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Journal of Materials Science
Erschienen in: Journal of Materials Science 19/2018

30.04.2018 | Mechanochemical Synthesis

BaF-benzenedicarboxylate: the first mechanochemical synthesis of a new coordination polymer with a direct Ba–F bond

verfasst von: S. Breitfeld, G. Scholz, F. Emmerling, E. Kemnitz

Erschienen in: Journal of Materials Science | Ausgabe 19/2018

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Abstract

A new barium coordination polymer, BaF-benzenedicarboxylate (BaF(p-BDC)0.5), with fluorine directly coordinated to the metal cation, was prepared by mechanochemical synthesis routes. Phase-pure BaF-benzenedicarboxylate was synthesized by milling starting either from barium hydroxide or from barium acetate as sources for barium cations. In both cases, the second reactant was 1,4-benzenedicarboxylic acid (H2(p-BDC)). Ammonium fluoride was used as fluorinating agent directly at milling. This is the first mechanochemical synthesis of coordination polymers where fluorine is directly coordinated to the metal cation. Following the second possibility, barium acetate fluoride (Ba(OAc)F) is formed as intermediate product after milling, and the new coordination polymer is accessible only after washing with water and dimethyl sulfoxide. The new compound BaF(p-BDC)0.5 was characterized by X-ray powder diffraction, FTIR-, and 19F, 1H-13C CP MAS NMR spectroscopies, DTA-TG, and elemental analysis.
Vorheriger Artikel F anion dynamics in cation-mixed nanocrystalline LaF3: SrF2
Nächster Artikel Effect of process parameters on mechanochemical nitration of toluene

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Literatur
1.
Yang C, Wang X, Omary MA (2007) Fluorous metal–organic frameworks for high-density gas adsorption. J Am Chem Soc 129(50):15454–15455CrossRef
2.
Yang C, Wang X, Omary MA (2009) Crystallographic observation of dynamic gas adsorption sites and thermal expansion in a breathable fluorous metal–organic framework. Angew Chem Int Ed 48(14):2500–2505CrossRef
3.
Abdi I, Lhoste J, Leblanc M, Maisonneuve V, Grenèche J-M, Viau G, Ali AB (2015) [H2 amtaz]+ iron fluorides: synthesis, crystal structures, magnetic and Mössbauer studies. J Fluor Chem 173:23–28CrossRef
4.
Adil K, Le Bail A, Leblanc M, Maisonneuve V (2010) Novel layered hybrid fluoroaluminate in the composition space diagram of the Al (OH)3-HguaCl-HFaq-EtOH system. Inorg Chem 49(5):2392–2397CrossRef
5.
Cadiau A, Martineau C, Leblanc M, Maisonneuve V, Hémon-Ribaud A, Taulelle F, Adil K (2011) ZnAlF5 [TAZ]: an Al fluorinated MOF of MIL-53 (Al) topology with cationic Zn (1, 2, 4 triazole)2+ linkers. J Mater Chem 21(11):3949–3951CrossRef
6.
Lhoste J, Body M, Legein C, Ribaud A, Leblanc M, Maisonneuve V (2014) F−/OH− substitution in [H4 tren]4+ and [H3 tren]3+ hydroxyfluorotitanates (IV) and classification of tren cation configurations. J Solid State Chem 217:72–79CrossRef
7.
Pimenta V, Le QHH, Clark L, Lhoste J, Hémon-Ribaud A, Leblanc M, Grenèche J-M, Dujardin G, Lightfoot P, Maisonneuve V (2015) New iron tetrazolate frameworks: synthesis, temperature effect, thermal behaviour, Mössbauer and magnetic studies. Dalton Trans 44(17):7951–7959CrossRef
8.
Pimenta V, Le QHH, Hemon-Ribaud A, Leblanc M, Maisonneuve V, Lhoste J (2016) Effect of the synthesis temperature on the dimensionality of hybrid fluorozincates. J Fluor Chem 188:164–170CrossRef
9.
Pimenta V, Lhoste J, Hémon-Ribaud A, Leblanc M, Grenèche J-M, Jouffret L, Martel A, Dujardin G, Maisonneuve V (2015) Evidence of new fluorinated coordination compounds in the composition space diagram of FeF3/ZnF2-Hamtetraz-HFaq system. Cryst Growth Des 15(9):4248–4255CrossRef
10.
Smida M, Lhoste J, Pimenta V, Hémon-Ribaud A, Jouffret L, Leblanc M, Dammak M, Grenèche JM, Maisonneuve V (2013) New series of hybrid fluoroferrates synthesized with triazoles: various dimensionalities and Mössbauer studies. Dalton Trans 42(44):15748–15755CrossRef
11.
Goforth AM, Su C-Y, Hipp R, Macquart RB, Smith MD, zur Loye HC (2005) Connecting small ligands to generate large tubular metal–organic architectures. J Solid State Chem 178(8):2511–2518CrossRef
12.
Su C-Y, Goforth AM, Smith MD, Pellechia P, zur Loye HC (2004) Exceptionally stable, hollow tubular metal–organic architectures: synthesis, characterization, and solid-state transformation study. J Am Chem Soc 126(11):3576–3586CrossRef
13.
Aguado S, Aquino C, Martineau C, Ryabchikov YV, Lysenko V, Quadrelli EA, Canivet J, Farrusseng D (2013) Design of microporous mixed zinc–nickel triazolate metal–organic frameworks with functional ligands. Cryst Eng Commun 15(45):9336–9339CrossRef
14.
Liu L, Wang X, Jacobson AJ (2010) AlF 1,4-benzenedicarboxylate: synthesis and absorption properties. Dalton Trans 39(7):1722–1725CrossRef
15.
Boutin A, Bousquet D, AlU Ortiz, Fo-X Coudert, Fuchs AH, Ballandras A, Weber G, Bezverkhyy I, Bellat J-P, Ortiz G (2013) Temperature-induced structural transitions in the gallium-based MIL-53 metal–organic framework. J Phys Chem C 117(16):8180–8188CrossRef
16.
Huang Z-L, Wang L-P, Mou C-X, Li J-Z (2014) Magnesium terephthalate as an organic anode material for Sodium ion batteries. Acta Phys Chim Sin 30(10):1787–1793
17.
Wang L, Mou C, Sun Y, Liu W, Deng Q, Li J (2015) Structure-property of metal organic frameworks calcium terephthalates anodes for lithium-ion batteries. Electrochim Acta 173:235–241CrossRef
18.
Wang L, Mou C, Wu B, Xue J, Li J (2016) Alkaline earth metal terephthalates MC8H4O4 (M = Ca, Sr, Ba) as anodes for lithium ion batteries. Electrochim Acta 196:118–124CrossRef
19.
He S, Zhou X, Li Z, Wang J, Ma L, Yang S (2017) Fluorine doping strengthens the lithium-storage properties of the Mn-based metal–organic framework. ACS Appl Mater Interfaces 9(32):26907–26914CrossRef
20.
Al-Terkawi A-A, Scholz G, Buzanich AG, Reinsch S, Emmerling F, Kemnitz E (2017) Ca-and Srtetrafluoroisophthalates: mechanochemical synthesis, characterization, and ab initio structure determination. Dalton Trans 46(18):6003–6012CrossRef
21.
Al-Terkawi A-A, Scholz G, Emmerling F, Kemnitz E (2016) Mechanochemical synthesis, characterization, and structure determination of new alkaline earth metal-tetrafluoroterephthalate frameworks: Ca(pBDC-F4) 4H2O, Sr (pBDC-F4) 4H2O, and Ba(pBDC-F4). Cryst Growth Des 16(4):1923–1933CrossRef
22.
Scholz G, Abdulkader A, Kemnitz E (2014) Mechanochemical synthesis and characterization of alkaline earth metal terephthalates: M(C8H4O4) nH2O (M = Ca, Sr, Ba). Z Anorg Allg Chem 640(2):317–324CrossRef
23.
Scholz G, Emmerling F, Dreger M, Kemnitz E (2013) Mechanochemical synthesis and characterization of hydrated and dehydrated crystalline strontium terephtalates. Z Anorg Allg Chem 639(5):689–693CrossRef
24.
Dreger M, Scholz G, Kemnitz E (2012) An easy access to nanocrystalline alkaline earth metal fluorides-just by shaking. Solid State Sci 14(4):528–534CrossRef
25.
Scholz G, Meyer K, Düvel A, Heitjans P, Kemnitz E (2013) Fast ion conducting nanocrystalline alkaline earth fluorides simply prepared by mixing or manual shaking. Z Anorg Allg Chem 639(6):960–966CrossRef
26.
Cory DG, Ritchey WM (1988) Suppression of signals from the probe the in Bloch decay spectra. J Magn Res 80:128–132
27.
JCPDS-ICDD, International Centre for Diffraction Data: PDF-2 database (sets 1–51 plus 70–89), PA 19073–3273 U. S. A., Release 2001-PCPDFWIN Version 2.2
28.
Willmott P, Meister D, Leake S, Lange M, Bergamaschi A, Böge M, Calvi M, Cancellieri C, Casati N, Cervellino A (2013) The materials science beamline upgrade at the Swiss Light Source. J Synchrotron Radiat 20(5):667–682CrossRef
29.
Scholz G, Stosiek C, Noack J, Kemnitz E (2011) Local fluorine environments in nanoscopic magnesium hydr (oxide) fluorides studied by 19 F MAS NMR. J Fluor Chem 132(12):1079–1085CrossRef
30.
Hollauer E, Mondragon M, Castaño VM (2001) Fourier transform infrared and Raman spectra, vibrational assignment and ab initio calculations of terephthalic acid and related compounds. Spectrochim. Acta Part A: molecular and Biomolecular. Spectroscopy 57(5):993–1007
31.
Panasyuk G, Azarova L, Budova G, Izotov A (2002) Synthesis and characterization of ammonium terephthalates. Inorg Mater 38(4):385–389CrossRef
Metadaten
Titel
BaF-benzenedicarboxylate: the first mechanochemical synthesis of a new coordination polymer with a direct Ba–F bond
verfasst von
S. Breitfeld
G. Scholz
F. Emmerling
E. Kemnitz
Publikationsdatum
30.04.2018
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 19/2018
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-018-2331-3

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