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Polymer Bulletin
Erschienen in: Polymer Bulletin 5/2010

01.09.2010 | Original Paper

Rheological and mechanical properties of poly(lactic acid)/polystyrene polymer blend

verfasst von: Kotiba Hamad, Mosab Kaseem, Fawaz Deri

Erschienen in: Polymer Bulletin | Ausgabe 5/2010

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Abstract

Properties modification by blending polymers has been an area of immense interest. In this work, rheological and mechanical properties of poly(lactic acid)/polystyrene (PLA/PS) blends were investigated. PLA/PS blends in different ratios were prepared using a laboratory scale single screw extruder to obtain (3 mm) granules. Rheological properties were studied using a capillary rheometer and the Bagley’s correction was performed. True shear rate (γ r ), true shear stress (τ r ), and true viscosity (η r ) were determined, the relationship between true viscosity and (1/T) was studied for PLA70 blend and the flow activation energy at a constant shear stress (E τ ) and a constant shear rate (E γ ) was determined. The mechanical property measurements were performed at room temperature. Stress at break and strain at break were determined. The results showed that PLA/PS blend exhibited a typical shear-thinning behavior over the range of the studied shear rates, and the viscosity of the blend decreased with increasing PLA content. Also it was found that no equal-viscosity temperature exists between PLA and PS. The mechanical results showed immiscibility between PLA and PS in the blend.
Vorheriger Artikel Effect of the presence of lignin or peat in IPN hydrogels on the sorption of heavy metals
Nächster Artikel Effect of end-group modification on the adsorption of poly(ethylene oxide)-b-poly(butylene oxide) diblock copolymers at the solid–liquid interface

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Literatur
1.
Lunt J (1998) Larg-scale production, properties and commercial applications of poly lactic acid polymers. Polym Degrad Stab 59:145–152CrossRef
2.
Ishida S, Nagasaki R, Chino K, Dong T, Inoue Y (2009) Toughening of poly(l-lactide) by melt blending with rubbers. J Appl Polym Sci 113:558–566CrossRef
3.
Sarazin P, Li G, Orts W, Favis B (2008) Binary and ternary blends of polylactide, polycaprolactone and thermoplastic starch. Polymer 49:599–609CrossRef
4.
Wang N, Yu J, Chang P, Ma X (2008) Influence of formamide and water on the properties of thermoplastic starch/poly(lactic acid) blends. Carbohydr Polym 71:109–118CrossRef
5.
Wang N, Yu J, Ma X (2008) Preparation and characterization of compatible thermoplastic dry starch/poly(lactic acid). Polym Compos 29:551–559CrossRef
6.
Wang N, Yu J, Ma X (2007) Preparation and characterization of thermoplastic starch/PLA blends by one-step reactive extrusion. Polym Inter 56:1440–1447CrossRef
7.
Wang N, Yu J, Chang P, Ma X (2007) Influence of citric acid on the properties of glycerol-plasticized dry starch (DTPS) and DTPS/Poly(lactic acid) blends. Starch 59:409–417CrossRef
8.
Huneault M, Li H (2007) Morphology and properties of compatibilized polylactide/thermoplastic starch blends. Polymer 48:270–280CrossRef
9.
Bhatia A, Gupta R, Bhattacharya S, Choi H (2007) Compatibility of biodegradable poly (lactic acid) (PLA) and poly (butylenes succinate) (PBS) blends for packaging application. Korea-Australia Rheo J 19:125–131
10.
Lee S, Lee JW (2005) Characterization and processing of Biodegradable polymer blends of poly(lactic acid) with poly(butylene succinate adipate). Korea-Australia Rheo J 17:71–77
11.
Ren J, Fu H, Ren T, Yuan W (2009) Preparation, characterization and properties of binary and ternary blends with thermoplastic starch, poly(lactic acid) and poly(butylene adipate-co-terephthalate). Carbohydr Polym 77:576–582CrossRef
12.
Yeh JT, Tsou CH, Huang CY, Chen KN, Wu CS, Chai WL (2009) Compatible and crystallization properties of poly(lactic acid)/poly(butylene adipate-co-terephthalate) blends. J Appl Polym Sci 116:680–687
13.
Coltelli MB, Maggiore ID, Bertoldo M, Signori F, Bronco S, Ciardelli F (2008) Poly(lactic acid) properties as a consequence of poly(butylene adipate-co-terephthalate) blending and acetyl tributyl citrate plasticization. J Appl Polym Sci 110:1250–1262CrossRef
14.
Xiao H, Lu W, Yeh JT (2008) Crystallization behavior of fully biodegradable poly(lactic acid)/poly(butylene adipate-co-terephthalate) blends. J Appl Polym Sci 112:3754–3763CrossRef
15.
Li Y, Shimizu H (2009) Improvement in toughness of poly(l-lactic acid) (PLLA) through reactive blending with acrylonitrile–butadiene–styrene copolymer (ABS): morphology and properties. Eur Polym J 45:738–746CrossRef
16.
Bourmaud A, Pimbert S (2008) Investigations on mechanical properties of poly(propylene) and poly(lactic acid) reinforced by miscanthus fibers. Composites A 39:1444–1454CrossRef
17.
Reddy N, Nama D, Yang Y (2008) Polylactic acid/polypropylene polyblend fibers for better resistance to degradation. Polym Degrad Stab 39:233–241CrossRef
18.
Anderson KS, Hillmyer MA (2004) The influence of block copolymer microstructure on the toughness of compatibilized polylactide/polyethylene blends. Polymer 45:8809–8823CrossRef
19.
Schlemmer D, Sales M, Resck IS (2009) Degradation of different polystyrene/thermoplastic starch blends buried in soil. Carbohydr Polym 75:58–62CrossRef
20.
Schlemmer D, Oliveira ER, Sales M (2007) Polystyrene/theromoplastic starch blends with different plasticizer, preparation and thermal characterization. J Therm Anal Calorim 87:635–638CrossRef
21.
Pimentel T, Duraes J, Drummond A, Schlemmer D, Falcao R, Sales M (2007) Preparation and characterization of blends of recycled polystyrene with cassava starch. J Mater Sci 42:7530–7536CrossRef
22.
Mihai M, Huneault M, Favias B (2007) Foaming of polystyrene/thermoplastic starch blends. J Cell Plast 43:215–236CrossRef
23.
Tadmor Z, Gogos CG (2006) Principles of polymer processing. Wiley, New Jersey
24.
Han CD (2007) Rheology and processing of polymeric materials (Polymer Processing). Oxford University Press, New York
25.
Bagley EB (1957) End corrections in the capillary flow of polyethylene. J Appl Phys 28:624–627CrossRef
26.
Sinthavathavorn W, Nithitanakul M, Grady B, Mangaraphan R (2009) Melt rheology and die swell of PA6/LDPE blends by using lithium ionomer as a compatibilizer. Polym Bull 63:23–35CrossRef
27.
Lenk RS (1978) Polymer rheology. Applied Science Publishers Ltd, London
28.
Ebewele RO (2000) Polymer science and technology. CRC Press LLC Publication, FloridaCrossRef
29.
Biresaw G, Carriere CJ (2004) Compatibility and mechanical properties of blends of polystyrene with biodegradable polyesters. Composites A 35:313–320CrossRef
Metadaten
Titel
Rheological and mechanical properties of poly(lactic acid)/polystyrene polymer blend
verfasst von
Kotiba Hamad
Mosab Kaseem
Fawaz Deri
Publikationsdatum
01.09.2010
Verlag
Springer-Verlag
Erschienen in
Polymer Bulletin / Ausgabe 5/2010
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-010-0354-2

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