Skip to main content
Erschienen in: Rare Metals 4/2020

27.04.2019

Low-cost Sm0.7Y0.3Co5 sintered magnet produced by traditional powder metallurgical techniques

verfasst von: Dong-Tao Zhang, Nai-Xing Cai, Rong-Chun Zhu, Wei-Qiang Liu, Ming Yue

Erschienen in: Rare Metals | Ausgabe 4/2020

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

RCo5 (R = rare earth) sintered magnets have good temperature stability, so it is still widely used in high temperature field. In this paper, by the method of adding liquid phase SmCo1.7 to the main phase, Sm0.7Y0.3Co5 magnet was prepared by traditional powder metallurgical process. The results show the presence of a main phase RCo5, a minor phase R2Co7, and a R-rich phase in the magnet. Contrasting the results of the XRD (X-ray diffraction) in random and oriented directions, the magnet has a well-aligned (00l) orientated texture, which is consistent with the result of the electron backscattered diffraction (EBSD). The Sm0.7Y0.3Co5 sintered magnet has good magnetic properties as remanence (Br) is 0.96 T, the coercivity (Hcj) is 1201.96 kA·m−1, and maximum magnetic energy product ((BH)max) is 175.16 kJ·m−3.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
[1]
Zurück zum Zitat Landa A, Söderlind P, Parker D, Åberg D, Lordi V, Perron A, Turchi PEA, Chouhan RK, Paudyal D, Lograsso TA. Thermodynamics of the SmCo5 compound doped with Fe and Ni: an ab initio study. J Alloys Compd. 2018;765:659.CrossRef Landa A, Söderlind P, Parker D, Åberg D, Lordi V, Perron A, Turchi PEA, Chouhan RK, Paudyal D, Lograsso TA. Thermodynamics of the SmCo5 compound doped with Fe and Ni: an ab initio study. J Alloys Compd. 2018;765:659.CrossRef
[2]
Zurück zum Zitat Zhang DT, Yuan X, Yue M, Zhou DS, Zhu J, Gao X. Crystallographic orientation dependent magnetic properties of a PrCo5 permanent magnet prepared by hot deformation. CrystEngComm. 2016;18(15):2632.CrossRef Zhang DT, Yuan X, Yue M, Zhou DS, Zhu J, Gao X. Crystallographic orientation dependent magnetic properties of a PrCo5 permanent magnet prepared by hot deformation. CrystEngComm. 2016;18(15):2632.CrossRef
[3]
Zurück zum Zitat Xue ZQ, Guo YQ. Correlation between valence electronic structure and magnetic properties in RCo5 (R = rare earth) intermetallic compound. Chin Phys B. 2016;25(6):165.CrossRef Xue ZQ, Guo YQ. Correlation between valence electronic structure and magnetic properties in RCo5 (R = rare earth) intermetallic compound. Chin Phys B. 2016;25(6):165.CrossRef
[4]
Zurück zum Zitat Thantirige RM, Pradhan NR, Tuominen MT. The effect of microstructure in exchange decoupling of SmCo5/Co bi-layers at low temperatures. J Appl Phys. 2016;8(6):26. Thantirige RM, Pradhan NR, Tuominen MT. The effect of microstructure in exchange decoupling of SmCo5/Co bi-layers at low temperatures. J Appl Phys. 2016;8(6):26.
[5]
Zurück zum Zitat Zhang JJ, Gao HM, Yan Y, Bai X, Wang WQ, Su F, Du XB. Processing YCo5 permanent magnetic submicron flakes by surfactant-assisted high-energy ball milling. Chin Phys Lett. 2012;29(5):57501.CrossRef Zhang JJ, Gao HM, Yan Y, Bai X, Wang WQ, Su F, Du XB. Processing YCo5 permanent magnetic submicron flakes by surfactant-assisted high-energy ball milling. Chin Phys Lett. 2012;29(5):57501.CrossRef
[6]
Zurück zum Zitat Hoffer G, Strnat K. Magnetocrystalline anisotropy of YCo5 and Y2Co17. IEEE Trans Magn. 2003;2(3):487.CrossRef Hoffer G, Strnat K. Magnetocrystalline anisotropy of YCo5 and Y2Co17. IEEE Trans Magn. 2003;2(3):487.CrossRef
[7]
Zurück zum Zitat Zhu K, Hou YL. Controllable synthesis of rare-earth based permanent magnetic nanomaterials and their magnetic properties. Chin J Rare Metals. 2017;41(5):466. Zhu K, Hou YL. Controllable synthesis of rare-earth based permanent magnetic nanomaterials and their magnetic properties. Chin J Rare Metals. 2017;41(5):466.
[8]
Zurück zum Zitat Zana I, Zangari G. Magnetic interaction and thermal stability in CoSm thin films. IEEE Trans Magn. 2000;36(5):2345.CrossRef Zana I, Zangari G. Magnetic interaction and thermal stability in CoSm thin films. IEEE Trans Magn. 2000;36(5):2345.CrossRef
[9]
Zurück zum Zitat Saravanan P, Gopalan R, Rao NVR, Raja MM, Chandrasekaran V. SmCo5/Fe nanocomposite magnetic powders processed by magnetic field-assisted ball milling with and without surfactant. J Appl Phys. 2007;40(17):5021. Saravanan P, Gopalan R, Rao NVR, Raja MM, Chandrasekaran V. SmCo5/Fe nanocomposite magnetic powders processed by magnetic field-assisted ball milling with and without surfactant. J Appl Phys. 2007;40(17):5021.
[10]
Zurück zum Zitat Ma ZH, Zhang TL, Wang H, Jiang CB. Synthesis of SmCo5 nanoparticles with small size and high performance by hydrogenation technique. Rare Met. 2018;37(12):1021.CrossRef Ma ZH, Zhang TL, Wang H, Jiang CB. Synthesis of SmCo5 nanoparticles with small size and high performance by hydrogenation technique. Rare Met. 2018;37(12):1021.CrossRef
[11]
Zurück zum Zitat Zuo JH, Yue M, Lu QM, Zhang DT, Gao XX, Zhang JX, Guo ZH, Li W. Structure, magnetic properties, and thermal stability of Sm1−xTmxCo5 compounds. Rare Met. 2014;33(2):176.CrossRef Zuo JH, Yue M, Lu QM, Zhang DT, Gao XX, Zhang JX, Guo ZH, Li W. Structure, magnetic properties, and thermal stability of Sm1−xTmxCo5 compounds. Rare Met. 2014;33(2):176.CrossRef
[12]
Zurück zum Zitat Larson P, Mazin II, Papaconstantopoulos DA. Calculation of magnetic anisotropy energy in YCo5. Phys Rev B. 2003;67(21):6888.CrossRef Larson P, Mazin II, Papaconstantopoulos DA. Calculation of magnetic anisotropy energy in YCo5. Phys Rev B. 2003;67(21):6888.CrossRef
[13]
Zurück zum Zitat Velu EMT, Obermyer RT, Sankar SG, Wallace WE. PrCo5-based high-energy-density permanent magnets. J Less Common Metals. 1989;148(1):67.CrossRef Velu EMT, Obermyer RT, Sankar SG, Wallace WE. PrCo5-based high-energy-density permanent magnets. J Less Common Metals. 1989;148(1):67.CrossRef
[14]
Zurück zum Zitat Shen Y, Laughlin DE, Velu EMT, Sankar SG. Microstructural studies of PrCo5 magnets. J Magn Magn Mater. 1991;94(1):57.CrossRef Shen Y, Laughlin DE, Velu EMT, Sankar SG. Microstructural studies of PrCo5 magnets. J Magn Magn Mater. 1991;94(1):57.CrossRef
[15]
Zurück zum Zitat Gutfleisch O. High-temperature samarium cobalt permanent magnets. In: Liu JP, Fullerton E, Gutfleisch O, Sellmyer DJ, editors. Nanoscale Magnetic Materials and Applications. Boston: Springer; 2009. 6. Gutfleisch O. High-temperature samarium cobalt permanent magnets. In: Liu JP, Fullerton E, Gutfleisch O, Sellmyer DJ, editors. Nanoscale Magnetic Materials and Applications. Boston: Springer; 2009. 6.
[16]
Zurück zum Zitat Ohtake M, Nukaga Y, Kirino F, Futamoto M. Preparation and structure characterization of SmCo5(0001) epitaxial thin films grown on Cu(111) underlayers. J Appl Phys. 2009;105(7):1703.CrossRef Ohtake M, Nukaga Y, Kirino F, Futamoto M. Preparation and structure characterization of SmCo5(0001) epitaxial thin films grown on Cu(111) underlayers. J Appl Phys. 2009;105(7):1703.CrossRef
[17]
Zurück zum Zitat Leupold HA, Rothwarf F, Breslin JT, Winter JJ, Tauber A, Paul DI. Contrasts in the coercivities of SmCo5 and Sm2Co17 type permanent magnets. J Appl Phys. 1982;53(3):2392.CrossRef Leupold HA, Rothwarf F, Breslin JT, Winter JJ, Tauber A, Paul DI. Contrasts in the coercivities of SmCo5 and Sm2Co17 type permanent magnets. J Appl Phys. 1982;53(3):2392.CrossRef
[18]
Zurück zum Zitat Rong CB, Zhang HW, Chen RJ, Shen BG, He SL. Micromagnetic investigation on the coercivity mechanism of the SmCo5/Sm2Co17 high-temperature magnets. J Appl Phys. 2006;100(12):123913.CrossRef Rong CB, Zhang HW, Chen RJ, Shen BG, He SL. Micromagnetic investigation on the coercivity mechanism of the SmCo5/Sm2Co17 high-temperature magnets. J Appl Phys. 2006;100(12):123913.CrossRef
[19]
Zurück zum Zitat Xu X, Zhang H, Wang T, Li Y, Zhang DT, Yue M. Local orientation texture analysis in nanocrystalline Sm0.6Pr0.4Co5 magnet and (SmCo5)0.6(PrCo5)0.4 composite magnet with strong magnetic anisotropy. J Alloys Compd. 2017;699:262.CrossRef Xu X, Zhang H, Wang T, Li Y, Zhang DT, Yue M. Local orientation texture analysis in nanocrystalline Sm0.6Pr0.4Co5 magnet and (SmCo5)0.6(PrCo5)0.4 composite magnet with strong magnetic anisotropy. J Alloys Compd. 2017;699:262.CrossRef
[20]
Zurück zum Zitat Kündig AA, Gopalan R, Ohkubo T, Hono K. Coercivity enhancement in melt-spun SmCo5 by Sn addition. Scripta Mater. 2006;54(12):2047.CrossRef Kündig AA, Gopalan R, Ohkubo T, Hono K. Coercivity enhancement in melt-spun SmCo5 by Sn addition. Scripta Mater. 2006;54(12):2047.CrossRef
[21]
Zurück zum Zitat Yang C, Hou YL. Advance in the chemical synthesis and magnetic properties of nanostructured rare-earth-based permanent magnets. Rare Met. 2013;32(2):105.CrossRef Yang C, Hou YL. Advance in the chemical synthesis and magnetic properties of nanostructured rare-earth-based permanent magnets. Rare Met. 2013;32(2):105.CrossRef
[22]
Zurück zum Zitat Buschow KHJ, Diepen AM, Wijn HW. Crystal-field anisotropy of Sm3+ in SmCo5. Solid State Commun. 1974;15(5):903.CrossRef Buschow KHJ, Diepen AM, Wijn HW. Crystal-field anisotropy of Sm3+ in SmCo5. Solid State Commun. 1974;15(5):903.CrossRef
[23]
Zurück zum Zitat Sankar SG, Rao VUS, Segal E, Wallace WE, Frederick WGD, Garrett HJ. Magnetocrystalline anisotropy of SmCo5 and its interpretation on a crystal-field model. Phys Rev B. 1975;11(1):1157.CrossRef Sankar SG, Rao VUS, Segal E, Wallace WE, Frederick WGD, Garrett HJ. Magnetocrystalline anisotropy of SmCo5 and its interpretation on a crystal-field model. Phys Rev B. 1975;11(1):1157.CrossRef
[24]
Zurück zum Zitat Jowitt SM, Werner TT, Weng ZH, Mudd GM. Recycling of the rare earth elements. Curr Opin Green Sustain Chem. 2018;13:1.CrossRef Jowitt SM, Werner TT, Weng ZH, Mudd GM. Recycling of the rare earth elements. Curr Opin Green Sustain Chem. 2018;13:1.CrossRef
[25]
Zurück zum Zitat Foner S, Mcniff EJ, Martin DL, Benz MG. Magnetic properties of cobalt-samarium with a 24 MGOe energy product. Appl Phys Lett. 1972;20(11):447.CrossRef Foner S, Mcniff EJ, Martin DL, Benz MG. Magnetic properties of cobalt-samarium with a 24 MGOe energy product. Appl Phys Lett. 1972;20(11):447.CrossRef
[26]
Zurück zum Zitat Strnat KJ, Strnat RMW. Rare earth-cobalt permanent magnets. J Magn Magn Mater. 1991;100(1):38.CrossRef Strnat KJ, Strnat RMW. Rare earth-cobalt permanent magnets. J Magn Magn Mater. 1991;100(1):38.CrossRef
[27]
Zurück zum Zitat Alameda JM, Deportes J, Givord D, Lemaire R, Lu Q. Large magnetization anisotropy in uniaxial YCo5 intermetallic. J Magn Magn Mater. 1980;1(15–18):1257.CrossRef Alameda JM, Deportes J, Givord D, Lemaire R, Lu Q. Large magnetization anisotropy in uniaxial YCo5 intermetallic. J Magn Magn Mater. 1980;1(15–18):1257.CrossRef
[28]
Zurück zum Zitat Collocott SJ, Dunlop JB, Lovatt HC, Ramsden VS. Rare-earth permanent magnets: new magnet materials and applications. Mater Sci Forum. 1999;315–317(51):77.CrossRef Collocott SJ, Dunlop JB, Lovatt HC, Ramsden VS. Rare-earth permanent magnets: new magnet materials and applications. Mater Sci Forum. 1999;315–317(51):77.CrossRef
[29]
Zurück zum Zitat Raichlen JS, Doremus RH. Kinetics of hydriding and allotropic transformation in SmCo5. J Appl Phys. 1971;42(8):3166.CrossRef Raichlen JS, Doremus RH. Kinetics of hydriding and allotropic transformation in SmCo5. J Appl Phys. 1971;42(8):3166.CrossRef
[30]
Zurück zum Zitat Yonamine T, Fukuhara M, Machado R, Missell FP. Electron back scattered diffraction study of SmCo magnets. J Magn Magn Mater. 2008;320(14):77.CrossRef Yonamine T, Fukuhara M, Machado R, Missell FP. Electron back scattered diffraction study of SmCo magnets. J Magn Magn Mater. 2008;320(14):77.CrossRef
[31]
Zurück zum Zitat Yuan X, Yue M, Zhang DT, Jin T, Zhang Z, Zuo J, Zhang J, Zhu J, Gao X. Orientation textures of grains and boundary planes in a hot deformed SmCo5 permanent magnet. CrystEngComm. 2014;16(9):1669.CrossRef Yuan X, Yue M, Zhang DT, Jin T, Zhang Z, Zuo J, Zhang J, Zhu J, Gao X. Orientation textures of grains and boundary planes in a hot deformed SmCo5 permanent magnet. CrystEngComm. 2014;16(9):1669.CrossRef
[32]
Zurück zum Zitat Bedoya PA, Zube C, Malindretos J, Urban A, Rizzi A. Epitaxial δ-MnxGa1−x layers on GaN(0001): structural, magnetic, and electrical transport properties. Phys Rev B Condens Matter. 2011;84(10):1247. Bedoya PA, Zube C, Malindretos J, Urban A, Rizzi A. Epitaxial δ-MnxGa1−x layers on GaN(0001): structural, magnetic, and electrical transport properties. Phys Rev B Condens Matter. 2011;84(10):1247.
Metadaten
Titel
Low-cost Sm0.7Y0.3Co5 sintered magnet produced by traditional powder metallurgical techniques
verfasst von
Dong-Tao Zhang
Nai-Xing Cai
Rong-Chun Zhu
Wei-Qiang Liu
Ming Yue
Publikationsdatum
27.04.2019
Verlag
Nonferrous Metals Society of China
Erschienen in
Rare Metals / Ausgabe 4/2020
Print ISSN: 1001-0521
Elektronische ISSN: 1867-7185
DOI
https://doi.org/10.1007/s12598-019-01257-8

Weitere Artikel der Ausgabe 4/2020

Rare Metals 4/2020 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.