nach oben

Polymer Bulletin

Erschienen in:

07.12.2019 | Original Paper

Reinforcing agents based on cellulose fibers modified by insertion of end-alkyl groups obtained from pyrolytic bio-oil of sugarcane bagasse

verfasst von: Manuel Palencia, Mayra A. Mora, Tulio A. Lerma, Natalia Afanasjeva, José H. Isaza

Erschienen in: Polymer Bulletin | Ausgabe 11/2020

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

Modification of cellulose fibers is a promissory alternative for the production of new composite materials, but the high hydrophilicity of cellulose limits its use as a reinforcing agent in the making of olefin-based composites. The aim of this research was to develop reinforcing agents based on cellulose fibers modified by insertion of end-alkyl groups from pyrolytic bio-oil (PBO). For that, PBO of sugarcane bagasse was obtained and characterized by several techniques including gas chromatography coupled to mass spectrometry. Later, the surface of cellulose fibers was activated using methylene-bis-isocyanate and modified using acetic acid, formic acid, and PBO. Results show that the modification of cellulose surface is possible by the use of PBO at low temperature obtaining results like to those obtained when organic acids are used.

Vorheriger Artikel Synthesis, characterization and end-functionalization of a novel telechelic star: styrene hexamer core carrying polyisobutylene arms fitted with allyl termini

Nächster Artikel From starch to oligoetherols and polyurethane foams

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Kumar V, Kumari M (2014) Processing and characterization of natural cellulose fibers/thermoset polymer composites. Carbon Polym 109:102–117. https://doi.org/10.1016/j.carbpol.2014.03.039CrossRef

Ng HM, Sin LT, Bee ST, Tee TT, Tahmat AR (2017) Review of nanocellulose polymer composite characteristics and challenges. Polymer-Plastic Technol Eng 56:687–731. https://doi.org/10.1080/03602559.2016.1233277CrossRef

Pappu A, Pickering K, Kumar V (2019) Manufacturing and characterization of sustainable hybrid composites using sisal and hemp fibres as reinforcement of poly(lactic acid) via injection moulding. Ind Crops Prod 137:260–269. https://doi.org/10.1016/j.indcrop.2019.05.040CrossRef

Moshiul AK, Beg MD, Reddy DM, Khan MR, Mina MF (2012) Structures and performances of simultaneous ultrasound and alkali treated oil palm empty fruit bunch fiber reinforced poly(lactic acid) composites. Compos Part A Appl Sci Manuf 43:1921–1929. https://doi.org/10.1016/j.compositesa.2012.06.012CrossRef

Belgacem RN, Gandini A (2005) The surface modification of cellulose fibres for use as reinforcing elements in composite materials. Compos interf 12:41–75. https://doi.org/10.1163/1568554053542188CrossRef

Alila S, Boufi S (2009) Removal of organic pollutants from water by modified cellulose fibres. Ind Crops Prod 30:93–104. https://doi.org/10.1016/j.indcrop.2009.02.005CrossRef

Alila S, Ferraria AM, Botelho do Rego AM, Boufi S (2009) Controlled surface modification of cellulose fibers by amino derivatives using N,N′-carbonyldiimidazole as activator. Carbohydr Polym 77:553–562. https://doi.org/10.1016/j.carbpol.2009.01.028CrossRef

Elegir G, Kindl A, Sadocco P, Orlandi M (2008) Development of antimicrobial cellulose packaging through laccase-mediated grafting of phenolic compounds. Enzyme Microbial Technol 43:84–92. https://doi.org/10.1016/j.enzmictec.2007.10.003CrossRef

Palencia M, Berrio ME, García-Quintero A, Lerma T (2019) In: Giri T, Ghosh B (eds) Polysacharide-based nano-biocarrier in drug delivery. CRC Press, Boca Raton, Chapter 3, pp 39–62

10.

Jedvert K, Heinze T (2017) Cellulose modification and shaping—a review. J Polym Eng 37:845–860. https://doi.org/10.1515/polyeng-2016-0272CrossRef

11.

Hajlane A, Kaddami H, Joffe R (2017) Chemical modification of regenerated cellulose fibers by cellulose nano-crystals: towards hierarchical structure for structural composites reinforcement. Ind Crops Prod 100:41–50. https://doi.org/10.1016/j.indcrop.2017.02.006CrossRef

12.

Sultan M, Mahmood K, Nawaz H, Jamil T, Hussain R, Zuber M (2012) Modification of cellulosic fiber with polyurethane acrylate copolymers. Part I Physicochemical properties. Carbohyd Polym 87:397–404. https://doi.org/10.1016/j.carbpol.2011.07.070CrossRef

13.

Gustavsson MT, Persson PV, Iversen T, Martinelle M, Hult K, Teeri TT, Brumer H (2005) Modification of cellulose fiber surfaces by use of a lipase and a xyloglucan endotransglycosylase. Biomacromol 6:196–203. https://doi.org/10.1021/bm049588iCrossRef

14.

Ramesh S, Shanti R, Morris E (2013) Characterization of conducting cellulose acetate based polymer electrolytes doped with “green” ionic mixture. Carbohyd Polym 91:14–21. https://doi.org/10.1016/j.carbpol.2012.07.061CrossRef

15.

Meier D, Faix O (1999) State of the art of applied fast pyrolysis of lignocellulosic materials—a review. Biores Technol 68:71–77. https://doi.org/10.1016/S0960-8524(98)00086-8CrossRef

16.

Stefanidis SD, Kalogiannis KG, Iliopoulou EF et al (2014) A study of lignocellulosic biomass pyrolysis via the pyrolysis of cellulose, hemicellulose and lignin. J Anal Appl Pyrol 105:143–150. https://doi.org/10.1016/j.jaap.2013.10.013CrossRef

17.

Afanasjeva N, Castillo LC, Sinisterra JC (2017) Lignocellulosic biomass. Part I: biomass transformation. J Sci Tecnol Appl 3:27–43. https://doi.org/10.34294/j.jsta.17.3.22CrossRef

18.

Kumar A, Mondal P (2017) Pyrolysis of sugarcane bagasse in semi batch reactor: effects of process parameters on product yields and characterization of products. Ind Crops Prod 95:704–717. https://doi.org/10.1016/j.indcrop.2016.11.039CrossRef

19.

Sohaib Q, Muhammad A, Younas M (2017) Fast pyrolysis of locally available green waste at different residence time and temperatures. Energy Sources Part A Recovery Util Environ Effects 39:184–190. https://doi.org/10.1080/15567036.2017.1363830CrossRef

20.

Durange JA, Santos MR, Pereira MM et al (2013) Physicochemical properties of pyrolysis bio-oil from sugarcane straw and sugarcane in natura. J Biomater Nanobiotechnol 4:10–19. https://doi.org/10.4236/jbnb.2013.42A002CrossRef

21.

Palencia M (2017) Surface free energy of solids by contact angle measurements. J Sci Technol Appl 2:84–93. https://doi.org/10.34294/j.jsta.17.2.17CrossRef

22.

García-Pérez M, Chaala A, Roy C (2002) Vacuum pyrolysis of sugarcane bagasse. J Anal Appl Pyrol 65:111–136. https://doi.org/10.1016/S0165-2370(01)00184-XCrossRef

23.

Restrepo D, García A, Combatt E (2018) Infrared spectroscopy in the analysis of cation exchange capacity of soils—A review. J Sci Technol Appl 5:55–65. https://doi.org/10.34294/j.jsta.18.5.35CrossRef

24.

Palencia M, Lerma T, Berrio ME (2017) Thin-film composite by in situ polymerization of 4-chloromethyl styrene functionalized with N-methyl-D-glucamine in pore-type microreactors. J Sci Technol Appl 3:66–76. https://doi.org/10.34294/j.jsta.17.3.25CrossRef

25.

Palencia M (2018) Functional transformation of Fourier-transform mid-infrared spectrum for improving spectral specificity by simple algorithm based on wavelet-like functions. J Adv Res 14:53–62. https://doi.org/10.1016/j.jare.2018.05.009CrossRefPubMedPubMedCentral

26.

Arbelaez N, Lerma T, Córdoba A (2017) Modification of membranes by insertion of short-chain alcohols on reactive porous substrates: effect of chain length on the surface free energy. J Sci Technol Appl 2:75–83. https://doi.org/10.34294/j.jsta.17.2.16CrossRef

27.

Sardo H, Pascual A, Mecerreyes D, Taton D, Cramail H, Hedrick J (2015) Synthesis of polyurethanes using organocatalysis: a perspective. Macromol 48:3153–3165. https://doi.org/10.1021/acs.macromol.5b00384CrossRef

28.

Wiley J, Atalla R (1987) Band assignments in the Raman spectra of celluloses. Carbohydr Res 160:113–129. https://doi.org/10.1016/0008-6215(87)80306-3CrossRef

29.

Rahman R, Hamdan S, Ngaini ZB et al (2018) Cellulose fiber-reinforced thermosetting composites: impact of cyanoethyl modification on mechanical, thermal and morphological properties. Polym Bull. https://doi.org/10.1007/s00289-018-2598-1CrossRef

30.

Miléo PC, Oliveira MF, Luz SM et al (2016) Thermal and chemical characterization of sugarcane bagasse cellulose/lignin-reinforced composites. Polym Bull 73:3163. https://doi.org/10.1007/s00289-016-1647-xCrossRef

31.

Gaan S, Rupper P, Salimova V et al (2009) Thermal decomposition and burning behavior of cellulose treated with ethyl ester phosphoramidates: Effect of alkyl substituent on nitrogen atom. Polym Degrad Stabil 94:1125–1134. https://doi.org/10.1016/j.polymdegradstab.2009.03.017CrossRef

32.

Loof D, Hiller M, Oschkinat H, Koschek K (2016) Quantitative and qualitative analysis of surface modified cellulose utilizing TGA-MS. Materials (Basel, Switzerland) 9(6):415. https://doi.org/10.3390/ma9060415CrossRefPubMedCentral

Titel: Reinforcing agents based on cellulose fibers modified by insertion of end-alkyl groups obtained from pyrolytic bio-oil of sugarcane bagasse
verfasst von: Manuel Palencia
Mayra A. Mora
Tulio A. Lerma
Natalia Afanasjeva
José H. Isaza
Publikationsdatum: 07.12.2019
Verlag: Springer Berlin Heidelberg
Erschienen in: Polymer Bulletin / Ausgabe 11/2020
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-019-03050-0

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 11/2020

Adsorptive abatement of ciprofloxacin using NiFe2O4 nanoparticles incorporated into G. ghatti-cl-P(AAm) nanocomposites hydrogel: isotherm, kinetic, and thermodynamic studies

Compatibilization of immiscible polymer blends (R-PET/PP) by adding PP-g-MA as compatibilizer: analysis of phase morphology and mechanical properties

Mechanical properties and creep behavior of fluoroelastomer under hydrochloric acid environments

Silver nanoparticles-embedded poly(1-naphthylamine) nanospheres for low-cost non-enzymatic electrochemical H2O2 sensor

Investigation of the mechanical and thermal properties of reactive AAEM-co-MMA adhesive

Preparation and characterization of aliphatic polyurethane and modified hydroxyapatite composites for bone tissue engineering

Premium Partner

Marktübersichten