nach oben

Journal of Materials Science

Erschienen in:

01.02.2021 | Energy materials

Porous spinel-type (Al_0.2CoCrFeMnNi)_0.58O_4-δ high-entropy oxide as a novel high-performance anode material for lithium-ion batteries

verfasst von: Hou-Zheng Xiang, Hong-Xiang Xie, Yu-Xue Chen, Hui Zhang, Aiqin Mao, Cui-Hong Zheng

Erschienen in: Journal of Materials Science | Ausgabe 13/2021

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

Owing to their entropy stabilization and multi-principal effect, transition-metal-based high-entropy oxides are attracting extensive attention as an effective family of anode materials for lithium ion batteries (LIBs). Herein, spinel-type (Al_0.2CoCrFeMnNi)_0.58O_4-δ HEO nanocrystalline powder with high concentration of oxygen vacancies is successfully prepared by the method of solution combustion synthesis (SCS), and explored as a novel anode active material for LIBs. As compared to (CoCrFeMnNi)_0.6O_4-δ, the inactive Al³⁺-doped (Al_0.2CoCrFeMnNi)_0.58O_4-δ anode provides more than twice the reversible specific capacity of 554 mAh g⁻¹ after 500 cycles at a specific current of 200 mA g⁻¹, accompanied with good rate capability (634 mAh g⁻¹ even at 3 A g⁻¹) and cycling performance. The enhanced electrochemical properties can be attributed to that inactive Al³⁺-doping resulted into the more space for Li⁺ intercalation and deintercalation, enhanced structural stability, and the improved electronic conductivity and Li⁺ diffusivity.

Graphical abstract

Vorheriger Artikel Fast and facile synthesis of carbonate-modified NiFe layered double hydroxide nanosheets by dielectric barrier discharge microplasma: mechanism and application in enhanced water oxidation

Nächster Artikel Nanostructured tubular carbon materials doped with cobalt as electrocatalyst for efficient oxygen reduction reaction

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Nur mit Berechtigung zugänglich

Zhou L, Zhang K, Hu Z et al (2018) Recent developments on and prospects for electrode materials with hierarchical structures for lithium-ion batteries. Adv Energy Mater 8:1701415CrossRef

Nitta N, Wu F, Lee JT et al (2015) Li-ion battery materials: present and future. Mater Today 18:252–264CrossRef

Gao Y, Yin L, Kim SJ et al (2019) Enhanced lithium storage by ZnFe₂O₄ nanofibers as anode materials for lithium-ion battery. Electrochim Acta 296:565–574CrossRef

Xu S, Hessel CM, Ren H et al (2014) α-Fe₂O₃ multi-shelled hollow microspheres for lithium ion battery anodes with superior capacity and charge retention. Energy Environ Sci 7:632–637CrossRef

Poizot P, Laruelle S, Grugeon S et al (2000) Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries. Nature 407:496–499CrossRef

Wang W, Ai T, Li W et al (2017) Photoelectric and electrochemical performance of Al-doped ZnO Thin films hydrothermally grown on graphene-coated polyethylene terephthalate bilayer flexible substrates. J Phys Chem C 121:28148–28157CrossRef

Han X, Cui Y, Liu H (2020) Ce-doped Mn₃O₄ as high-performance anode material for lithium ion batteries. J Alloys Compd 814:152348CrossRef

Ma Y, Fang C, Ding B et al (2013) Fe-doped Mn_xO_y with hierarchical porosity as a high-performance lithium-ion battery anode. Adv Mater 25:4646–4652CrossRef

Woo SW, Myung ST, Bang H et al (2009) Improvement of electrochemical and thermal properties of Li[Ni_0.8Co_0.1Mn_0.1]O₂ positive electrode materials by multiple metal (Al, Mg) substitution. Electrochim Acta 54:3851–3856CrossRef

10.

Huang B, Li X, Wang Z et al (2014) Synthesis of Mg-doped LiNi_0.8Co_0.15Al_0.05O₂ oxide and its electrochemical behavior in high-voltage lithium-ion batteries. Ceram Int 40:13223–13230CrossRef

11.

Wang D, Zhou W, Zhang R et al (2018) MOF-derived Zn–Mn mixed oxides@carbon hollow disks with robust hierarchical structure for high-performance lithium-ion batteries. J Mater Chem A 6:2974–2983CrossRef

12.

Liu H, Zheng H, Li L et al (2018) Surface-coating-mediated electrochemical performance in CuO nanowires during the sodiation-desodiation cycling. Adv Mater Interf 5:1701255CrossRef

13.

Sarkar A, Velasco L, Wang D et al (2018) High entropy oxides for reversible energy storage. Nat Commun 9:3400CrossRef

14.

Qiu N, Chen H, Yang Z et al (2019) A high entropy oxide (Mg_0.2Co_0.2Ni_0.2Cu_0.2Zn_0.2O) with superior lithium storage performance. J Alloys Compd 777:767–774CrossRef

15.

Chen H, Qiu N, Wu B et al (2019) Tunable pseudocapacitive contribution by dimension control in nanocrystalline-constructed (Mg_0.2Co_0.2Ni_0.2Cu_0.2Zn_0.2)O solid solutions to achieve superior lithium-storage properties. RSC Adv 9:28908–28915CrossRef

16.

Sarkar A, Wang Q, Schiele A et al (2019) High-entropy oxides: fundamental aspects and electrochemical properties. Adv Mater 31:1806236CrossRef

17.

Wang Q, Sarkar A, Li Z et al (2019) High entropy oxides as anode material for Li-ion battery applications: A practical approach. Electrochem Commun 100:121–125CrossRef

18.

Chen H, Qiu N, Wu B et al (2020) A new spinel high-entropy oxide (Mg_0.2Ti_0.2Zn_0.2Cu_0.2Fe_0.2)₃O₄ with fast reaction kinetics and excellent stability as an anode material for lithium ion batteries. RSC Adv 10:9736–9744CrossRef

19.

Bérardan D, Franger S, Meena AK et al (2016) Room temperature lithium superionic conductivity in high entropy oxides. J Mater Chem A 4:9536–9541CrossRef

20.

Wang D, Jiang S, Duan C et al (2020) Spinel-structured high entropy oxide (FeCoNiCrMn)₃O₄ as anode towards superior lithium storage performance. J Alloys Compd 844:156158CrossRef

21.

Mao A, Quan F, Xiang H-Z et al (2019) Facile synthesis and ferrimagnetic property of spinel (CoCrFeMnNi)₃O₄ high-entropy oxide nanocrystalline powder. J Mol Struct 1194:11–18CrossRef

22.

Xiang H-Z, Xie H-X, Mao A et al (2020) Facile preparation of single phase high-entropy oxide nanocrystalline powders by solution combustion synthesis. Int J Mater Res 111:246–249CrossRef

23.

Mao A, Xiang H-Z, Zhang Z-G et al (2020) A new class of spinel high-entropy oxides with controllable magnetic properties. J Magn Magn Mater 497:165884CrossRef

24.

Xiang H, Xie H, W LI, et al (2020) Synthesis and electrochemical performance investigation of spinel-type high-entropy oxides. Chem J Chin U 41:1801–1809

25.

Mao A, Xie H-X, Xiang H-Z et al (2020) A novel six-component spinel-structure high-entropy oxide with ferrimagnetic property. J Magn Magn Mater 503:166594CrossRef

26.

Dąbrowa J, Stygar M, Mikuła A et al (2018) Synthesis and microstructure of the (Co, Cr, Fe, Mn, Ni)3O4 high entropy oxide characterized by spinel structure. Mater Lett 216:32–36CrossRef

27.

Wang H, Gao R, Li Z et al (2018) Different effects of Al substitution for Mn or Fe on the structure and electrochemical properties of Na_0.67Mn_0.5Fe_0.5O₂ as a sodium ion battery cathode material. Inorg Chem 57:5249–5257CrossRef

28.

Mo M, Hui KS, Hong X et al (2014) Improved cycling and rate performance of Sm-doped LiNi_0.5Mn_1.5O₄ cathode materials for 5V lithium ion batteries. Appl Surf Sci 290:412–418CrossRef

29.

Xiang M, Su C-W, Feng L et al (2014) Rapid synthesis of high-cycling performance LiMg_xMn_2–xO₄ (x ≤ 0.20) cathode materials by a low-temperature solid-state combustion method. Electrochim Acta 125:524–529CrossRef

30.

Manikandan A, Durka M, Seevakan K et al (2015) A novel one-pot combustion synthesis and opto-magnetic properties of magnetically separable spinel Mn_xMg_1−xFe₂O₄ (0.0≤x≤0.5) nanophotocatalysts. J Supercond Nov Magn 28:1405–1416CrossRef

31.

Ashok A, Kumar A, Bhosale RR et al (2018) Combustion synthesis of bifunctional LaMO3 (M=Cr, Mn, Fe Co, Ni) perovskites for oxygen reduction and oxygen evolution reaction in alkaline media. J Electroanal Chem 809:22–30CrossRef

32.

Khort A, Podbolotov K, Serrano García R et al (2018) One-step solution combustion synthesis of cobalt nanopowder in air atmosphere: the fuel effect. Inorg Chem 57:1464–1473CrossRef

33.

Lin J-Y, Hsu C-C, Ho H-P et al (2013) Sol–gel synthesis of aluminum doped lithium titanate anode material for lithium ion batteries. Electrochim Acta 87:126–132CrossRef

34.

Sanchez JS, Pendashteh A, Palma J et al (2018) Porous NiCoMn ternary metal oxide/graphene nanocomposites for high performance hybrid energy storage devices. Electrochim Acta 279:44–56CrossRef

35.

Biesinger MC, Payne BP, Grosvenor AP et al (2011) Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Cr, Mn, Fe, Co and Ni. Appl Surf Sci 257:2717–2730CrossRef

36.

Zhu YM, Zhang L, Zhao BT et al (2019) Improving the activity for oxygen evolution reaction by tailoring oxygen defects in double perovskite oxides. Adv Funct Mater 29:1901783

37.

Fang D-l, Wang Z-b, Yang P-h et al (2006) Preparation of ultra-fine nickel manganite powders and ceramics by a solid-state coordination reaction. J Am Ceram Soc 89:230–235CrossRef

38.

Phan TN, Gong MK, Thangavel R et al (2019) Enhanced electrochemical performance for EDLC using ordered mesoporous carbons (CMK-3 and CMK-8): Role of mesopores and mesopore structures. J Alloys Compd 780:90–97CrossRef

39.

Zou F, Hu X, Li Z et al (2014) MOF-derived porous ZnO/ZnFe₂O₄/C octahedra with hollow interiors for high-rate lithium-ion batteries. Adv Mater 26:6622–6628CrossRef

40.

Fang D-L, Zhao Y-C, Wang S-S et al (2020) Highly efficient synthesis of nano-Si anode material for Li-ion batteries by a ball-milling assisted low-temperature aluminothermic reduction. Electrochim Acta 330:135346CrossRef

41.

Lu C-H, Lin S-W (2001) Influence of the particle size on the electrochemical properties of lithium manganese oxide. J Power Sour 97–98:458–460CrossRef

42.

Maleski K, Ren CE, Zhao M-Q et al (2018) Size-dependent physical and electrochemical properties of two-dimensional mxene flakes. ACS Appl Mater Inter 10:24491–24498CrossRef

43.

Hu S, Wang C, Zhou L et al (2018) Hydrothermal-assisted synthesis of surface aluminum-doped LiCoO₂ nanobricks for high-rate lithium-ion batteries. Ceram Int 44:14995–15000CrossRef

44.

Bao S-J, Liang Y-Y, Zhou W-J et al (2006) Synthesis and electrochemical properties of LiAl_0.1Mn_1.9O₄ by microwave-assisted sol–gel method. J Power Sour 154:239–245CrossRef

45.

Li Y-C, Xiang W, Wu Z-G et al (2018) Construction of homogeneously Al³⁺ doped Ni rich Ni-Co-Mn cathode with high stable cycling performance and storage stability via scalable continuous precipitation. Electrochim Acta 291:84–94CrossRef

46.

Cao K, Jin T, Yang L et al (2017) Recent progress in conversion reaction metal oxide anodes for Li-ion batteries. Mater Chem Front 1:2213–2242CrossRef

47.

Nguyen TX, Patra J, Chang J-K et al (2020) High entropy spinel oxide nanoparticles for superior lithiation–delithiation performance. J Mater Chem A 8:18963–18973CrossRef

48.

Li C, Li G, Guan X (2018) Synthesis and electrochemical performance of micro-nano structured LiFe_1−xMnxPO₄/C (0 ≤x ≤ 0.05) cathode for lithium-ion batteries. J Energy Chem 27:923–929CrossRef

Titel: Porous spinel-type (Al0.2CoCrFeMnNi)0.58O4-δ high-entropy oxide as a novel high-performance anode material for lithium-ion batteries
verfasst von: Hou-Zheng Xiang
Hong-Xiang Xie
Yu-Xue Chen
Hui Zhang
Aiqin Mao
Cui-Hong Zheng
Publikationsdatum: 01.02.2021
Verlag: Springer US
Erschienen in: Journal of Materials Science / Ausgabe 13/2021
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-021-05805-5

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Graphical abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 13/2021

Fabrication of reduced graphene oxide/manganese oxide ink for 3D-printing technology on the application of high-performance supercapacitors

Synthesis, characterization and catalytic performance of magnetic La0.7Sr0.3MnO3/α-Fe2O3 with p–n heterojunction structure

Wettability and reactivity between molten aluminum and randomly aligned carbon nanotubes

Bi-component MOF-derived high-sensitive triethylamine gas sensors based on MoO3/ZnMoO4/CoMoO4 hierarchical structures effectuated by tunable surface/interface transfer behavior

Preface to the special section on high-temperature capillarity

Electron irradiation effects on Ag nanoparticles

Premium Partner

Marktübersichten