Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Journal of Materials Science: Materials in Electronics
Erschienen in: Journal of Materials Science: Materials in Electronics 18/2021

20.08.2021

Structural, optical and electrical properties of copper composite ZrO2 nanoparticles prepared via sol–gel method

verfasst von: N. Mahendran, S. Johnson Jeyakumar, M. Ponnar

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 18/2021

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

In the present work, pure and copper composite zirconium oxide nanoparticles with a different percentages of copper (0.02, 0.04, 0.06 and 0.08%) were successfully synthesized by a low cost sol–gel technique. It was found that as-prepared samples of copper-composite (zirconium oxide) ZrO2 nanoparticles are in monoclinic phase. The copper-doped zirconium oxide (ZrO2) NPs are present as spherical morphology and highly agglomeration confirmed by scanning electron microscopy and high resolution transmission electron microscope analyses. The synthesis samples exhibited two bandgap energy at 3.6 eV and 2.6 eV, 3.57 eV and 2.4 eV, 3.55 eV and 2.14 eV, and 3.5 eV and 2.1 eV. The presence of functional groups and the chemical bonding is confirmed by FT-IR spectra. PL spectra of the pure and Cu-doped ZrO2 nanoparticles exhibited oxygen vacancies. Voltage–current characteristics of pure and composite ZrO2 nanoparticles are studied at vary incident light intensity that show the negative photoconductivity.
Vorheriger Artikel Hollow ZnO microspheres self-assembled from rod-like nanostructures: morphology-dependent linear and Kerr-type nonlinear optical properties
Nächster Artikel Lattice vibrational modes, crystal structure, and dielectric properties of phase pure Ba(Mg1/2Mo1/2)O3 ceramic

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 340 Zeitschriften

aus folgenden Fachgebieten:

  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Versicherung + Risiko




Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
1.
S.K. Jose, A. George, A. Jose, C. Joseph, N.V. Unnikrishnan, P.R. Biju, Structural and luminescence characterization of Eu3+/ZnS nanoparticle-doped ZrO2/PEG composites. J. Mater. Sci.: Mater Electron. 32, 9755–9764 (2021)
2.
R. Gopal, A. Sambandam, T. Kuppulingam, S. Meenakshisundaram, M.S. AlSalhi, S. Devanesan, Versatile fabrication and characterization of Cu-doped ZrO2 nanoparticles: enhanced photocatalytic and photoluminescence properties. J. Mater. Sci.: Mater. Electron. 31, 7232–7246 (2020)
3.
G. Rajesh, S. Akilandeswari, D. Govindarajan, K. Thirumalai, Enhancement of photocatalytic activity of ZrO2 nanoparticles by doping with Mg for UV light photocatalytic degradation of methyl violet and methyl blue dyes. J. Mater. Sci.: Mater. Eectron. 31, 4058–4072 (2020)
4.
M.A. Waghmare, N.I. Beedri, P.K. Baviskar, H.M. Pathan, A.U. Ubale, Effect of ZrO2 barrier layers on the photovoltaic parameters of rose bengal dye-sensitized TiO2 solar cell. J. Mater. Sci. 30, 6015–6022 (2019)
5.
S. Akilandeswari, G. Rajesh, D. Govindarajan, K. Thirumalai, M. Swaminathan, Efficacy of photoluminescence and photocatalytic properties of Mn doped ZrO2 nanoparticles by facile precipitation method. J. Mater. Sci.: Mater. Electron. 29, 18258–18270 (2018)
6.
S. Bhand, D. Chadar, K. Pawar, M. Naushad, H. Pathan, S. Salunke-Gawali, Benzo [α]phenothiazine sensitized ZrO2 based dye sensitized solar cell. J. Mater. Sci. 29, 1034–1041 (2018)
7.
A. Behbahani, S. Rowshanzamir, A. Esmaeilifar, Hydrothermal synthesis of zirconia nanoparticles from commercial zirconia. Proc. Eng. 42, 908–917 (2012)CrossRef
8.
R.A. Espinoza-González, D.E. Diaz-Droguett, J.I. Avil, C.A. Gonzalez-Fuentes, V.M. Fuenzalid, Hydrothermal growth of zirconia nanobars on zirconium oxide. Mater. Lett. 65, 2121–2123 (2011)CrossRef
9.
K.V.R. Chary, K.K. Seela, D. Naresh, P. Ramakanth, Characterization and reductive amination of cyclohexanol and cyclohexanone over Cu/ZrO2 catalysts. Catal. Commun. 9, 75–81 (2008)CrossRef
10.
T. Tsonchevaa, I. Genovaa, M. Dimitrova, E.S. Priboczkib, A.M. Veneziac, D. Kovachevad, Nanostructured copper-zirconia composites as catalysts for methanol decomposition. Appl. Catal. B. 165, 599–610 (2015)CrossRef
11.
S. López-Romero, M. García-Hipólito, A. Aguilar-Castillo, Bright green luminescence from zirconium oxide stabilized with Tb3+ ions synthesized by solution combustion technique. J. Condens. Matter Phys. 3, 173–179 (2013)
12.
R. Li, A.E. Clark, L.L. Hench, An investigation of bioactive glass powders by sol-gel processing. J. Appl. Biomater. Funct. Mater. 2, 231 (1991)CrossRef
13.
S.J Golden, R. Hatfield, J.D. Pless, Catalyst with lanthanide-doped zirconia and methods of making. U.S. Patent No. 9,011,784, 21 April 2015.
14.
V. Kiisk, L. Puust, H. Mandar, P. ItslaidRahn, I. Bite, D. Jankovica, I. Sildos, A. Jaaniso, Phastability and oxygen-sensitive photoluminescence of ZrO2:Eu, Nb nanopowders. Mater. Chem. Phys. 214, 135–142 (2018)CrossRef
15.
H. Wang, G. Li, Y. Xue, L. Li, Hydrated surface structure and its impacts on the stabilization of t-ZrO2. J. Solid State Chem. 180, 2790 (2007)CrossRef
16.
K. Inui, T. Kurabayashi, S. Sato, Direct synthesis of ethyl acetate from ethanol carried out under pressure. J. Catal. 212, 207–215 (2002)CrossRef
17.
J. Liu, J. Shi, D. He, Q. Zhang, X. Wu, Y. Liang, Q. Zhu, Surface active structure of ultra-fine Cu/ZrO2 catalysts used for the CO2+H2 to methanol reaction. Appl. Catal. A Gen. 218, 113 (2001)CrossRef
18.
M.D. Rhodes, K.A. Pokrovski, A.T. Bell, The effects of zirconia morphology on methanol synthesis from CO and H2 over Cu/ZrO2 catalysts: Part II. Transient-response infrared studies. J. Catal. 233, 210 (2005)CrossRef
19.
L. Wang, W. Zhu, D. Zheng, X. Yu, J. Cui, M. Jia, W. Zhang, Z. Wang, React. Kinet. Direct transformation of ethanol to ethyl acetate on Cu/ZrO2 catalyst. Mech. Catal. 101, 365–375 (2010)
20.
A.B. Gaspar, A.M.L. Esteves, F.M.T. Mendes, F.G. Barbosa, L.G. Appel, Chemicals from thanol—the ethyl acetate one-pot synthesis. Appl. Catal. A Gen. 363, 109–114 (2009)CrossRef
21.
A.B. Gaspar, F.G. Barbosa, S. Letichevsky, L.G. Appel, The one-pot ethyl acetate syntheses: the role of the support in the oxidative and the dehydrogenative routes. Appl. Catal. A-Gen. 380, 113–117 (2010)CrossRef
22.
J.B. Ko, C.M. Bae, Y.S. Jung, D.H. Kim, Cu–ZrO2 catalysts for water-gas-shift reaction at low temperatures Catal. Lett. 105, 157–161 (2005)
23.
Z.Y. Ma, C. Yang, W. Wei, W.H. Li, Y.H. Sun, Catalytic performance of copper supported on zirconia polymorphs for CO hydrogenation. J. Mol. Catal. A Chem. 231, 75–81 (2005)CrossRef
24.
V.K. Chandragiri, I. Neelakanta Reddy, J. Shim, K. Dongseob, Y. Kisoo, A stable novel nanostructure of ZnFe2O4 based nanocomposite for improved photoelectrocatalytic and photocatalytic activities. J. Electroanal. Chem. 823, 517–523 (2018)CrossRef
25.
J.R. De la Rosa, A. Hernandez, F. Rojas, J.J. Ledezma, Sol–gel synthesis and characterization of novel La, Mn and Fe doped zirconia: catalytic combustion activity of trichloroethylene. Colloids Surf. A 315, 147 (2008)CrossRef
26.
R. Gopal, A. KuppulingamSwaminathan, M. Mohamad, S. AlSalhi, S. Devanesan, Versatile fabrication and characterization of Cu-doped ZrO2 nanoparticles: enhanced photocatalytic and photoluminescence properties. Mater. Sci. Mater. Electron. 31, 7232–7246 (2020)CrossRef
27.
L. Renuka, K.S. Anantharaju, S.C. Sharma, H.P. Nagaswarupa, S.C. Prashantha, H. Nagabhushana, Y.S. Vidya, Hollow microspheres Mg-doped ZrO2 nanoparticles: green assisted synthesis and applications in photocatalysis and photoluminescence. J. Alloys Compd. 672, 609–622 (2016)CrossRef
28.
K. Gnanamoorthi, M. Balakrishnan, R. Mariappan, E.R. Kumar, Effect of Ce doping on microstructural, morphological and optical properties of ZrO2 nanoparticles. Mater. Sci. Semicond. Process. 30, 518–526 (2015)CrossRef
29.
K.M. Shrestha, C.M. Sorensen, MgO–TiO2 mixed oxide nanoparticles: comparison of flame synthesis versus aerogel method; characterization, and photocatalytic activities. J. Mater. Res. 28, 431–439 (2012)CrossRef
30.
Y. Liu, G. Zhu, J. Gao, M. Hojamberdiev, R. Zhu, X. Wei, P. Liu, Enhanced photocatalytic activity of Bi4Ti3O12 nanosheets by Fe3+-doping and the addition of Au nanoparticles: photodegradation of phenol and bisphenol A. Appl. Catal. B 200, 72–82 (2017)CrossRef
31.
G. Rajesh, S. Akilandeswari, D. Govindarajan, K. Thirumalai, Facile precipitation synthesis, structural, morphological, photoluminescence and photocatalytic properties of Ni doped ZrO2 nanoparticles. Mater. Res. Express 6, 1050a9 (2019)CrossRef
32.
J.W. Cui, Y.H. Li, L.Y. Zhao, G.H. Cui, Photoluminescence, electrochemical behavior and photocatalytic activities of cobalt(II) coordination polymer nanostructures synthesized by sonochemical process. Ultrason. Sonochem. 39, 837 (2017)CrossRef
33.
M. Alipour, D. Pudasainee, J.A. Nychka, R. Gupta, ZrO2–CuO sorbents for high-temperature air separation. Ind. Eng. Chem. Res. 53, 10990 (2014)CrossRef
34.
F. Rao, G. Zhu, M. Hojamberdiev, W. Zhang, S. Li, J. Gao, Y. Huang, Uniform Zn2+ doped BiOI microspheres assembled by ultrathin nanosheets with tunable oxygen vacancies for super-stable removal of NO. J. Phys. Chem. C 123(26), 16268–16280 (2019)CrossRef
35.
R. Gopal, S. Akilandeswari, K. Thirumalai, M. Swaminathan, S.A. Mohamad, D. Sandhanasamy, Versatile fabrication and characterization of Cu-doped ZrO2 nanoparticles: enhanced photocatalytic and photoluminescence properties. J. Mater. Sci.: Mater. Electron. 31, 7232–7246 (2020)
36.
W. Ahmed, J. Iqbal, Co doped ZrO2 nanoparticles: An efficient visible light triggered photocatalyst with enhanced structural, optical and dielectric characteristics. Ceram. Intl. 46, 25833–25844 (2020)CrossRef
37.
K. Anandan, K. Rajesh, K. Gayathri, S. Vinoth Sharma, S.G. Mohammed Hussain, V. Rajendran, Effects of rare earth, transition and post transition metal ions on structural and optical properties and photocatalytic activities of zirconia (ZrO2) nanoparticles synthesized via the facile precipitation process. Phys. E. 124, 114342 (2020)CrossRef
38.
C. Venkata Reddya, I. Neelakanta Reddya, J. Shima, D. Kimb, K. Yoo, Synthesis and structural, optical, photocatalytic, and electrochemical properties of undoped and yttrium-doped tetragonal ZrO2 nanoparticles. Ceram. Int. 44, 12329–12339 (2018)CrossRef
39.
W. Ahmed, J. Iqbal, O. Samson, O. Aisida, A. Badshah, I. Ahmad, K. Alamgirf, H. Iftikhar Gul, Structural, magnetic and dielectric characteristics of optically tuned Fe doped ZrO2 nanoparticles with visible light driven photocatalytic activity. Mater. Chem. Phys. 251, 122999 (2020)CrossRef
40.
R. Mekala, B. Deepa, V. Rajendran, Preparation, characterization and antibacterial property of rare earth (Dy and Ce) doping on ZrO2 nanoparticles prepared by co-precipitation method. Mater. Today: Proc. 5, 8837–8843 (2018)
41.
S. Sambasivam, V.V. Chandu, M. Gopi, P. Saradhi Maram, H. Mueen Arbi, V. Narayanaswamy, S. Aleksandr Kamzin, I.M. Obaidat, Investigation of optical and magnetic properties of Mn-doped tetragonal ZrO2 nanocrystals. J. Solid State Chem. 294, 121872 (2021)CrossRef
42.
K. Gnanamoorthi, M. Balakrishnan, R. Mariappan, E. Ranjith Kumar, Effect of Ce doping on microstructural, morphological and optical properties of ZrO2 nanoparticles. Mater. Sci. Semicond. Process. 30, 518–526 (2015)CrossRef
43.
B. Sathyaseelan, E. Manikandan, I. Baskaran, K. Senthilnathan, K. Sivakumar, M.K. Moodley, R. Ladchumananandasivam, M. Maaza, Studies on structural and optical properties of ZrO2 nanopowder for opto-electronic applications. J. Alloys Compd. 694, 556–559 (2017)CrossRef
44.
G. Kaur Sidhu, R. Kumar, Role of anionic and cationic surfactants on the structural and dielectric properties of ZrO2 nanoparticles. Appl. Surf. Sci. 392, 598–607 (2017)CrossRef
45.
H.C. Madhusudhana, S.N. Shobhadevi, B.M. Nagabhushana, R. Hari Krishna, M.V. Murugendrappa, H. Nagabhushana, Structural characterization and dielectric studies of Gd doped ZrO2 nano crystals synthesized by solution combustion method. Mater. Today: Proc. 5, 21195–21204 (2018)
46.
B. Choudhury, M. Dey, A. Choudhury, Defect generation, d-d transition, and band gap reduction in Cu-doped TiO2 nanoparticles Int. Nano Lett. 3, 25 (2013)CrossRef
47.
W.B. Li, X.F. Yang, L.F. Chen, J.A. Wang, Adsorption/desorption of NOx on MnO2/ZrO2 oxides prepared in reverse microemulsions. Catal. Today 148, 75–80 (2009)CrossRef
48.
J. Berlin, S. Sujatha, V. Ganesan, P.V. Thomas, K. Joy, Effect of Mn doping on the structural and optical properties of ZrO2 thin films prepared by sol–gel method. Thin Solid Films 550, 19 (2014)CrossRef
49.
H. Zhu, D. Yang, Z. Xi, L. Zhu, Hydrothermal synthesis and characterization of zirconia nanocrystallites. Commun. Am. Ceram. Soc. 90, 1334 (2007)CrossRef
50.
S.Z.M. Salavati-niasari, Synthesis of Co2P/Co nanocomposites using single source precursor by thermal decomposition method. J. Mater. Sci. 27, 3918 (2016)
51.
L. Li, W. Wang, Synthesis and characterization of monoclinic ZrO2 nanorods by a novel and simple precursor thermal decomposition approach. Solid State Commun. 127, 639 (2003)CrossRef
52.
H. Toraya, Calibration curve for quantitative analysis of the monoclinic-tetragonal ZrO2 system by X-ray diffraction. Commun. Am. Ceram. Soc. 67, 119 (1984)
53.
T. Lopez, M. Alvarez, F. Tzompantzi, M. Picquart, Photocatalytic degradation of 2,4-dichlorophenoxiacetic acid and 2,4,6-trichlorophenol with ZrO2 and Mn/ZrO2 sol-gel materials. J. Sol-Gel Sci. Technol. 37, 207 (2006)CrossRef
54.
S. Ramya, G. Viruthagiri, R. Gobi, N. Shanmugam, N. Kannadasan, Synthesis and characterization of Ni2+ ions incorporated CuO nanoparticles and its application in antibacterial activity. J. Mater. Sci. Mater. Elect. 27, 2701 (2016)CrossRef
55.
Y.F. Sun, S.B. Liu, F.L. Meng, J.Y. Liu, Z. Jin, L.T. Kong, J.H. Liu, Metal oxide nanostructures and their gas sensing properties: a review. Sensors 12, 2610 (2012)CrossRef
56.
S. Sujathalekshmy, V. Ganesan, P.V. Thomas, K. Joy, Effect of Mn doping on the structural and optical properties of ZrO2 thin films prepared by sol–gel method. Thin Solid Films 550, 199 (2014)CrossRef
57.
Y.S. Zhang, L.T. Hu, H. Zhang, J.M. Chen, W.M. Liu, Stable bionic superhydrophobic coating surface fabricated by a conventional curing process. J. Mater Process. Technol. 198, 191 (2008)CrossRef
58.
J. Kennedy, P.P. Murmu, P.S. Gupta, D.A. Carder, S.V. Chong, J. Leveneur, S. Rubanov, Effects of annealing on the structural and optical properties of zinc sulfide thin films deposited by ion beam sputtering. Mater. Sci. Semicond. Pro. 26, 561 (2014)CrossRef
59.
60.
R.C. Ramola, M. Rawat, K. Joshi, A. Das, S.K. Gautam, F. Singh, Study of phase transformation induced by electronic excitation in pure and yttrium doped ZrO2 thin films. Mater. Res. Exp. 4, 096401 (2017)CrossRef
61.
V. Kumar, S. Kumari, P. Kumar, M. Kar, Structural and magnetic properties of nanocrystalline yttrium substituted cobalt ferrite synthesized by the citrate precursor technique. Mater. Lett. 6, 139 (2015)CrossRef
62.
P. Ji, Z. Mao, Z. Wang, X. Xue, Y. Zhang, J. Lv, X. Shi, Improved surface-enhanced Raman scattering properties of ZrO2 nanoparticles by Zn doping. Nanomaterials 9(7), 983 (2019)CrossRef
63.
E.S. Agorku, A.T. Kuvarega, B.B. Mamba, A.C. Pandey, A.K. Mishra, Enhanced visible-light photocatalytic activity of multi-elements-doped ZrO2 for degradation of indigo carmine. J. Rare Earth 33, 498 (2015)CrossRef
Metadaten
Titel
Structural, optical and electrical properties of copper composite ZrO2 nanoparticles prepared via sol–gel method
verfasst von
N. Mahendran
S. Johnson Jeyakumar
M. Ponnar
Publikationsdatum
20.08.2021
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 18/2021
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-021-06828-z

Weitere Artikel der Ausgabe 18/2021

Journal of Materials Science: Materials in Electronics 18/2021 Zur Ausgabe

OriginalPaper

Lattice vibrational modes, crystal structure, and dielectric properties of phase pure Ba(Mg1/2Mo1/2)O3 ceramic

OriginalPaper

Facile fabrication of bimetallic Fe2P–Ni2P heterostructure for boosted oxygen evolution

OriginalPaper

Nano-crystalline powders and microwave dielectric properties of Zr0.8Sn0.2TiO4 ceramics derived using deep eutectic solvents

OriginalPaper

An electrochemical enzyme-free glucose sensor based on bimetallic PtNi materials

OriginalPaper

Co-modified Ni/N-doped carbon as electrocatalysts for HER and OER

OriginalPaper

Novel NBT-based relaxor ferroelectric ceramics with excellent discharge performance and high-temperature stability

Neuer Inhalt

    Bildnachweise