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01.05.2020 | Original Research

Water accessibility to hydroxyls confined in solid wood cell walls

verfasst von: Emil Engelund Thybring, Sara Piqueras, Asghar Tarmian, Ingo Burgert

Erschienen in: Cellulose | Ausgabe 10/2020

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Abstract

The hydrophilicity of wood cell walls derives from the presence of hydroxyls, but their accessibility is restricted by physical confinement from the stiff, solid cell walls. This study examines how this confinement affects water uptake of the accessible hydroxyls by tuning their amount through replacement with various non-hydrophilic functional groups. Results from gravimetrically determined hydroxyl accessibility by deuterium exchange are shown not to correlate with moisture uptake in cell walls under vapour conditions or at water-saturation. Instead, spatial availability for water inside solid cell walls is suggested as the dominant factor in controlling cell wall moisture uptake at given climatic conditions.

Vorheriger Artikel In silico structure prediction of full-length cotton cellulose synthase protein (GhCESA1) and its hierarchical complexes

Nächster Artikel BcsAB synthesized cellulose on nickel surface: polymerization of monolignols during cellulose synthesis alters cellulose morphology

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Titel: Water accessibility to hydroxyls confined in solid wood cell walls
verfasst von: Emil Engelund Thybring
Sara Piqueras
Asghar Tarmian
Ingo Burgert
Publikationsdatum: 01.05.2020
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 10/2020
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-020-03182-x

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