nach oben

Cellulose

Erschienen in:

18.01.2018 | Original Paper

Fabrication of carboxymethyl-functionalized porous ramie microspheres as effective adsorbents for the removal of cadmium ions

verfasst von: Xiongyi Peng, Siwei Su, Minggui Xia, Kankan Lou, Feng Yang, Shuai Peng, Yingjie Cai

Erschienen in: Cellulose | Ausgabe 3/2018

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

Ramie fiber, one of the strongest and oldest natural fibers, has gained much interest in adsorption of heavy metal ions in water, however, it is severely limited due to the low response rates and low adsorption capability to heavy metal ions. A novel type of carboxymethyl-functionalized porous ramie microspheres (CPRM) were prepared with a combined emulsification-evaporation method and a carboxymethylation reaction, in order to effectively remove Cd(II) in water. XPS and FTIR characterizations confirmed that the carboxyl groups were introduced onto the CPRM. The diameters of the CPRM mainly lied within the range of 8–12 μm, and the BET surface area of the CPRM was 47.6 m²/g. SEM images confirmed a porous structure was present on the CPRM surface. The CPRM obtained a high adsorption capacity of Cd(II) (173.1 mg/g) at 303 K, which was higher than most reported conventional adsorbents. The adsorption isotherms and the kinetics were in agreement with the Langmuir isotherm model and the pseudo-second-order kinetic model. The process was both endothermic and spontaneous. The CPRM could also remove Cd(II), Pb(II), Ni(II), and Zn(II) from wastewater with various efficiencies. The Cd(II)-loading CPRM could be successfully regenerated by the HCl and NaOH treatment. The CPRM show good potential for purifying wastewater.

Vorheriger Artikel Activated carbon derived from chitin aerogels: preparation and CO2 adsorption

Nächster Artikel Polyelectrolyte layer assembly of bacterial nanocellulose whiskers with plasmid DNA as biocompatible non-viral gene delivery system

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Abney CW, Gilhula JC, Lu K, Lin W (2014) Metal-organic framework templated inorganic sorbents for rapid and efficient extraction of heavy metals. Adv Mater 26:7993–7997CrossRef

Benhammou A, Yaacoubi A, Nibou L, Tanouti B (2005) Adsorption of metal ions onto Moroccan stevensite: kinetic and isotherm studies. J Colloid Interface Sci 282:320–326CrossRef

Brunauer S, Emmett PH, Teller E (1938) Adsorption of gases in multimolecular layers. J Am Chem Soc 60:309–319CrossRef

Cai Y, Huang Y, Liu F, He L, Lin L, Zeng Q (2014) Liquid ammonia dyeing of cationic ramie yarn with triazinyl reactive dyes. Cellulose 21:3841–3849CrossRef

El-Sheikh AH, Sweileh JA, Al-Degs YS, Insisi AA, Al-Rabady N (2008) Critical evaluation and comparison of enrichment efficiency of multi-walled carbon nanotubes, C18 silica and activated carbon towards some pesticides from environmental waters. Talanta 74:1675–1680CrossRef

Feng Y, Gong JL, Zeng GM, Niu QY, Zhang HY, Niu CG, Deng JH, Yan M (2010) Adsorption of Cd(II) and Zn(II) from aqueous solutions using magnetic hydroxyapatite nanoparticles as adsorbents. Chem Eng J 162:487–494CrossRef

Freundlich HMF (1906) Over the adsorption in solution. J Phys Chem 57:385–470

Geary CD, Zudans I, Goponenko AV, Asher SA, Weber SG (2005) Electrochemical investigation of Pb²⁺ binding and transport through a polymerized crystalline colloidal array hydrogel containing benzo-18-crown-6. Anal Chem 77:185–192CrossRef

Gundogdu A, Duran C, Senturk HB, Soylak M, Ozdes D, Serencam H, Imamoglu M (2012) Adsorption of phenol from aqueous solution on a low-cost activated carbon produced from tea industry waste: equilibrium, kinetic, and thermodynamic study. J Chem Eng Data 57:2733–2743CrossRef

Guo J, Guo X, Wang S, Yin Y (2016) Effects of ultrasonic treatment during acid hydrolysis on the yield, particle size and structure of cellulose nanocrystals. Carbohydr Polym 135:248–255CrossRef

Ho YS, Mckay G (1998) A comparison of chemisorption kinetic models applied to pollutant removal on various sorbents. Process Saf Environ 76:332–340CrossRef

Kilic M, Apaydin-Varol E, Pütün AE (2011) Adsorptive removal of phenol from aqueous solutions on activated carbon prepared from tobacco residues: equilibrium, kinetics and thermodynamics. J Hazard Mater 189:397–403CrossRef

Kurniawan TA, Chan GY, Lo WH, Babel S (2006) Comparisons of low-cost adsorbents for treating wastewaters laden with heavy metals. Sci Total Environ 366:409–426CrossRef

Langmuir I (1918) The adsorption of gases on plane surface of glass, mica and platinum. J Am Chem Soc 40:1361–1403CrossRef

Li X, Li Y, Ye Z (2011) Preparation of macroporous bead adsorbents based on poly(vinyl alcohol)/chitosan and their adsorption properties for heavy metals from aqueous solution. Chem Eng J 178:60–68CrossRef

Li Z, Ge Y, Wan L (2015a) Fabrication of a green porous lignin-based sphere for the removal of lead ions from aqueous media. J Hazard Mater 285:77–83CrossRef

Li Z, Kong Y, Ge Y (2015b) Synthesis of porous lignin xanthate resin for Pb²⁺ removal from aqueous solution. Chem Eng J 270:229–234CrossRef

Li Z, Xiao D, Ge Y, Koehler S (2015c) Surface-functionalized porous lignin for fast and efficient lead removal from aqueous solution. ACS Appl Mater Interfaces 7:15000–15009CrossRef

Li Z, Chen J, Zhou J, Zheng L, Pradel KC, Fan X, Guo H, Wen Z, Yeh MH, Yu C, Wang Z (2016) High-efficiency ramie fiber degumming and self-powered degumming wastewater treatment using triboelectric nanogenerator. Nano Energy 22:548–557CrossRef

Li Z, Chen J, Ge Y (2017) Removal of lead ion and oil droplet from aqueous solution by lignin-grafted carbon nanotubes. Chem Eng J 308:809–817CrossRef

Liu ZT, Yang Y, Zhang L, Sun P, Liu ZW, Lu J, Xiong H, Peng Y, Tang S (2008) Study on the performance of ramie fiber modified with ethylenediamine. Carbohydr Polym 71:18–25CrossRef

Liu Y, Yan C, Zhang Z, Wang H, Zhou S, Zhou W (2016) A comparative study on fly ash, geopolymer and faujasite block for Pb removal from aqueous solution. Fuel 185:181–189CrossRef

Ma H, Pu S, Ma J, Yan C, Zinchenko A, Pei X, Ch W (2018) Formation of multi-layered chitosan honeycomb spheres via breath-figure-like approach in combination with co-precipitation processing. Mater Lett 211:91–95CrossRef

Mahmood-Ul-Hassan M, Suthar V, Rafique E, Ahmad R, Yasin M (2015) Kinetics of cadmium, chromium, and lead sorption onto chemically modified sugarcane bagasse and wheat straw. Environ Monit Assess 187:1–11CrossRef

Mohan D, Pittman CU, Steele PH (2006) Single, binary and multi-component adsorption of copper and cadmium from aqueous solutions on kraft lignin—a biosorbent. J Colloid Interface Sci 297:489–504CrossRef

Musyoka SM, Ngila JC, Moodley B, Petrik L, Kindness A (2011) Synthesis, characterization, and adsorption kinetic studies of ethylenediamine modified cellulose for removal of Cd and Pb. Anal Lett 44:1925–1936CrossRef

Nagarjuna R, Challagulla S, Alla N, Ganesan R, Roy S (2015) Synthesis and characterization of reduced-graphene oxide/tio 2/zeolite-4a: a bifunctional nanocomposite for abatement of methylene blue. Mater Des 86:621–626CrossRef

Nowicki P, Kazmierczak-Razna J, Pietrzak R (2016) Physicochemical and adsorption properties of carbonaceous sorbents prepared by activation of tropical fruit skins with potassium carbonate. Mater Des 90:579–585CrossRef

Oliva J, De PJ, Cortina JL, Cama J, Ayora C (2011) Removal of cadmium, copper, nickel, cobalt and mercury from water by apatite II™: column experiments. J Hazard Mater 194:312–323CrossRef

Peng S, Meng H, Ouyang Y, Chang J (2014a) Nanoporous magnetic cellulose–chitosan composite microspheres: preparation, characterization, and application for Cu(II) adsorption. Ind Eng Chem Res 53:2106–2113CrossRef

Peng S, Meng HC, Zhou L, Chang J (2014b) Synthesis of novel magnetic cellulose–chitosan composite microspheres and their application in laccase immobilization. J Nanosci Nanotechnol 14:7010–7014CrossRef

Peng X, Cai Y, Li M, Zhu X, Zou H (2016) Synthesis and application of ramie fiber soft modifier comprised of carboxylate-containing polymer. Fiber Polym 17:533–539CrossRef

Peng S, Liu Y, Xue Z, Yin W, Liang X, Li M, Chang J (2017a) Modified nanoporous magnetic cellulose–chitosan microspheres for efficient removal of Pb(II) and methylene blue from aqueous solution. Cellulose 24:4793–4806CrossRef

Peng X, Lou K, Zhang Y, Li M, Wen S, Cai Y (2017b) Ammonified modification and dyeing of ramie fabric in liquid ammonia. Dyes Pigments 138:154–161CrossRef

Proniewicz LM, Paluszkiewicz C, Wesełucha-Birczyńska A, Majcherczyk H, Barański A, Konieczna A (2001) FT-IR and FT-Raman study of hydrothermally degradated cellulose. J Mol Struct 596:163–169CrossRef

Pu S, Ma H, Zinchenko A, Chu W (2017a) Novel highly porous magnetic hydrogel beads composed of chitosan and sodium citrate: an effective adsorbent for the removal of heavy metals from aqueous solutions. Environ Sci Pollut Res 24:16520–16530CrossRef

Pu S, Xiang C, Zhu R, Ma H, Zinchenko A, Chu W (2017b) An efficient heterogeneous fenton catalyst based on modified diatomite for degradation of cationic dye simulated wastewater. Desalin Water Treat 79:378–385CrossRef

Sekar M, Sakthi V, Rengaraj S (2004) Kinetics and equilibrium adsorption study of lead(II) onto activated carbon prepared from coconut shell. J Colloid Interface Sci 279:307–313CrossRef

Shawky HA, El-Aassar AHM, Abo-Zeid DE (2012) Chitosan/carbon nanotube composite beads: preparation, characterization, and cost evaluation for mercury removal from wastewater of some industrial cities in egypt. J Appl Polym Sci 125:E93–E101CrossRef

Siswoyo E, Mihara Y, Tanaka S (2014) Determination of key components and adsorption capacity of a low cost adsorbent based on sludge of drinking water treatment plant to adsorb cadmium ion in water. Appl Clay Sci 97–98:146–152CrossRef

Sun Z, Liu Y, Huang Y, Tan X, Zeng G, Hu X, Yang Z (2014) Fast adsorption of Cd²⁺ and Pb²⁺ by EGTA dianhydride (EGTAD) modified ramie fiber. J Colloid Interface Sci 434:152–158CrossRef

Wang P, Cao M, Wang C, Ao Y, Hou J, Jin Q (2014) Kinetics and thermodynamics of adsorption of methylene blue by a magnetic graphene–carbon nanotube composite. Appl Surf Sci 290:116–124CrossRef

Wang GW, Chen B, Zhuang LH, Yun K, Guo JR, Wang Y, Xu B (2015) Dyeing performances of ramie fabrics modified with an amino-terminated aliphatic hyperbranched polymer. Cellulose 22:1401–1414CrossRef

Yamamoto T, Endo A, Ohmori T, Nakaiwa M (2004) Porous properties of carbon gel microspheres as adsorbents for gas separation. Carbon 42:1671–1676CrossRef

Yao T, Guo S, Zeng C, Wang C, Zhang L (2015) Investigation on efficient adsorption of cationic dyes on porous magnetic polyacrylamide microspheres. J Hazard Mater 292:90–97CrossRef

Zhang F, Wu W, Zhang X, Meng X, Tong G, Deng Y (2016) Temperature-sensitive poly-nipam modified cellulose nanofibril cryogel microspheres for controlled drug release. Cellulose 23:415–425CrossRef

Zhang C, Zhai T, Turng LS (2017) Aerogel microspheres based on cellulose nanofibrils as potential cell culture scaffolds. Cellulose 24:2791–2799CrossRef

Zhao L, Yan H, Fang Z, Wang J, Wang H (2015) On the flameproof treatment of ramie fabrics using a spray-assisted layer-by-layer technique. Polym Degrad Stab 121:11–17CrossRef

Zhou Z, Liu X, Hu B, Wang J, Xin D, Wang Z, Qiu Y (2011) Hydrophobic surface modification of ramie fibers with ethanol pretreatment and atmospheric pressure plasma treatment. Surf Coat Technol 205:4205–4210CrossRef

Zhou G, Liu C, Tang Y, Luo S, Zeng Z, Liu Y, Xu R, Chu L (2015) Sponge-like polysiloxane-graphene oxide gel as a highly efficient and renewable adsorbent for lead and cadmium metals removal from wastewater. Chem Eng J 280:275–282CrossRef

Zhu G, Zhu X, Xiao Z, Yi F (2012) Study of cellulose pyrolysis using an in situ visualization technique and thermogravimetric analyzer. J Anal Appl Pyrolysis 94:126–130CrossRef

Titel: Fabrication of carboxymethyl-functionalized porous ramie microspheres as effective adsorbents for the removal of cadmium ions
verfasst von: Xiongyi Peng
Siwei Su
Minggui Xia
Kankan Lou
Feng Yang
Shuai Peng
Yingjie Cai
Publikationsdatum: 18.01.2018
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 3/2018
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-018-1656-z

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Springer Professional "Wirtschaft+Technik"

Weitere Artikel der Ausgabe 3/2018

Calcium alginate beads reinforced with synthetic oligomers, linear polyethylenimine and Cu(II): structural stability and potential applications

Correction to: Carbon/ZnO nanorods composites templated by TEMPO-oxidized cellulose and photocatalytic activity for dye degradation

Functionalization of cellulose fiber by in situ growth of zeolitic imidazolate framework-8 (ZIF-8) nanocrystals for preparing a cellulose-based air filter with gas adsorption ability

Activated carbon derived from chitin aerogels: preparation and CO2 adsorption

Preparation of a sustainable bioadsorbent by modifying filter paper with sodium alginate, with enhanced mechanical properties and good adsorption of methylene blue from wastewaters

Cellulose films from the aqueous DMSO/TBAH-system