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Polymer Bulletin

Erschienen in:

10.12.2019 | Original Paper

Synthesis of surface-functionalized polymer particles prepared by amphiphilic macromonomers with hydrophobic end groups

verfasst von: Jin Motoyanagi, Noor Faizah Che Harun, Masahiko Minoda

Erschienen in: Polymer Bulletin | Ausgabe 11/2020

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Abstract

A series of amphiphilic poly(vinyl ether)-based macromonomers having an aromatic ring, such as phenyl, naphthyl, and anthryl group, at ω-terminus (MA-PMEEVE-Ph, MA-PMEEVE-Nap, and MA-PMEEVE-Ant) were synthesized by living cationic polymerization and reductive amination. The obtained amphiphilic macromonomers possess narrow molecular distributions (M_w/M_n = 1.14–1.41) and well-controlled degree of polymerization (DP_n ≈ 40). In addition, the functionality of the ω-terminus is equal to unity for all the macromonomers. Then, copolymerizations of the obtained macromonomers with styrene in polar solvents were performed to form nearly monodisperse polymer particles. In order to clarify the effect of the terminal hydrophobic group on particle formation behavior, we have investigated the relationships between the feed ratio of the macromonomers to styrene and particle diameter (D_n) and distribution of the particle diameter. As a result, MA-PMEEVE-Ant afforded the smallest polymer particle of D_n = 70 nm. It was also found that the particle diameter can be controlled by tuning the hydrophobicity of the ω-terminus group.

Vorheriger Artikel Silver nanoparticles-embedded poly(1-naphthylamine) nanospheres for low-cost non-enzymatic electrochemical H2O2 sensor

Nächster Artikel Synthesis, thermal stability and kinetic decomposition of triblock copolymer polypropylene glycol–poly glycidyl nitrate–polypropylene glycol (PPG–PGN–PPG)

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Titel: Synthesis of surface-functionalized polymer particles prepared by amphiphilic macromonomers with hydrophobic end groups
verfasst von: Jin Motoyanagi
Noor Faizah Che Harun
Masahiko Minoda
Publikationsdatum: 10.12.2019
Verlag: Springer Berlin Heidelberg
Erschienen in: Polymer Bulletin / Ausgabe 11/2020
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-019-03044-y

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