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Arabian Journal for Science and Engineering
Erschienen in: Arabian Journal for Science and Engineering 12/2019

12.07.2019 | Research Article - Chemical Engineering

Effective Dephenolation of Effluent from Petroleum Industry Using Ionic-Liquid-Induced Hybrid Adsorbent

verfasst von: M. N. Abonyi, C. O. Aniagor, M. C. Menkiti

Erschienen in: Arabian Journal for Science and Engineering | Ausgabe 12/2019

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Abstract

In this study, naturally heated clay (NHC) was complexed with synthesized ionic liquid (1-ethyl-3-methyl imidazolium bromide solution (EMIB)) to form NHC/EMIB composite. The effectiveness of NHC/EMIB composite in comparison with naturally heated clay (NHC) as an eco-friendly adsorbent for dephenolation of petroleum effluent was investigated. The adsorbents were characterized using Fourier transform infrared spectroscopy and scanning electron microscopy. Batch mode experiments were conducted to ascertain the effect of process variables on adsorption. Removal efficiencies of 81.70% and 91.7% were obtained for NHC and NHC/EMIB composite, respectively, at 25 min, 308 K, pH 4.0 and 150 µm. The linear and nonlinear isotherm data fitted best to the Langmuir model for both adsorbent, while the linear and nonlinear kinetic data fitted best to pseudo-second-order and pseudo-first-order models for both adsorbents. The estimated average thermodynamic parameters (ΔG0 = − 9.653 kJ/mol, ΔH0 = –28.295 kJ/mol and ΔS0 = –46.395 kJ/mol) revealed the feasibility, exothermic nature and spontaneity, respectively, of the studied adsorption system.
Vorheriger Artikel Influence of the Release Kinetics of Chemical Species on the Sustainability of Stabilized/Solidified Materials with Hydraulic Binder Subjected to Chemically Aggressive Environments
Nächster Artikel Characterization of Bauxite as a Potential Natural Photocatalyst for Photodegradation of Textile Dye

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Metadaten
Titel
Effective Dephenolation of Effluent from Petroleum Industry Using Ionic-Liquid-Induced Hybrid Adsorbent
verfasst von
M. N. Abonyi
C. O. Aniagor
M. C. Menkiti
Publikationsdatum
12.07.2019
Verlag
Springer Berlin Heidelberg
Erschienen in
Arabian Journal for Science and Engineering / Ausgabe 12/2019
Print ISSN: 2193-567X
Elektronische ISSN: 2191-4281
DOI
https://doi.org/10.1007/s13369-019-04000-8

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