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Cellulose

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01.08.2014 | Original Paper

Highly specific capacitance materials constructed via in situ synthesis of polyaniline in a cellulose matrix for supercapacitors

verfasst von: Xingwei Shi, Yanli Hu, Mingzhe Li, Yanwen Y. Duan, Yixiang Wang, Lingyun Chen, Lina Zhang

Erschienen in: Cellulose | Ausgabe 4/2014

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Abstract

On the basis of the requirements for both biobased economy and energy storage materials, we are interested in using cellulose-based microporous film as a template for in situ synthesis of polyaniline (PANI). Multifunctional carbon nanotube (CNT)/cellulose composite films were also prepared from a CNT/cellulose suspension in a NaOH/urea aqueous system. Subsequently, PANI was synthesized in situ in the pores of cellulose and CNT/cellulose substrates to construct PANI/cellulose (PC) films and PANI/CNT/cellulose (PCC) films, respectively. Both PC and PCC films were flexible and exhibited a highly specific capacitance and good cycle stability. With the addition of CNTs, the specific capacitance of the PCC films as supercapacitor materials was significantly improved. Moreover, a homogeneous structure intertwined with the cellulose, CNTs and PANI appeared in the composite films, indicating good miscibility. This work has provided a new approach to the fabrication of flexible, lightweight, highly effective, and low-cost energy storage materials, broadening the applications of cellulose.

Vorheriger Artikel Efficient hydrolyzation of cellulose in ionic liquid by novel sulfonated biomass-based catalysts

Nächster Artikel Symbiosis of photosynthetic microorganisms with non-photosynthetic ones for the conversion of cellulosic mass into electrical energy and pigments

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Titel: Highly specific capacitance materials constructed via in situ synthesis of polyaniline in a cellulose matrix for supercapacitors
verfasst von: Xingwei Shi
Yanli Hu
Mingzhe Li
Yanwen Y. Duan
Yixiang Wang
Lingyun Chen
Lina Zhang
Publikationsdatum: 01.08.2014
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 4/2014
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-014-0288-1

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