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01.09.2020 | Original Article

Nonsolvent-induced phase separation-derived TiO₂ nanotube arrays/porous Ti electrode as high-energy-density anode for lithium-ion batteries

verfasst von: Zhi-Jia Zhang, Jun Zhao, Zhi-Jun Qiao, Jia-Min Wang, Shi-Hao Sun, Wen-Xing Fu, Xi-Yuan Zhang, Zhen-Yang Yu, Yu-Hai Dou, Jian-Li Kang, Ding Yuan, Yue-Zhan Feng, Jian-Min Ma

Erschienen in: Rare Metals | Ausgabe 2/2021

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Abstract

TiO₂ nanotube arrays, growing on three-dimensional (3D) porous Ti membrane, were synthesized using a facile nonsolvent-induced phase separation and anodization process. The length of those three-dimensional nanotube arrays could be tuned by prolonging the anodizing time. When the anodizing time is 8 h, the three-dimensional TiO₂ nanotube arrays/porous Ti electrode exhibits well cycling stability and ultra-high specific capacity, which is used in lithium-ion batteries, attributed to the high utilization rate of the substrate and the high growth intensity of the active materials. Three-dimensional TiO₂ nanotube arrays/porous Ti electrode, at 100 μA·cm⁻² with 8 h anodizing time, shows a typical discharge plateau at 1.78 V and exhibits the specific capacity with 2126.7 μAh·cm⁻². The novel nanotube arrays@3D porous architecture effectively shortens the electron/ion transmission path, which could pave way for optimizing the design of high-performance anode materials for next-generation energy storage system.

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Vorheriger Artikel Graphene-encapsulated blackberry-like porous silicon nanospheres prepared by modest magnesiothermic reduction for high-performance lithium-ion battery anode

Nächster Artikel Utilization of electroless plating to prepare Cu-coated cotton cloth electrode for flexible Li-ion batteries

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Titel: Nonsolvent-induced phase separation-derived TiO2 nanotube arrays/porous Ti electrode as high-energy-density anode for lithium-ion batteries
verfasst von: Zhi-Jia Zhang
Jun Zhao
Zhi-Jun Qiao
Jia-Min Wang
Shi-Hao Sun
Wen-Xing Fu
Xi-Yuan Zhang
Zhen-Yang Yu
Yu-Hai Dou
Jian-Li Kang
Ding Yuan
Yue-Zhan Feng
Jian-Min Ma
Publikationsdatum: 01.09.2020
Verlag: Nonferrous Metals Society of China
Erschienen in: Rare Metals / Ausgabe 2/2021
Print ISSN: 1001-0521
Elektronische ISSN: 1867-7185
DOI: https://doi.org/10.1007/s12598-020-01571-6

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Abstract

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