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Polymer Bulletin
Erschienen in: Polymer Bulletin 5/2017

07.09.2016 | Original Paper

Sulfonium cation based ionic liquid incorporated polymer electrolyte for lithium ion battery

verfasst von: R. Muthupradeepa, M. Sivakumar, R. Subadevi, V. Suryanarayanan

Erschienen in: Polymer Bulletin | Ausgabe 5/2017

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Abstract

Polymer electrolyte (PE) composed of poly(vinylidene fluoride-co-hexafluoropropylene) P(VdF-co-HFP) and triethylsulfonium bis(trifluoromethylsulfonyl)imide (SEt3TFSI) ionic liquid (IL) had been evaluated in lithium ion battery for the first time in order to improve its performance and cycle life. X-ray diffraction analysis (XRD) reveals that incorporation of the IL (20 and 25 wt%) into the polymer matrix results in the change of state of the material from semi-crystalline to amorphous nature. Thermo-gravimetric and differential thermal analysis (TG/DTA) of the PE sample with 25 wt% of the IL shows high thermal stability. The nature of functional groups present in the PE was investigated by Raman spectrum. Surface morphological characteristics indicate that increase in the loading of the IL into the polymer matrix leads to maximum number of pores with good interconnected network. Polymer/IL electrolyte (wt. ratio of 75:25) having a maximum ionic conductivity of 6.93 × 10−5 S/cm at 303 K with an activation energy of 0.23 eV shows excellent electrochemical potential stability of 4.4 V vs Li, as revealed by cyclic voltammetry (CV). Charge–discharge characteristics of the coin cell containing the above optimized ratio of PE with LiFePO4 cathode and Li anode shows a discharge capacity of 133 mAh/g, which is stable up to ten cycles.

Graphical abstract

Vorheriger Artikel Synthesis of poly(n-octadecyl methacrylate-co-2-hydroxyethyl methacrylate) copolymer and their utilization as polymeric stabilizer in the preparation of PCL microspheres
Nächster Artikel Analytical interpretation of mechanical response of green biocomposites based on poly(ε-caprolactone) and granular tapioca starch

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Metadaten
Titel
Sulfonium cation based ionic liquid incorporated polymer electrolyte for lithium ion battery
verfasst von
R. Muthupradeepa
M. Sivakumar
R. Subadevi
V. Suryanarayanan
Publikationsdatum
07.09.2016
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 5/2017
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-016-1796-y

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