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Cellulose

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09.10.2017 | Original Paper

Structure characterization of cellulose nanofiber hydrogel as functions of concentration and ionic strength

verfasst von: Lihong Geng, Xiangfang Peng, Chengbo Zhan, Ali Naderi, Priyanka R. Sharma, Yimin Mao, Benjamin S. Hsiao

Erschienen in: Cellulose | Ausgabe 12/2017

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Abstract

Carboxylated cellulose nanofibers (CNFs), having an average width of 7 nm and thickness of 1.5 nm, were produced by TEMPO (2,2,6,6-tetramethylpiperidine-1-oxyl radical)-mediated oxidation method. The fiber cross-sectional dimensions were determined using small-angle X-ray scattering (SAXS), transmission electron microscopy and atomic force microscopy techniques, where the rheological properties under different concentration and ionic strength were also investigated. The formation of hydrogel was evidenced by increasing the CNF concentration or ionic strength of the solvent (water), while the gel structure in ion-induced CNF hydrogels was found to be relatively inhomogeneous. The gelation behavior was closely related to the segmental aggregation of charged CNF, which could be quantitatively characterized by the correlation length (ξ) from the low-angle scattering profile and the scattering invariant (Q) in SAXS.

Vorheriger Artikel Metal sulfates-catalyzed butanolysis of cellulose: butyl levulinate production and optimization

Nächster Artikel Length-controlled cellulose nanofibrils produced using enzyme pretreatment and grinding

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Titel: Structure characterization of cellulose nanofiber hydrogel as functions of concentration and ionic strength
verfasst von: Lihong Geng
Xiangfang Peng
Chengbo Zhan
Ali Naderi
Priyanka R. Sharma
Yimin Mao
Benjamin S. Hsiao
Publikationsdatum: 09.10.2017
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 12/2017
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-017-1496-2

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