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Rare Metals

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30.07.2020 | REVIEW

Recent progress in Li-ion batteries with TiO₂ nanotube anodes grown by electrochemical anodization

verfasst von: Meng-Meng Zhang, Jia-Yuan Chen, Hui Li, Chun-Rui Wang

Erschienen in: Rare Metals | Ausgabe 2/2021

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Abstract

Self-organized titanium dioxide (TiO₂) nanotubes, which are prepared by electrochemical anodizing, have been widely researched as promising anodes for Li-ion batteries. Both nanotubular morphology and bulk structure of TiO₂ nanotubes can be easily changed by adjusting the anodizing and annealing parameters. This is provided to investigate different phenomena by selectively adjusting a specific parameter of the Li⁺ insertion mechanism. In this paper, we reviewed how the morphology and crystallography of TiO₂ nanotubes influence the electrochemical performance of Li⁺ batteries. In particular, electrochemical performances of amorphous and anatase titanium dioxide nanotube anodes were compared in detail. As we all know, TiO₂ nanotube anodes have the advantages of nontoxicity, good stability, high safety and large specific surface area, in lithium-ion batteries. However, they suffer from poor electronic conductivity, inferior ion diffusivity and low theoretical capacity (335 mAh·g⁻¹), which limit their practical application. Generally, there are two ways to overcome the shortcomings of titanium dioxide nanotube anodes, including doping and synthesis composites. The achievements and existing problems associated with doped TiO₂ nanotube anodes and composite material anodes are summarized in the present review. Based on the analysis of lithium insertion mechanism of titanium dioxide nanotube electrodes, the prospects and possible research directions of TiO₂ anodes in lithium-ion batteries are discussed.

Vorheriger Artikel Editorial for advanced energy storage and conversion materials and technologies

Nächster Artikel Alloy anodes for sodium-ion batteries

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Titel: Recent progress in Li-ion batteries with TiO2 nanotube anodes grown by electrochemical anodization
verfasst von: Meng-Meng Zhang
Jia-Yuan Chen
Hui Li
Chun-Rui Wang
Publikationsdatum: 30.07.2020
Verlag: Nonferrous Metals Society of China
Erschienen in: Rare Metals / Ausgabe 2/2021
Print ISSN: 1001-0521
Elektronische ISSN: 1867-7185
DOI: https://doi.org/10.1007/s12598-020-01499-x

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