nach oben

Cellulose

Erschienen in:

25.11.2021 | Original Research

Adsorbent grafted on cellulose by in situ synthesis of EDTA-like groups and its properties of metal ion adsorption from aqueous solution

verfasst von: Tao Hu, Xiaoli Hu, Cheng Tang, Dan Liu

Erschienen in: Cellulose | Ausgabe 2/2022

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

This paper describes the synthesis of a novel chelating material derived from cellulose, and its heavy metal ion adsorption properties from aqueous solution. The first section of this paper reports the chemical grafting of cellulose, that amino acetic acid groups were grafted onto the cellulose by in situ synthesis, a novel yet unreported modified cellulose derivative N,N-(dicarboxymethylaminoethyl, carboxymethyl)aminoethylamine carboxymethyl cellulose amide was synthesized. This obtained adsorbent was characterized by elemental analysis, infrared spectroscopy (IR) and Solid State Nuclear Magnetic Resonance (SSNMR) ¹³C NMR spectroscopy. In the second section, the adsorption of Cu²⁺and Pb²⁺ from single metal ion aqueous solutions onto this adsorbent were evaluated and analyzed by the Freundlich and Langmuir models. Further more, adsorption capacity for Ba²⁺, Mg²⁺, Mn²⁺, Co²⁺, Zn²⁺, Pb²⁺, Ni²⁺ and Cu²⁺, and the competitive adsorption of this adsorbent between ions were also evaluated by ICP spectroscopy. The results indicated that this modified cellulose exhibited adsorption properties similar to those of EDTA, and showed good adsorption capacity for a wide range of metal ions.

Graphical abstract

Vorheriger Artikel Full bagasse bio-waste derived 3D photothermal aerogels for high efficient solar steam generation

Nächster Artikel Hierarchical porous aero-cryogels for wind energy enhanced solar vapor generation

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Ardiyanita PZ, Sutriyo S, Suryadi H (2020) Preparation and characterization of sodium carboxymethyl cellulose from kapok (Ceiba Pentandra) alpha-cellulose. Int J Appl Pharm 12:9–14. https://doi.org/10.22159/ijap.2020.v12s1.25840CrossRef

Barakat MA (2011) New trends in removing heavy metals from industrial wastewater. Arab J Chem 4:361–377. https://doi.org/10.1016/j.arabjc.2010.07.019CrossRef

Bhalla V, Kumar R, Kumar M, Dhir A (2007) Bifunctional fluorescent thiacalix[4]arene based chemosensor for Cu²⁺ and F⁻ ions. Tetrahedron 63:11153–11159. https://doi.org/10.1016/j.tet.2007.08.021CrossRef

Cao J, Fei D, Tian X, Zhu Y, Wang S, Zhang Y, Mao Q, Sun M (2017) Novel modified microcrystalline cellulose-based porous material for fast and effective heavy-metal removal from aqueous solution. Cellulose 24:5565–5577. https://doi.org/10.1007/s10570-017-1504-6CrossRef

Carver PL (2013) Metal ions and infectious diseases: an overview from the clinic. In: Sigel A, Sigel H, Sigel RKO (eds) Interrelations between essential metal ions and human diseases: metal ions in life sciences. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-7500-8_1CrossRef

Chauhan GS, Guleria L, Sharma R (2005) Synthesis, characterization and metal ion sorption studies of graft copolymers of cellulose with glycidyl methacrylate and some comonomers. Cellulose 12:97–110. https://doi.org/10.1007/s10570-004-2720-4CrossRef

d’Halluin M, Rull-Barrull J, Bretel G, Labrugère C, Le Grognec E, Felpin F-X (2017) Chemically modified cellulose filter paper for heavy metal remediation in water. ACS Sustain Chem Eng 5:1965–1973. https://doi.org/10.1021/acssuschemeng.6b02768CrossRef

Gao X, Zhang H, Chen K, Zhou J, Liu Q (2018) Removal of heavy metal and sulfate ions by cellulose derivative-based biosorbents. Cellulose 25:2531–2545. https://doi.org/10.1007/s10570-018-1690-xCrossRef

Ho YS, Chiu WT, Wang CC (2005) Regression analysis for the sorption isotherms of basic dyes on sugarcane dust. Biores Technol 96:1285–1291. https://doi.org/10.1016/j.biortech.2004.10.021CrossRef

Hosangadi BD, Dave RH (1996) An efficient general method for esterification of aromatic carboxylic acids. Tetrahedron Lett 37:6375–6378. https://doi.org/10.1016/0040-4039(96)01351-2CrossRef

Huang Y, Yang C, Sun Z, Zeng G, He H (2015) Removal of cadmium and lead from aqueous solutions using nitrilotriacetic acid anhydride modified ligno-cellulosic material. RSC Adv 5:11475–11484. https://doi.org/10.1039/C4RA14859BCrossRef

Jilal I, El Barkany S, Bahari Z, Sundman O, El Idrissi A, Abou-Salama M, Romane A, Zannagui C, Amhamdi H (2018) New quaternized cellulose based on hydroxyethyl cellulose (HEC) grafted EDTA: Synthesis, characterization and application for Pb (II) and Cu (II) removal. Carbohyd Polym 180:156–167. https://doi.org/10.1016/j.carbpol.2017.10.012CrossRef

Júnior OK, Gurgel LVA, de Freitas RP, Gil LF (2009) Adsorption of Cu(II), Cd(II), and Pb(II) from aqueous single metal solutions by mercerized cellulose and mercerized sugarcane bagasse chemically modified with EDTA dianhydride (EDTAD). Carbohyd Polym 77:643–650. https://doi.org/10.1016/j.carbpol.2009.02.016CrossRef

Karnitz O, Gurgel LVA, de Melo JCP, Botaro VR, Melo TMS, de Freitas Gil RP, Gil LF (2007) Adsorption of heavy metal ion from aqueous single metal solution by chemically modified sugarcane bagasse. Biores Technol 98:1291–1297. https://doi.org/10.1016/j.biortech.2006.05.013CrossRef

Kirsipuu T, Zadorožnaja A, Smirnova J, Friedemann M, Plitz T, Tõugu V, Palumaa P (2020) Copper(II)-binding equilibria in human blood. Sci Rep 10:5686. https://doi.org/10.1038/s41598-020-62560-4CrossRefPubMedPubMedCentral

Lim MH, Lippard SJ (2007) Metal-based turn-on fluorescent probes for sensing nitric oxide. Acc Chem Res 40:41–51. https://doi.org/10.1021/ar950149tCrossRefPubMed

Lin X, Jin J, Guo X, Jia X (2021) All-carboxymethyl cellulose sponges for removal of heavy metal ions. Cellulose 28:3113–3122. https://doi.org/10.1007/s10570-021-03685-1CrossRef

Mengxuan Hu PX, Wang L, Liu Y (2016) Research progress of heavy metal ions removal in desulfurization wastewater. Water Pollut Treat 4:85–90CrossRef

Nongbe MC, Bretel G, Ekou T, Ekou L, Yao BK, Le Grognec E, Felpin FX (2018) Cellulose paper grafted with polyamines as powerful adsorbent for heavy metals. Cellulose 25:4043–4055. https://doi.org/10.1007/s10570-018-1833-0CrossRef

Pereira TCB, Campos MM, Bogo MR (2016) Copper toxicology, oxidative stress and inflammation using zebrafish as experimental model. J Appl Toxicol 36:876–885. https://doi.org/10.1002/jat.3303CrossRefPubMed

Singh AV, Singh R et al (2012) Synthesis, characterization and application of cellulose nitrilotriacetic acid (CNTAA) resin for removal of heavy metal ions from industrial effluent. J Indian Chem Soc 89:77–84

Tsukinoki S, Yamada K, Ito O, Nanbu N, Belles-lettre A (2008) Solid phase extration of Cu, Ni and Co by EDTA type chelating cellulose. Jpn Soc Anal Chem 57:1033–1038. https://doi.org/10.2116/bunsekikagaku.57.1033CrossRef

Vaughan T, Seo CW, Marshall WE (2001) Removal of selected metal ions from aqueous solution using modified corncobs. Biores Technol 78:133–139. https://doi.org/10.1016/S0960-8524(01)00007-4CrossRef

Wilpiszewska K, Antosik AK, Schmidt B, Janik J, Rokicka J (2020) Hydrophilic films based on carboxymethylated derivatives of starch and cellulose. Polymer 12:2447. https://doi.org/10.3390/polym12112447CrossRef

Xu C, Liu F, Ling C et al (2014) Research progress in adsorption performance of heavy metal ion with polyamine chelating adsorbents: a review. Ion Exch Adsorpt 30:87–96. https://doi.org/10.16026/j.cnki.iea.2014.01.003CrossRef

Titel: Adsorbent grafted on cellulose by in situ synthesis of EDTA-like groups and its properties of metal ion adsorption from aqueous solution
verfasst von: Tao Hu
Xiaoli Hu
Cheng Tang
Dan Liu
Publikationsdatum: 25.11.2021
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 2/2022
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-021-04324-5

Springer Professional

Abstract

Graphical abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Springer Professional "Wirtschaft+Technik"

Weitere Artikel der Ausgabe 2/2022

A salt-free, zero-discharge and dyebath-recyclable circular coloration technology based on cationic polyelectrolyte complex for cotton fabric dyeing

Humidity influence on mechanics of paper materials: joint numerical and experimental study on fiber and fiber network scale

The influence of the multi-level structure under high drawing on the preparation of high strength Lyocell fiber

Highly antibacterial hydrogels prepared from amino cellulose, dialdehyde xylan, and Ag nanoparticles by a green reduction method

Local force titration of wood surfaces by chemical force microscopy

Surfactant-free cellulose filaments stabilized oil in water emulsions