Ding, Y.; Wei, F.; Dong, C.; Li, J.; Zhang, C.; Han, X.: UiO-66 based electrochemical sensor for simultaneous detection of Cd (II) and Pb (II). Inorg. Chem. Commun. 131, 108785 (2021)CrossRef
39.
Zhu, Y.; Zhou, S.; Zhu, J.; Wang, P.; Wang, X.; Jia, X.; Wågberg, T.; Hu, G.: Mesoporous carbon decorated with MIL-100 (Fe) as an electrochemical platform for ultrasensitive determination of trace cadmium and lead ions in surface water. Ecotoxicol. Environ. Saf. 243, 113987 (2022)CrossRef
40.
Cao, Y.; Wang, L.; Shen, C.; Wang, C.; Hu, X.; Wang, G.: An electrochemical sensor on the hierarchically porous Cu-BTC MOF platform for glyphosate determination. Sens. Actuators B Chem. 283, 487–494 (2019)CrossRef
41.
Nagles, E.; Arancibia, V.; Rojas, C.; Segura, R.: Nafion–mercury coated film electrode for the adsorptive stripping voltammetric determination of lead and cadmium in the presence of pyrogallol red. Talanta 99, 119–124 (2012)CrossRef
42.
Reiley, M.C.: Science, policy, and trends of metals risk assessment at EPA: How understanding metals bioavailability has changed metals risk assessment at US EPA. Aquat. Toxicol. 84, 292–298 (2007)CrossRef
43.
Genchi, G.; Sinicropi, M.S.; Lauria, G.; Carocci, A.; Catalano, A.: The effects of cadmium toxicity. Int. J. Environ. Res. Public Health. 17, 3782 (2020)CrossRef
44.
Ensafi, A.A.; Khayamian, T.; Benvidi, A.; Mirmomtaz, E.: Simultaneous determination of copper, lead and cadmium by cathodic adsorptive stripping voltammetry using artificial neural network. Anal. Chim. Acta. 561, 225–232 (2006)CrossRef
45.
Veerakumar, P.; Veeramani, V.; Chen, S.-M.; Madhu, R.; Liu, S.-B.: Palladium nanoparticle incorporated porous activated carbon: electrochemical detection of toxic metal ions. ACS Appl. Mater. Interfaces. 8, 1319–1326 (2016)CrossRef
46.
Hou, J.; Fan, Y.; Ma, X.; Dong, X.; Yao, S.: Effects of modified fly ash doped carbon paste electrodes and metal film electrodes on the determination of trace cadmium (ii) by anodic stripping voltammetry. RSC Adv. 11, 17240–17248 (2021)CrossRef
47.
Sharma, D.; Rajput, J.; Kaith, B.; Kaur, M.; Sharma, S.: Synthesis of ZnO nanoparticles and study of their antibacterial and antifungal properties. Thin Solid Films 519, 1224–1229 (2010)CrossRef
48.
Júnior, E.A.A.; Nobre, F.X.; da Silva Sousa, G.; Cavalcante, L.S.; Santos, M.R.D.M.C.; Souza, F.L.; de Matos, J.M.E.: Synthesis, growth mechanism, optical properties and catalytic activity of ZnO microcrystals obtained via hydrothermal processing. RSC Adv. 7, 24263–24281 (2017)CrossRef
49.
Sun, X.; Gao, G.; Yan, D.; Feng, C.: Synthesis and electrochemical properties of Fe3O4@ MOF core-shell microspheres as an anode for lithium ion battery application. Appl. Surf. Sci. 405, 52–59 (2017)CrossRef
50.
Zhong, L.; Yun, K.: Graphene oxide-modified ZnO particles: synthesis, characterization, and antibacterial properties. Int. J. Nanomed. 10, 79 (2015)
51.
Jabarian, S.; Ghaffarinejad, A.: Simultaneous electrosynthesis of Cu–BTC and Zn–BTC metal–organic frameworks on brass. New J. Chem. 44, 19820–19826 (2020)CrossRef
52.
Aristov, N.; Habekost, A.: Cyclic voltammetry-A versatile electrochemical method investigating electron transfer processes. World J. Chem. Educ. 3, 115–119 (2015)
53.
Rajawat, D.S.; Kumar, N.; Satsangee, S.P.: Trace determination of cadmium in water using anodic stripping voltammetry at a carbon paste electrode modified with coconut shell powder. J. Anal. Sci. Technol. 5, 1–8 (2014)CrossRef
54.
Mohammadi, S.; Taher, M.A.; Beitollahi, H.; Naghizadeh, M.: Sensitive voltammetric determination of cadmium at a carbon nanotubes/Fe3O4/eggshell composites modified carbon paste electrode. Environ. Nanotechnol. Monit. Manag. 12, 100241 (2019)
55.
Marino, G.; Bergamini, M.F.; Teixeira, M.F.; Cavalheiro, É.T.: Evaluation of a carbon paste electrode modified with organofunctionalized amorphous silica in the cadmium determination in a differential pulse anodic stripping voltammetric procedure. Talanta 59, 1021–1028 (2003)CrossRef
56.
Manikandan, R.; Narayanan, S.S.: Simultaneous anodic stripping voltammetric determination of Pb (II) and Cd (II) using poly methyl thymol blue film–modified electrode. Ionics 25, 6083–6092 (2019)CrossRef
57.
Song, Y.; Bian, C.; Tong, J.; Li, Y.; Xia, S.: The graphene/l-cysteine/gold-modified electrode for the differential pulse stripping voltammetry detection of trace levels of cadmium. Micromachines 7, 103 (2016)CrossRef
58.
Lee, P.M.; Chen, Z.; Li, L.; Liu, E.: Reduced graphene oxide decorated with tin nanoparticles through electrodeposition for simultaneous determination of trace heavy metals. Electrochim. Acta. 174, 207–214 (2015)CrossRef
59.
Zhao, G.; Wang, H.; Liu, G.; Wang, Z.; Cheng, J.: Simultaneous determination of trace Cd (II) and Pb (II) based on Bi/Nafion/reduced graphene oxide-gold nanoparticle nanocomposite film-modified glassy carbon electrode by one-step electrodeposition. Ionics 23, 767–777 (2017)CrossRef
60.
Hao, C.; Shen, Y.; Shen, J.; Xu, K.; Wang, X.; Zhao, Y.; Ge, C.: A glassy carbon electrode modified with bismuth oxide nanoparticles and chitosan as a sensor for Pb (II) and Cd (II). Microchim. Acta. 183, 1823–1830 (2016)CrossRef
61.
Korolczuk, M.; Stepniowska, A.; Tyszczuk, K.: Determination of cadmium by stripping voltammetry at a lead film electrode. Int. J. Environ. Anal. Chem. 89, 727–734 (2009)CrossRef
62.
Shrivastava, A.; Gupta, V.B.: Methods for the determination of limit of detection and limit of quantitation of the analytical methods. Chron. Young Sci. 2, 21–25 (2011)CrossRef
63.
Wu, W.; Jia, M.; Wang, Z.; Zhang, W.; Zhang, Q.; Liu, G.; Zhang, Z.; Li, P.: Simultaneous voltammetric determination of cadmium (II), lead (II), mercury (II), zinc (II), and copper (II) using a glassy carbon electrode modified with magnetite (Fe3O4) nanoparticles and fluorinated multiwalled carbon nanotubes. Microchim. Acta. 186, 1–10 (2019)CrossRef
64.
Serrano, N.; González-Calabuig, A.; Del Valle, M.: Crown ether-modified electrodes for the simultaneous stripping voltammetric determination of Cd (II), Pb (II) and Cu (II). Talanta 138, 130–137 (2015)CrossRef
65.
Pizarro, J.; Segura, R.; Tapia, D.; Navarro, F.; Fuenzalida, F.; Aguirre, M.J.: Inexpensive and green electrochemical sensor for the determination of Cd (II) and Pb (II) by square wave anodic stripping voltammetry in bivalve mollusks. Food Chem. 321, 126682 (2020)CrossRef
66.
Bhanjana, G.; Dilbaghi, N.; Kumar, R.; Umar, A.; Kumar, S.: SnO2 quantum dots as novel platform for electrochemical sensing of cadmium. Electrochim Acta. 169, 97–102 (2015)CrossRef
Metadaten
Titel
Fabrication of Zinc Oxide and Zinc Oxide-Copper-Benzene Tricarboxylic Acid-Modified Carbon Paste Electrodes as Electrochemical Sensor for Cd (II) Ions
Publikationsdatum
25.12.2022
Erschienen in
Arabian Journal for Science and Engineering / Ausgabe 6/2023
Print ISSN: 2193-567X
Elektronische ISSN: 2191-4281
DOI
https://doi.org/10.1007/s13369-022-07542-6

Weitere Artikel der Ausgabe 6/2023

Arabian Journal for Science and Engineering 6/2023 Zur Ausgabe

Research Article-Earth Sciences

Integrated Geological and Petrophysical Approaches for Characterizing the Pre-Cenomanian Nubian Sandstone Reservoirs in Ramadan Oil Field, Central Gulf of Suez, Egypt

Research Article-chemistry

Toward the Development of Novel Poly(o-toluidine)-Based Metal Composite Materials: Structural, Optical and Electrochemical Performance

Research Article-chemistry

Synthesis, Molecular Modeling, and Antioxidant Activity of New Thiadiazole-Triazole Analogs Hybridized with Thiophene

Research Article-Chemistry

Photocatalytic Performance of Organically Templated Cr-Doped Co3O4 in Remediation of Industrial Wastewater: Effect of Order–Disorder in the Lattice

Research Article-Physics

Laguerre–Gaussian Beam Scattering by a Perfect Electromagnetic Conductor (PEMC) Sphere

Research Article--Chemistry

Attenuation of Mild Steel-Acid Corrosion Using Exfoliated Graphite Oxide-Polymer Composite: Synthesis, Characterization, Electrochemical, and Response Surface Method Approach

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise