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Erschienen in: Cellulose 1/2013

01.02.2013 | Original Paper

Hydrophobic modification of cellulose fibres by cationic-modified polyacrylate latex with core-shell structure

verfasst von: Yuanfeng Pan, Huining Xiao, Zhaoping Song

Erschienen in: Cellulose | Ausgabe 1/2013

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Abstract

In cellulose fibre-based green packaging, the poor resistance or barrier against water or water vapour has remained as one of the key challenges. In this work, cationic polymer latex, butyl acrylate-co-styrene/2-ethylhexylacrylate-co-methyl methacrylate (BA-co-St/EHA-co-MMA), with core-shell structure was especially synthesized and used as a wet-end additive to render the fibre or paper hydrophobic. TEM observation confirmed that the latex particles obtained indeed possessed desired characteristic of core-shell structure. The experimental results showed that the cationic polymer was especially suitable for use in papermaking processes due to its high retention with cellulose fibres. The surface modification of the natural fibre by the adsorption of cationic latex on the fibre surfaces potentially created the thin films of polymers on fibre surfaces. The resulting paper is highly hydrophobic with improved barrier property, as demonstrated by the high contact angles and relatively low WVTR value. Moreover, the mechanical properties of paper were maintained or even improved in the presence of an appropriate level of the latex.

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Metadaten
Titel
Hydrophobic modification of cellulose fibres by cationic-modified polyacrylate latex with core-shell structure
verfasst von
Yuanfeng Pan
Huining Xiao
Zhaoping Song
Publikationsdatum
01.02.2013
Verlag
Springer Netherlands
Erschienen in
Cellulose / Ausgabe 1/2013
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-012-9837-7

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