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Erschienen in: Journal of Materials Science: Materials in Electronics 18/2021

24.08.2021

Lattice vibrational modes, crystal structure, and dielectric properties of phase pure Ba(Mg1/2Mo1/2)O3 ceramic

verfasst von: Danhui Cheng, Jiqing Lv, Luke Wang, Runhao Han, Feng Shi, Zeming Qi, Jing Wang

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 18/2021

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Abstract

A phase pure Ba(Mg1/2Mo1/2)O3 (BMM) ceramic was prepared by a traditional solid-state reaction method with a double perovskite structure (Fm-3 m), which is confirmed by X-ray diffraction. The scanning electron microscope image of the BMM sample confirmed the presence of dense grains and clear grain boundaries. The Raman and far-infrared reflection spectra were measured, and the lattice vibrational modes were analyzed in detail. The intrinsic properties were fitted by the four-parameter semi-quantum model based on the far-infrared spectrum, whose values (εr = 4.728, tanδ = 4.594 × 10–4) were analogous to the theoretical values (εr = 4.290, tanδ = 5.962 × 10–4) calculated by the Clausius–Mossotti (C–M) and damping equations, as well as the measured values (εr = 4.468, tanδ = 4.439 × 10–4).

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Metadaten
Titel
Lattice vibrational modes, crystal structure, and dielectric properties of phase pure Ba(Mg1/2Mo1/2)O3 ceramic
verfasst von
Danhui Cheng
Jiqing Lv
Luke Wang
Runhao Han
Feng Shi
Zeming Qi
Jing Wang
Publikationsdatum
24.08.2021
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 18/2021
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-021-06829-y

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