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Colloid and Polymer Science
Erschienen in: Colloid and Polymer Science 10/2015

01.10.2015 | Original Contribution

New interpretation of the dependence of the conductibility of PSS and PAA polyions with the nature of the counterions

verfasst von: Anis Ghazouani, Sondes Boughammoura, Jalel M’halla

Erschienen in: Colloid and Polymer Science | Ausgabe 10/2015

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Abstract

The main object of this paper is to give a new interpretation of the dependence of the conductibility of a polyion with the nature of its counterions. For this, we analyzed in detail while comparing several models, the various physical factors influencing the mobility of a polyion (ionic condensation, hydrodynamic and electrophoretic frictions, ionic relaxation effect, and dielectric friction), and also their correlation with the ionic force and the conformation of the polyion. We showed that the specificity of the counterions appears in the hydrodynamic and electrophoretic effects via their effective radii, as in the dielectric friction effect, because of the influence of the condensed ions on the local permittivity around polyions.
Vorheriger Artikel Fabrication of non-close-packed colloidal monolayers by convective self-assembly using cationic polyelectrolyte-grafted silica particles
Nächster Artikel Preparation of multicompartment micelles from amphiphilic linear triblock terpolymers by pH-responsive self-assembly

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Literatur
1.
M’halla J (1999) Polyelectrolytic conductance limiting laws in conformity with the principles of equilibrium and non-equilibrium thermodynamics interdependence between conformation condensation and dielectric friction. J Mol Liq 82:183–218CrossRef
2.
M’halla J, Besbes R, Bouazzi R, Boughammoura S (2006) About the singular behavior of the ionic condensation of sodium chondroitin sulfate conductivity study in water and water-dioxane mixture. J Chem Phys 321:10–24
3.
M’halla J, Besbes R, Bouazzi R, Boughammoura S (2007) Ionic condensation of sodium chondroitin sulfate in water-dioxane mixture. J Mol Liq 130:59–69CrossRef
4.
Boughammoura S, M’halla J (2012) Estimation of the hydrophobic reactivity of SDS micelles by the use of BPh4 − anions. J Mol Liq 175:148–161CrossRef
5.
Ghazouani A, Boughammoura S, M’halla J (2012) Studies of electrolytic conductivity of some polyelectrolyte solutions importance of the dielectric friction effect at high dilution. J Chem 2013:1–15CrossRef
6.
Muthukumar M (1997) Dynamics of polyelectrolyte solutions. J Chem Phys 107:2619–2635CrossRef
7.
Sélégny E (1974) Polyelectrolytes. D. Reildel Publishing Company, Dordrecht-HollandCrossRef
8.
Manning GS (1975) Limiting laws for the conductance of the rod model of a salt-free polyelectrolyte solution. J Phys Chem 79:262–265CrossRef
9.
Manning GS (1981) Limiting laws and counterion condensation in polyelectrolyte solutions 7 electrophoretic mobility and conductance. J Phys Chem 85:1506–1515CrossRef
10.
Dobrynin AV, Rubinstein M (2005) Theory of polyelectrolytes in solutions and at surfaces. Prog Polym Sci 30:1049–1118CrossRef
11.
Brilliantov NV, Kuznetsov DV, Klein R (1998) Chain collapse counterion condensation in dilute polyelectrolyte solutions. Phys Rev Lett 8:1433–1436CrossRef
12.
Wandrey C (1999) Concentration regimes in polyelectrolyte solutions. Langmuir 15:4069–4075CrossRef
13.
M’halla J, Boughammoura S (2010) Translation dielectric friction and mobility of ellipsoidal polyions. J Mol Liq 157:89–101CrossRef
14.
M’halla J, Boughammoura S, Ghazouani A (2011) Sharp decrease of the dielectric friction on polyions during conformation transition from pearl-chain to coiled shapes. 32iémeInternational conference on solution chemistry-ICSI, la Grande Motte France
15.
Ghazouani A, Boughammoura S, M’halla J (2014) About the correlation between the mobility of a polyion and that of its counterions. J Adv Chem 10:2558–2574
16.
Vink H (1981) Conductivity of polyelectrolyte in very dilute solutions. J Chem Soc Faraday Trans 77:2439–2449CrossRef
17.
Vink H (1984) A new modified Hittorf method for the determination of transport numbers in polyelectrolyte solutions. J Chem Soc Faraday Trans 80:1297–1304CrossRef
18.
Vink H (1989) Studies of electrical transport processes in polyelectrolyte solutions. J Chem Soc Faraday Trans 85:699–709CrossRef
19.
Robinson RA, Stokes RH (1959) Electrolyte solutions. Butterworths scientific publications, London
20.
Justice JC (1971) An interpretation for the distance parameter of the Fuoss-Onsager conductance equation in the case of ionic association. Electrochim Acta 16:701–712CrossRef
21.
Blum L (1975) and (1993) Mean spherical model for asymmetric electrolytes. J Mol Phys 30: 1529–1535. J Mol Phys 47: 2983–2986
22.
23.
Fuoss R, Accascina F (1969) Electrolytic conductance. Interscience, New York
24.
Michael J, Carrillo Y, Dobrynin V (2010) Detailed molecular dynamics simulations of a model NaPSS in water. J Phys Chem B 114:9391–9399CrossRef
25.
Lee MJ, Green MM, Mikes F, Morawetz H (2002) NMR spectra of polyelectrolytes in poor solvents are consistent with the pearl necklace model of the chain molecules. Macromolecules 35:4216–4217CrossRef
26.
Batzill S, Luxemburger R, Deike R, Weber R (1998) Structural and dynamical properties of aqueous suspensions of NaPSS (HPSS) at very low ionic strength. Eur Phys J B Condens Matter Complex Syst 1:491–501CrossRef
27.
Pavlov GM, Gubarev AS, Gavrilova II, Panarin EF (2011) Conformations of sodium poly(styrene-4-sulfonate) macromolecules in solutions with different ionic strengths. Polym Sci 53(11):1003–1011
28.
Hubbard JB, Douglas JF (1993) Hydrodynamic friction of arbitrarily shaped Brownian particles. Phys Rev E 47:2983–2986CrossRef
29.
Manning GS (1969) Limiting laws and counterion condensation in polyelectrolyte solutions II. Self-diffusion of the small ions. J Chem Phys 51:934–938CrossRef
30.
Onsager L, Fuoss RM (1932) Irreversible processes in electrolytes. Diffusion, conductance and viscous flow in arbitrary mixtures of strong electrolytes. J Phys Chem 36:2689–2778CrossRef
31.
Zwanzig R (1963) Dielectric friction on a moving ion. J Chem Phys 38:1603–1605CrossRef
32.
Hubbard JB, Onsager L (1977) Dielectric dispersion and dielectric friction in electrolyte solutions I and II. J Chem Phys 67:4850–4857, J. B. Hubbard J B (1978). J Chem Phys 68: 1649–1664 CrossRef
33.
Wolynes PG (1978) Molecular theory of solvated ion dynamics. J Chem Phys 68:473–483CrossRef
34.
Manning GS (1967) Molecular theory of counterion conductivity and self-diffusion in polyelectrolyte solutions. J Chem Phys 47:2010–2013CrossRef
35.
Huizenga JR, Griegor PF, Wall FT (1950) Electrolytic properties of aqueous solutions of polyacrylic acid and sodium hydroxude. II. Diffusion experiments using radioactive sodium. J Am Chem Soc 72:4228–4232CrossRef
36.
Katchalsky A, Alexandrowicz Z, Kedem O (1966) In: Conway BE, Barradas RG (eds) Chemical physics of ionic solutions. John Wiley and Sons, New York, pp 295–346
37.
Hasted JB (1973) Electrolytic solutions aqueous dielectrics. Chapman and Hall, London, pp 136–175
38.
Metadaten
Titel
New interpretation of the dependence of the conductibility of PSS and PAA polyions with the nature of the counterions
verfasst von
Anis Ghazouani
Sondes Boughammoura
Jalel M’halla
Publikationsdatum
01.10.2015
Verlag
Springer Berlin Heidelberg
Erschienen in
Colloid and Polymer Science / Ausgabe 10/2015
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-015-3699-0

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