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07.09.2017 | Original Paper

Modified nanoporous magnetic cellulose–chitosan microspheres for efficient removal of Pb(II) and methylene blue from aqueous solution

verfasst von: Shuai Peng, Yi Liu, Zhiyong Xue, Weiyan Yin, Xiaocong Liang, Ming Li, Jie Chang

Erschienen in: Cellulose | Ausgabe 11/2017

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Abstract

Pyromellitic dianhydride-modified nanoporous magnetic cellulose–chitosan microspheres (PNMCMs) were designed and synthesized to introduce abundant carboxyl groups onto the basic microstructure. The novel microspheres were studied by scanning electron microscopy (SEM), Fourier-transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD) analysis, thermogravimetric analysis (TGA), and X-ray photoelectron spectroscopy (XPS). Subsequently, a batch technique was applied to investigate various environmental parameters that could affect the adsorption behavior of the PNMCMs. Due to its nanoporous structure and large quantity of carboxyl groups, the cellulose/chitosan-based bioadsorbent exhibited excellent adsorption performance for removal of Pb(II) ions and methylene blue (MB) from aqueous solution, with maximum adsorption capacity of 384.6 and 833.3 mg/g, respectively. Furthermore, the adsorption kinetics and isotherms of Pb(II) ions and MB on PNMCMs obeyed the pseudo-second-order and Langmuir isotherm models, and the rate of adsorption was found to be controlled by film diffusion. Finally, the PNMCMs with adsorbed Pb(II) and MB could be easily regenerated using HCl, retaining removal capacity of almost 89% after six repeated uses.

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Titel: Modified nanoporous magnetic cellulose–chitosan microspheres for efficient removal of Pb(II) and methylene blue from aqueous solution
verfasst von: Shuai Peng
Yi Liu
Zhiyong Xue
Weiyan Yin
Xiaocong Liang
Ming Li
Jie Chang
Publikationsdatum: 07.09.2017
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 11/2017
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-017-1463-y

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