Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Polymer Bulletin
Erschienen in: Polymer Bulletin 11/2020

13.12.2019 | Review Paper

Ni/Pd-catalyzed coordination-insertion copolymerization of ethylene with alkyl acrylate

verfasst von: Urmilla Baruah, Prakash J. Saikia, Shashi D. Baruah

Erschienen in: Polymer Bulletin | Ausgabe 11/2020

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Commercially, polyethylene is a highly produced commodity polymer. But due to its hydrophobic nature, it limits its applications, where utility is based on surface properties, such as adhesion, printability, wettability, and miscibility with other polar polymers. Therefore, the presence of a hydrophilic polar functionality is desired to overcome such difficulties. With its high exigency, synthesis of functionalized polyethylene with unique surface properties is now a very challenging task to be accomplished. In this perspective, developments on palladium and nickel (mainly based on ligands containing neutral α-diimine and anionic phosphine–sulfonate derivative)-mediated coordination/insertion copolymerization of ethylene with polar functionalized co-monomers are discussed herein.
Vorheriger Artikel Developed methods for the preparation of electrospun nanofibers containing plant-derived oil or essential oil: a systematic review

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
1.
Gaikwad SR, Deshmukh SS, Gonnade RG, Rajamohanan PR, Chikkali SH (2015) Insertion copolymerization of difunctional polar vinyl monomers with ethylene. ACS Macro Lett 4:933–937
2.
Hutley TJ, Ouederni M (2016) Polyolefins: the history and economic impact. In: AlMa’adeed MA-A, Krupa I (eds) Polyolefin compounds and materials: fundamentals and industrial applications. Springer series on polymer and composite materials. Springer, Berlin
3.
Boffa LS, Novak BM (2000) Copolymerization of Polar Monomers with Olefins Using Transition-Metal Complexes. Chem Rev 100:1479–1493PubMed
4.
Britovsek GJP, Gibson VC, Wass DF (1999) The search for new-generation olefin polymerization catalysts: life beyond metallocenes. Angew Chem Int Ed 38:428–447
5.
Baruah U, Gautam A, Saikia M, Borphukan S, Saikia PJ, Baruah SD (2017) Monodisperse copolymer nanosphere assembly by miniemulsion polymerization. Eur Polym J 96:111–118
6.
Baruah U, Saikia M, Assanvo EF, Borphukan S, Phukan L, Gautam A, Baruah SD (2016) Synthesis and thermal analysis of poly(methyl methacrylate) oligomer functionalized polyethylene block copolymer. Polym Bull 74:2137–2158
7.
Saikia M, Borphukan S, Baruah U, Gautam A, Saikia PJ, Baruah SD (2017) Poly(ethylene-co-BMA) via dual concurrent ATRP–RAFT and its thermokinetic study. J Therm Anal Calorim 131:1517–1526
8.
Boaen NK, Hillmyer MA (2005) Post-polymerization functionalization of polyolefins. Chem Soc Rev 34:267–275PubMed
9.
Rojas G, Berda EB, Wagener KB (2008) Precision polyolefin structure: modeling polyethylene containing alkyl branches. Polymer 49:2985–2995
10.
Camm KD, Castro NM, Liu Y, Czechura P, Snelgrove JL, Fogg DE (2007) Tandem ROMP–hydrogenation with a third-generation grubbs catalyst. J Am Chem Soc 129:4168–4169PubMed
11.
Leblanc A, Grau E, Broyer JP, Boisson C, Spitz R, Monteil V (2011) Homo- and copolymerizations of (meth)acrylates with olefins (styrene, ethylene) using neutral nickel complexes: a dual radical/catalytic pathway. Macromolecules 44:3293–3301
12.
Daigle JC, Piche L, Claverie JP (2011) Preparation of functional polyethylenes by catalytic copolymerization. Macromolecules 44:1760–1762
13.
Carrow BP, Nozaki K (2012) Synthesis of functional polyolefins using cationic bisphosphine monoxide–palladium complexes. J Am Chem Soc 134:8802–8805PubMed
14.
Meduri A, Montini T, Ragaini F, Fornasiero P, Zangrando E, Milani B (2013) Palladium-catalyzed ethylene/methyl acrylate cooligomerization: effect of a new nonsymmetric α-diimine. ChemCatChem 5:1170–1183
15.
Contrella ND, Sampson JR, Jordan RF (2014) Copolymerization of ethylene and methyl acrylate by cationic palladium catalysts that contain phosphine-diethyl phosphonate ancillary ligands. Organometallics 33:3546–3555
16.
Takano S, Takeuchi D, Osakada K, Akamatsu N, Shishido A (2014) Dipalladium catalyst for olefin polymerization: Introduction of acrylate units into the main chain of branched polyethylene. Angew Chemie Int Ed 53:9246–9250
17.
Allen KE, Campos J, Daugulis O, Brookhart M (2015) Living polymerization of ethylene and copolymerization of ethylene/methyl acrylate using “sandwich” diimine palladium catalysts. ACS Catal 5:456–464
18.
Nuzzo RG, Smolinsky G (1984) Preparation and characterization of functionalized polyethylene surfaces. Macromolecules 17:1013–1019
19.
Johnson LK, Mecking S, Brookhart M (1996) Copolymerization of ethylene and propylene with functionalized vinyl monomers by palladium(II) catalysts. J Am Chem Soc 118:267–268
20.
Johnson LK, Killian CM, Brookhart M (1995) New Pd(II)-and Ni(II)-based catalysts for polymerization of ethylene and. alpha.-olefins. J Am Chem Soc 117:6414–6415
21.
Rhinehart JL, Brown LA, Long BK (2013) A robust Ni(II) α-diimine catalyst for high temperature ethylene polymerization. J Am Chem Soc 135:16316–16319PubMed
22.
Meinhard D, Wegner M, Kipiani G, Hearley A, Reuter P, Fischer S, Marti O, Rieger B (2007) New nickel(II) diimine complexes and the control of polyethylene microstructure by catalyst design. J Am Chem Soc 129:9182–9191PubMed
23.
Ionkin AS, Marshall WJ (2004) Ortho-5-methylfuran- and benzofuran-substituted η3-allyl(α-diimine)nickel(II) complexes: syntheses, structural characterization, and the first polymerization results. Organometallics 23:3276–3283
24.
Schmid M, Eberhardt R, Klinga M, Leskela M, Rieger B (2001) New C2v- and chiral C2-symmetric olefin polymerization catalysts based on nickel(II) and palladium(II) diimine complexes bearing 2,6-diphenyl aniline moieties: synthesis, structural characterization, and first insight into polymerization properties. Organometallics 20:2321–2330
25.
Camacho DH, Guan Z (2005) Living polymerization of α-olefins at elevated temperatures catalyzed by a highly active and robust cyclophane-based nickel catalyst. Macromolecules 38:2544–2546
26.
Zanchin G, Bertini F, Vendier L, Ricci G, Lorber C, Leone G (2019) Copolymerization of ethylene with propylene and higher α-olefins catalyzed by (imido)vanadium(iv) dichloride complexes. Polym Chem 10:6200–6216
27.
Nakano R, Chung LW, Watanabe Y, Okuno Y, Okumura Y, Ito S, Morokuma K, Nozaki K (2016) Elucidating the key role of phosphine–sulfonate ligands in palladium-catalyzed ethylene polymerization: effect of ligand structure on the molecular weight and linearity of polyethylene. Catalysis 6:6101–6113
28.
Noda S, Nakamura A, Kochi T, Lung WC, Morokuma K, Nozaki K (2009) Mechanistic studies on the formation of linear polyethylene chain catalyzed by palladium phosphine–sulfonate complexes: experiment and theoretical studies. J Am Chem Soc 131:14088–14100PubMed
29.
Haras A, Anderson GDW, Michalak A, Rieger B, Ziegler T (2006) Computational insight into catalytic control of poly(ethylene–methyl acrylate) topology. Organometallics 25:4491–4497
30.
Guironnet D, Caporaso L, Neuwald B, Go I, Cavallo L, Mecking S (2010) Mechanistic insights on acrylate insertion polymerization. J Am Chem Soc 132:4418–4426PubMed
31.
Nozaki K, Kusumoto S, Noda S, Kochi T, Chung LW, Morokuma K (2010) Why did incorporation of acrylonitrile to a linear polyethylene become possible? Comparison of phosphine–sulfonate ligand with diphosphine and imine–phenolate ligands in the Pd-catalyzed ethylene/acrylonitrile copolymerization. J Am Chem Soc 132:16030–16042PubMed
32.
Kim Y, Jordan RF (2011) Synthesis, structures, and ethylene dimerization reactivity of palladium alkyl complexes that contain a chelating phosphine–trifluoroborate ligand. Organometallics 30:4250–4256
33.
Gott AL, Piers WE, Dutton JL, Mcdonald R, Parvez M (2011) Dimerization of ethylene by palladium complexes containing bidentate trifluoroborate-functionalized phosphine ligands. Organometallics 30:4236–4249
34.
Liu W, Malinoski JM, Brookhart M, Hill C, Carolina N (2002) Ethylene polymerization and ethylene/methyl 10-undecenoate copolymerization using nickel(II) and palladium(II) complexes derived from a bulky P, O chelating ligand. Organometallics 21:2836–2838
35.
Malinoski JM, Brookhart M, Hill C, Carolina N (2003) Polymerization and oligomerization of ethylene by cationic nickel(II) and palladium(II) complexes containing bidentate phenacyldiarylphosphine ligands. Organometallic 22:5324–5335
36.
Britovsek GJP, Keim W, Mecking S, Sainz D, Wagner T (1993) Hemilabile P, O-ligands in palladium catalysed C-C linkages: codimerization of ethylene and styrene and cooligomerization of ethylene and carbon monoxide. J Chem Soc Chem Commun 1993:1632–1634
37.
Mecking S, Keim W (1996) Cationic palladium η3-allyl complexes with hemilabile p, o-ligands: Synthesis and reactivity, insertion of ethylene into the pd–allyl function. Organometallics 15:2650–2656
38.
Reisinger CM, Nowack J, Volkmer D, Rieger B (2007) Novel palladium complexes employing mixed phosphine phosphonates and phosphine phosphinates as anionic chelating [P, O] ligands. Dalton Trans 2:272–278
39.
Carrow BP, Nozaki K (2014) Transition-metal-catalyzed functional polyolefin synthesis: effecting control through chelating ancillary ligand design and mechanistic insights. Macromolecules 47:2541–2555
40.
Brassat I, Keim W, Killat S, Mothrath M, Francesco C, Paolo G (2000) Synthesis and catalytic activity of allyl, methallyl and methyl complexes of nickel(II) and palladium(II) with biphosphine monoxide ligands: oligomerization of ethylene and copolymerization of ethylene and carbon monoxide. J Mol Catal A Chem 157:41–58
41.
Mitsushige Y, Carrow BP, Ito S, Nozaki K (2016) Ligand-controlled insertion regioselectivity accelerates copolymerisation of ethylene with methyl acrylate by cationic bisphosphine monoxide–palladium catalysts. Chem Sci 7:737–744PubMed
42.
Sui X, Dai S, Chen C (2015) Ethylene polymerization and copolymerization with polar monomers by cationic phosphine phosphonic amide palladium complexes. ACS Catal 5:5932–5937
43.
Zhang Y, Cao Y, Leng X, Chen C, Huang Z (2014) Cationic palladium (II) complexes of phosphine–sulfonamide ligands: synthesis, characterization, and catalytic ethylene oligomerization. Organometallics 33:3738–3745
44.
Schneider MJ, Schafer R, Mühaupt R (1997) Aminofunctional linear low density polyethylene via metallocene-catalysed ethene copolymerization with N,N-bis (trimethylsilyl)-1-amino-10-undecene. Polymer 38:2455–2459
45.
Purgeti MD, Vogl O (1988) Functional polymers: polymerization of ω-alkenoate derivatives. J Polym Sci Part A Polym Chem 26:677–700
46.
Kesti MR, Coates GW, Waymouth RM (1992) Homogeneous Ziegler–Natta polymerization of functionalized monomers catalyzed by cationic Group IV metallocenes. J Am Chem Soc 114:9679–9680
47.
Clark KJ (1970) Olefin copolymers containing polar groups and process for their preparation. US Patent 3949277
48.
Langer A, Haynes R (1973) Copolymerization of alpha olefins with sterically hindered alkenyl amines using ziegler catalysts. US Patent 3755279
49.
Rix FC, Brookhart M (1995) Energetics of migratory insertion reactions in Pd(II) acyl ethylene, alkyl ethylene, and alkyl carbonyl complexes. J Am Chem Soc 117:1137–1138
50.
Younkin TR, Connor EF, Henderson JI, Friedrich SK, Grubbs RH, Bansleben DA (2000) Neutral, single-component nickel(II) polyolefin catalysts that tolerate heteroatoms. Science 287:460–462PubMed
51.
Ascenso R, Ribeiro AFG, Correia SG, Marques MM, Gomes PT, Dias AR, Blais M, Rausch MD, Chien JCW (1999) Polymerization with TMA-protected polar vinyl comonomers. II. Catalyzed by nickel complexes containing α-diimine-type ligands. J Polym Sci Part A Polym Chem 37:2471–2480
52.
Chung TC (2002) Synthesis of functional polyolefin copolymers with graft and block structures. Prog Polym Sci 27:39–85
53.
Jagur-Grodzinski J (1992) Modification of polymers under heterogeneous conditions. Prog Polym Sci 17:361–415
54.
Singh RP (1992) Surface grafting onto polypropylene-a survey of recent developments. Prog Polym Sci 17:251–281
55.
Duchateau J, Lutsen L, Guedens W, Cleij TJ, Vanderzande D (2010) Versatile post-polymerization functionalization of poly(p-phenylene vinylene) copolymers containing carboxylic acid substituents: development of a universal method towards functional conjugated copolymers. Polym Chem 1:1313–1322
56.
Goldmann AS, Glassner M, Inglis AJ, Kowollik CB (2013) Post-functionalization of polymers via orthogonal ligation chemistry. Macromol Rapid Commun 34:810–849PubMed
57.
Zhou H, Plummer CM, Li H, Huang H, Ma P, Li L, Liu L, Chen Y (2019) Regioselective post-functionalization of isotactic polypropylene by amination in the presence of N-hydroxyphthalimide. Polym Chem 10:619–626
58.
Ittel SD, Johnson LK, Brookhart M (2000) Late-metal catalysts for ethylene homo-and copolymerization. Chem Rev 100:1169–1204PubMed
59.
Chen CL (2018) Designing catalysts for olefin polymerization and copolymerization: beyond electronic and steric tuning. Nat Rev Chem 2:6–14
60.
Johnson LK, Dobbs K, Hauptman E, Lonkin A, Ittel S, McCord E, McLain SJ, Yin Z, Wang Y, Brookhart M (2002) Presented at the American Chemical Society Meeting, Orlando, FL
61.
McLain SJ, Sweetman KJ, Johnson LK, McCord EF (2002) Presented at the American Chemical Society Meeting, Orlando, FL
62.
Makovetsky KL, Finkelshtein ES, Bykov VI, Bagdasaryan AK, Goodall BL, Rhodes LF (1998) Method for preparation of copolymers of ethylene/norbornene-type monomers with nickel catalysts. US Patent 5(929):181A
63.
Connor EF, Younkin TR, Henderson JI, Hwang S, Grubbs RH, Roberts WP, Litzau JJ (2002) Linear functionalized polyethylene prepared with highly active neutral Ni(II) complexes. J Polym Sci Part A Polym Chem 40:2842–2854
64.
Leibfarth FA, Schneider Y, Lynd NA, Schultz A, Moon B, Kramer EJ, Bazan GC, Hawker CW (2010) Ketene functionalized polyethylene: control of cross-link density and material properties. J Am Chem Soc 132:14706–14709PubMed
65.
Takeuchi D, Chiba Y, Takano S, Osakada K (2013) Double-decker-type dinuclear nickel catalyst for olefin polymerization: Efficient incorporation of functional co-monomers. Angew Chem 125:12768–12772
66.
Radlauer MR, Buckley AK, Henling LM, Agapie T (2013) Bimetallic coordination insertion polymerization of unprotected polar monomers: copolymerization of amino olefins and ethylene by dinickel bisphenoxyiminato catalysts. J Am Chem Soc 135:3784–3787PubMed
67.
Guo L, Dai S, Sui X, Chen C (2016) Palladium and nickel catalyzed chain walking olefin polymerization and copolymerization. ACS Catal 6:428–441
68.
Zhong L, Li G, Liang G, Gao H, Wu Q (2017) Enhancing thermal stability and living fashion in α-diimine–nickel-catalyzed (co)polymerization of ethylene and polar monomer by increasing the steric bulk of ligand backbone. Macromolecules 50:2675–2682
69.
Cheng H, Su Y, Hu Y, Zhang X, Cai Z (2018) Ethylene polymerization and copolymerization with polar monomers using nickel complexes bearing anilinobenzoic acid methyl ester ligand. Polymers 10:754–763PubMedCentral
70.
Xia J, Zhang Y, Zhang J, Jian Z (2019) High-performance neutral phosphine-sulfonate nickel(II) catalysts for efficient ethylene polymerization and copolymerization with polar monomers. Organometallics 38:1118–1126
71.
Gao J, Yang B, Chen C (2019) Sterics versus electronics: Imine/phosphine-oxide-based nickel catalysts for ethylene polymerization and copolymerization. J Catal 369:233–238
72.
Mecking S, Johnson LK, Wang L, Brookhart M (1998) Mechanistic studies of the palladium-catalyzed copolymerization of ethylene and α-olefins with methyl acrylate. J Am Chem Soc 120:888–899
73.
Drent E, van Dijk R, van Ginkel R, van Oort B, Pugh RI (2002) Palladium catalysed copolymerisation of ethene with alkylacrylates: polar comonomer built into the linear polymer chain. Chem Commun 31:744–745
74.
Hearley AK, Nowack J, Rieger B (2005) New single-site palladium catalysts for the nonalternating copolymerization of ethylene and carbon monoxide. Organometallics 24:2755–2763
75.
Skupov KM, Marella PR, Simard M, Yap GPA, Allen N, Conner D, Goodall BL, Claverie JP (2007) Palladium aryl sulfonate phosphine catalysts for the copolymerization of acrylates with ethene. Macromol Rapid Commun 28:2033–2038
76.
Kochi T, Noda S, Yoshimura K, Nozaki K (2007) Formation of linear copolymers of ethylene and acrylonitrile catalyzed by phosphine sulfonate palladium complexe. J Am Chem Soc 129:8948–8949PubMed
77.
Weng W, Shen Z, Jordan RF (2007) Copolymerization of ethylene and vinyl fluoride by (phosphine-sulfonate) Pd (Me)(py) catalysts. J Am Chem Soc 129:15450–15451PubMed
78.
Borkar S, Newsham DK, Sen A (2008) Copolymerization of ethene with styrene derivatives, vinyl ketone, and vinylcyclohexane using a (phosphine–sulfonate)palladium(II) system: unusual functionality and solvent tolerance. Organometallics 27:3331–3334
79.
Ito S, Munakata K, Nakamura A, Nozaki K (2009) Copolymerization of vinyl acetate with ethylene by palladium/alkylphosphine–sulfonate catalysts. J Am Chem Soc 131:14606–14607PubMed
80.
Shen Z, Jordan RF (2010) Copolymerization of ethylene and vinyl fluoride by (phosphine-bis (arenesulfonate)) PdMe (pyridine) catalysts: insights into inhibition mechanisms. Macromolecules 43:8706–8708
81.
Rünzi T, Fröhlich D, Mecking S (2010) Direct synthesis of ethylene–acrylic acid copolymers by insertion polymerization. J Am Chem Soc 132:17690–17691PubMed
82.
Kryuchkov VA, Daigle JC, Skupov KM, Claverie JP, Winnik FM (2010) Amphiphilic polyethylenes leading to surfactant-free thermoresponsive nanoparticles. J Am Chem Soc 132:15573–15579PubMed
83.
Ravasio A, Boggioni L, Tritto I (2011) Copolymerization of ethylene with norbornene by neutral aryl phosphine sulfonate palladium catalyst. Macromolecules 44:4180–4186
84.
Li H, Li L, Marks TJ (2004) Polynuclear olefin polymerization catalysis: proximity and cocatalyst effects lead to significantly increased polyethylene molecular weight and comonomer enchainment level. Angew Chem 116:5045–5048
85.
Dai S, Sui X, Chen C (2015) Highly robust palladium(II) α-diimine catalysts for slow-chain-walking polymerization of ethylene and copolymerization with methyl acrylate. Angew Chemie Int Ed 54:9948–9953
86.
Chen Z, Liu W, Daugulis O, Brookhart M (2016) Mechanistic studies of Pd(II)-catalyzed copolymerization of ethylene and vinylalkoxysilanes: Evidence for a β-silyl elimination chain transfer mechanism. J Am Chem Soc 138:16120–16129PubMed
87.
Tao W, Akita S, Nakano R, Ito S, Hoshimoto Y, Ogoshi S, Nozaki K (2017) Copolymerisation of ethylene with polar monomers by using palladium catalysts bearing an N-heterocyclic carbene–phosphine oxide bidentate ligand. Chem Commun 53:2630–2633
88.
Zhai F, Solomon JB, Jordan RF (2017) Copolymerization of ethylene with acrylate monomers by amide-functionalized α-diimine Pd catalysts. Organometallics 36:1873–1879
89.
Ding L, Cheng H, Li Y, Tanaka R, Shiono T, Cai Z (2018) Efficient ethylene copolymerization with polar monomers using palladium anilinonaphthoquinone catalysts. Polym Chem 9:5476–5482
90.
Ye J, Mu H, Wang Z, Jian Z (2019) Heteroaryl backbone strategy in bisphosphine monoxide palladium-catalyzed ethylene polymerization and copolymerization with polar monomers. Organometallics 38:2990–2997
Metadaten
Titel
Ni/Pd-catalyzed coordination-insertion copolymerization of ethylene with alkyl acrylate
verfasst von
Urmilla Baruah
Prakash J. Saikia
Shashi D. Baruah
Publikationsdatum
13.12.2019
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 11/2020
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-019-03055-9

Weitere Artikel der Ausgabe 11/2020

Polymer Bulletin 11/2020 Zur Ausgabe

Original Paper

Fabrication of rigid polyimide foams via thermal foaming of nadimide-end-capped polyester-amine precursor

Original Paper

New polymer systems based on polyethylene glycol: synthesis, characterization, and study of the solubility behavior

Original Paper

Investigation of the mechanical and thermal properties of reactive AAEM-co-MMA adhesive

Original Paper

Adsorptive abatement of ciprofloxacin using NiFe2O4 nanoparticles incorporated into G. ghatti-cl-P(AAm) nanocomposites hydrogel: isotherm, kinetic, and thermodynamic studies

Review Paper

Developed methods for the preparation of electrospun nanofibers containing plant-derived oil or essential oil: a systematic review

Original Paper

Synthesis of surface-functionalized polymer particles prepared by amphiphilic macromonomers with hydrophobic end groups

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise