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15.12.2022 | Original Research

Flame-retardant finishing of cotton fabric by surface-initiated photochemically induced atom transfer radical polymerization

verfasst von: Gamal Zain, Igor Jordanov, Sandra Bischof, Eva Magovac, Alena Opálková Šišková, Anna Vykydalová, Angela Kleinová, Matej Mičušík, Katarína Mosnáčková, Jana Nováčiková, Jaroslav Mosnáček

Erschienen in: Cellulose | Ausgabe 4/2023

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Abstract

Phosphorus-containing polymers are very promising because of the versatility of their applications. Polyphosphates and polyphosphonates are well-known for their excellent fire-retardant properties. In this work, a cotton fabric was grafted by oxygen-tolerant photochemically induced atom transfer radical polymerization (photoATRP) of dimethyl(methacryloyloxymethyl) phosphonate (MAPC1) in order to prepare flame resistant fabric. The photoATRP of MAPC1 was first optimized in solution and subsequently used for surface-initiated polymerization from cotton fabric pre-functionalized by ATRP initiator in order to achieve PMAPC1 brushes onto the surface. The modified cotton fabrics were characterized by attenuated total reflection–Fourier transforms infrared spectroscopy and X-ray photoelectron spectroscopy to prove successful grafting. Minimal effect of grafting on mechanical properties of the cotton fabric was confirmed by tensile tests. The thermal properties and flammability of the modified fabric were tested by thermogravimetric analysis, horizontal and vertical flame tests. Limiting oxygen index and microscale cone calorimeter were performed as well. The results show that modified fabric has a high flame resistance making it a good candidate for flame-retardant application. Washing tests confirmed that the grafted layer on the fabric has good durability from the point of view of retention of high flame resistance.

Vorheriger Artikel Multifunctional fluorine-free cotton fabrics modified by AgBr–TiO2/OV-POSS nanocomposites

Nächster Artikel Synthesis of reactive flame retardant containing Si–P–S–N and its application in cotton fabric

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Titel: Flame-retardant finishing of cotton fabric by surface-initiated photochemically induced atom transfer radical polymerization
verfasst von: Gamal Zain
Igor Jordanov
Sandra Bischof
Eva Magovac
Alena Opálková Šišková
Anna Vykydalová
Angela Kleinová
Matej Mičušík
Katarína Mosnáčková
Jana Nováčiková
Jaroslav Mosnáček
Publikationsdatum: 15.12.2022
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 4/2023
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-022-04982-z

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